普通铅同位素演化系统模式

已有的几种普通铅同位素模式仅反映了一些封闭体系铅同位素混合的特殊情况,不便于有效地应用于地质历史时期复杂的地质作用过程。本文应用概率论方法,从理论上分析包括开放体系在内的13种不同系统普通铅同位素混合的23种情况,讨论各种情况下铅同位素资料的地质年代学意义与地质事件发生年代的计算方法,从而建立多阶段铅同位素演化的系统模式。应用读系统模式研究燕山地区的成岩成矿时代,所得结果与其它方法测出的年龄一致。     

Seasonal variations in the origin of lead in snow at Dye 3, Greenland

The isotopic composition and concentration of lead has been measured in fresh and slightly aged snow collected at Dye 3 in southern Greenland during one full year. The lead concentration displayed large variations ranging from 14–3016 pg/g in April (spring) to 3–6 pg/g in September (summer) while the isotopic ratios changed in regular manner during the year. The ²⁰⁶Pb/²⁰⁷Pb ratios were 1.15 from spring to mid-summer snow, and increased in late summer to early autumn, reaching 1.20 in winter. These isotopic data indicate that the lead in the autumn to winter snow originated in North America, while that in spring to mid-summer snow is from Eurasia.     

基于FEA的填充墙与隔震器协同抗震系统性能分析

隔震器与填充墙对建筑抗震性能有很大作用。为了探究填充墙布置形式及填充材料和隔震器协同作用对钢筋混凝土框架结构动力特性及抗震性能的影响,采用等效斜撑理论,对3种不同填充墙布置形式与隔震器协同作用的抗震系统方案进行对比分析,研究发现顶层不布置填充墙与隔震器协同抗震系统钢筋混凝土框架结构的抗震性能最佳。在此系统上分析了不同填充材料对钢筋混凝土框架结构抗震性能的影响,结果表明,加气混凝土砌块填充墙的钢筋混凝土框架结构抗震性能最好。     

Response of hybrid isolation system during a shake table experiment of a full‐scale isolated building

A full‐scale 5‐story steel moment frame building was subjected to a series of earthquake excitations using the E‐Defense shake table in August, 2011. For one of the test configurations, the building was seismically isolated by a hybrid system of lead‐rubber bearings and low friction roller bearings known as cross‐linear bearings, and was designed for a very rare 100 000‐year return period earthquake at a Central and Eastern US soil site. The building was subject to 15 trials including sinusoidal input, recorded motions and simulated earthquakes, 2D and 3D input, and a range of intensities including some beyond the design basis level. The experimental program was one of the first system‐level full‐scale validations of seismic isolation and the first known full‐scale experiment of a hybrid isolation system incorporating lead‐rubber and low friction bearings. Stable response of the hybrid isolation system was demonstrated at displacement demands up to 550 mm and shear strain in excess of 200%. Torsional amplifications were within the new factor stipulated by the code provisions. Axial force was observed to transfer from the lead‐rubber bearings to the cross‐linear bearings at large displacements, and the force transfer at large displacements exceeded that predicted by basic calculations. The force transfer occurred primarily because of the flexural rigidity of the base diaphragm and the larger vertical stiffness of the cross‐linear bearings relative to the lead‐rubber bearings.     

内蒙古别鲁乌图铜多金属矿床锆石U-Pb年龄和S、Pb同位素特征及其地质意义

为了明确内蒙古别鲁乌图铜多金属矿床的成矿年龄与矿床成因,对该矿床中与成矿关系密切的流纹岩进行了锆石U-Pb年龄以及主要金属硫化物的S、Pb同位素测试。其中流纹岩的锆石206Pb/238U加权平均年龄为(271.7±1.6)Ma(MSWD=1.02),显示成矿作用发生于二叠纪。金属硫化物的S同位素分析结果显示δ34SV-CDT值分布在-0.6‰~1.0‰之间,平均为0.49‰,变化范围较窄,显示S的来源单一;Pb同位素组成比较集中,206Pb/204Pb为18.207~18.674,207Pb/204Pb为15.620~15.699,208Pb/204Pb为38.144~38.790,具有壳幔混源的特征。S、Pb同位素特征均指示成矿物质主要来源于岩浆热液。结合区域地质、矿床地质、空间分带等特征以及S、Pb同位素组成可知,别鲁乌图铜多金属矿床为VHMS型矿床,形成于二叠纪陆缘弧裂谷中。     

特高压互连电气设备减震性能振动台试验

为研究铅金属减震器对特高压互连电气设备的减震效果,进行由硬管母线连接的特高压避雷器设备和电容式电压互感器设备组成的互连耦合体系的地震模拟振动台试验。通过白噪声扫频、抗震及减震试验,测定互连耦合体系抗震结构及减震结构的自振频率以及关键部位的应变、加速度响应。试验结果表明:抗震结构中避雷器设备的最大应变响应大于互感器设备,互连耦合体系中的避雷器设备属于易损设备;安装减震器后互连设备频率降低幅度较小,减震器基本不会影响电气设备的正常运行;安装减震器后互连耦合体系中的避雷器设备和互感器设备在较大峰值加速度地震波作用下,设备顶端加速度响应和最大应变响应均有较大幅度的降低,避雷器设备和互感器设备的最大应变响应的减震效率分别为75%和50%,减震效果显著,减震器的应用大幅提升了互连耦合体系的抗震能力。     

泥蚶(Tegillarca granosa)重组铁蛋白富集重金属离子的特性及化学传感器的研究

利用泥蚶(Tegillarca granosa)铁蛋白原核表达工程菌获得的重组铁蛋白,通过圆二色光谱分析蛋白二级结构,扫描电镜和电感耦合等离子质谱研究重组铁蛋白富集Fe~(2+)、Mn~(2+)、