where k (M− 2 s− 1) can be determined from the
in the pH range 2 to 5, from 5 to 40 °C and 0.01 to 1 M.The effect of pH and ionic strength on the reaction suggest that the rates are due to
where H2A = H2CrO4, HA = HCrO4, H2B = H2SO3 and HB = HSO3. The overall rate expression over the investigated pH range can be determined from
k=kH2A–H2B(αH2A)(αH2B)2+kHA–H2B(αHA)(αH2B)2+kH2A–HB(αH2A)(αHB)2
with kH2A−H2B = 5.0 × 107, kHA–H2B = 1.5 × 106 and kH2A–HB = 6.7 × 107.Fe(III) in the range 1.5 to 20 μM exerts a small catalytic effect on the reaction and significantly lowers the initial concentration of Cr(VI) compared to the nominal value. Contrary to Fe(III), formaldehyde (20 to 200 μM) reacts with S(IV) to form the hydroxymethanesulfonate adduct (CH2OHSO3), which does not react with Cr(VI). Major cations Mg2+ and some minor elements such as Ba2+ and Cu2+ did not affect the rates. The application of this rate law to environmental conditions suggest that this reaction may have a role in acidic solutions (aerosols and fog droplets). This reaction becomes more important in the presence of high Fe(III) and low HMS concentrations, contributing to affect the atmospheric transport of chromium species and the distribution of redox species of chromium, which reach surface water from atmospheric depositions.  相似文献   
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11.
论述旅游目的地形象形成的 8个阶段 ,并结合南京郊区旅游地的实际情况 ,对目的地形象的推广思路进行分析。从旅游者心理特征出发 ,提出了目的地形象的生命周期问题 ,通过对南京郊区旅游地形象现状的评估 ,认为钟山风景区形象趋于老化 ,面临形象的重新定位。  相似文献   
12.
城市公共服务设施的配置水平直接影响到居民的生活品质。论文基于高德地图获取的地图数据,使用城市网络分析工具(Urban Network Analysis Toolbox, UNA)对大连市沙河口区内的6类公共服务设施分布进行空间分异分析,并对区内90个社区的居民出行可达设施的数量及类别进行测度,最后对各个社区进行总体评价。结果表明:① 大连市沙河口区公共服务设施空间分布不均,北多南少,呈现出“一主多次”的“廾”字形的结构,主要分布在西安路商业区周边和各个街道的次级商业区;② 居民可达设施数量空间差异大,北多南少,各街道均有1或2个区域可达设施数量较多;③ 居民可达设施类型数量存在一定差异,70%以上的住宅楼中的居民可以获得全部6类公共服务设施;④ 各社区居民可达设施总体处于差异较小的均衡状态,但仍有个别社区存在内部差异较大的现象。设施的分布、地物的阻隔和社区的封闭程度对居民获取各类公共服务设施影响较大,建议构建“设施完善、便捷可达”的15 min社区生活圈。  相似文献   
13.
This paper updates a life-cycle net energy analysis and carbon dioxide emissions analysis of three Midwestern utility-scale wind systems. Both the Energy Payback Ratio (EPR) and CO2 analysis results provide useful data for policy discussions regarding an efficient and low-carbon energy mix. The EPR is the amount of electrical energy produced for the lifetime of the power plant divided by the total amount of energy required to procure and transport the materials, build, operate, and decommission the power plants. The CO2 analysis for each power plant was calculated from the life-cycle energy input data. A previous study also analyzed coal and nuclear fission power plants. At the time of that study, two of the three wind systems had less than a full year of generation data to project the life-cycle energy production. This study updates the analysis of three wind systems with an additional four to eight years of operating data. The EPR for the utility-scale wind systems ranges from a low of 11 for a two-turbine system in Wisconsin to 28 for a 143-turbine system in southwestern Minnesota. The EPR is 11 for coal, 25 for fission with gas centrifuge enriched uranium and 7 for gaseous diffusion enriched uranium. The normalized CO2 emissions, in tonnes of CO2 per GWeh, ranges from 14 to 33 for the wind systems, 974 for coal, and 10 and 34 for nuclear fission using gas centrifuge and gaseous diffusion enriched uranium, respectively.  相似文献   
14.
海洋贝类利用模式生命周期评价方法研究   总被引:2,自引:0,他引:2  
首次将产品生命周期评价方法(LCA)应用于海洋贝类利用模式上。根据海洋贝类利用技术产业发展的特性和趋势,设计构建了由确定目标和范围、清单分析、影响评价3个步骤组成的评价体系,挑选了具有典型代表的2种扇贝利用模式进行评价,对其生产过程中的资源消耗、固体废弃物、富营养化、温室效应、酸化影响和潜在影响进行对比评价。评价结果显示其中资源消耗、温室效应、酸化影响、潜在健康影响的影响潜值模式2(产品模式为扇贝柱、复合氨基酸、鱼虾饵料和贝壳工艺品)比模式1(产品模式为扇贝柱、食用贝边、鱼虾鲜饵料和饲料添加剂)低;而固体废弃物、富营养化的影响潜值,模式2比模式1高。本评价方法可用于选择和优化海洋贝类的绿色化高值利用模式。研究表明,利用文章提出的海洋贝类利用评价方法可以有效掌握贝类利用的整个过程的环境行为,确定其中优化资源、节省能源和减少污染的关键步骤,为优化利用模式提供基础数据支持。  相似文献   
15.
皱纹盘鲍对氯霉素的通透性吸收与扩散   总被引:1,自引:0,他引:1  
在海水溶液中的氯霉素分子可以越过皱纹盘鲍Haliotis discus hannai Ino的体表结构进入其血淋巴液中。鲍血淋巴液中氯霉素的浓度与药浴液的氯霉素浓度,温度均呈线性关系,药浴时间的效应表现的S形逼近曲线。在20℃的海水中,鲍血淋巴液中的氯霉素向体外扩散的半衰期为42min。  相似文献   
16.
Optimal Design of TMD Under Long-Term Nonstationary Wave Loading   总被引:3,自引:0,他引:3  
—Traditionally,the use of a tuned mass damper(TMD)is to improve the surviability of the pri-mary structure under extraordinary loading environment while the design loading condition is describedby either a harmonic function or a stationary random process that can be fully characterized by a powerspectral density(PSD)function.Aiming at prolonging the fatigue life of an offshore platform,this studyconsiders an optimal design of TMD for the platform under long-term nonstationary loading due tolong-term random sea waves characterized by a probabilistic power spectral density(PPSD)function.Inprinciple,a PPSD could be derived based on numerous ordinary PSD functions;and each of them is treat-ed as realization of the corresponding PPSD.This study provides a theoretical development for theoptimal TMD design by minimizing the cost function to be the mean square value of the expectedlong-term response.A numerical example is presented to illustrate the developed design procedure.  相似文献   
17.
18.
The pattern of resource allocation into multiple life‐history traits can vary with the environment; for example, high temperatures generally facilitate growth. Changes in investment in growth due to temperature may alter the allocation to other traits that are in trade‐off with that. Here, we investigated the trade‐off between growth and reproduction and whether the proportion of allocation to these varies with increasing seawater temperature in the lancelet Branchiostoma japonicum. We reared the lancelets of early adult stage under three different temperature treatments (control, + 1°C and + 2°C treatments) for 427 days in the laboratory. Although the total body length at initiation did not differ between treatments, the length was influenced by the interaction between elapsed days and temperature treatments, suggesting that growth rate was temperature‐dependent; the lancelets under higher temperature conditions showed a more rapid growth rate than did those under the control conditions. The frequency of individuals with gonads did not differ between treatments throughout their reproductive season. The monthly growth increments were also not significantly affected by the interaction between the presence/absence of gonads and temperature treatments, although the presence of gonads caused the growth increments to decrease. In addition, the effect of temperature treatments was significant. These results suggest that changes in temperature did not alter the pattern of allocation between growth and reproduction that were in a trade‐off, whereas high temperature would solely result in an increase in resource intake, at least in the early adult stage of this species.  相似文献   
19.
为了得到海洋平台疲劳失效风险最大的焊接区域,提出了以有限元网格单元应力为基础的谱分析筛选方法,并开发了程序。程序采用并行计算架构,单次完成数万个单元的累积损伤度/疲劳寿命计算,并通过有限元软件以云图方式显示疲劳寿命。采用该程序计算双浮筒半潜式平台的疲劳寿命。结果表明,该型平台疲劳失效风险较高的区域为立柱与上壳体下浮体连接对角线转角区域、浮筒中纵舱壁与立柱连接区域。并行计算方法的引入,大大缩减疲劳损伤度计算的分析时间,采用22核心的CPU,时间缩短为原来的1/18.5,17小时完成全平台外壳单元谱分析计算。  相似文献   
20.
The rates of the reduction of Cr(VI) with S(IV) were measured in deaerated NaCl solution as a function of pH, temperature and ionic strength. The rates of the reaction were found to be first order with respect to Cr(VI) and second order with respect to S(IV), in agreement with previous results obtained at concentrations two order higher than the present study. The reaction also showed a first-order dependence of the rates on the concentration of the proton and a small influence of temperature with an apparent energy of activation ΔHapp of 22.8 ± 3.4 kJ/mol. The rates were independent of ionic strength from 0.01 to 1 M. The rate of Cr(VI) reduction is described by the general expression
−d[Cr(VI)]/dt=k[Cr(VI)][S(IV)]2
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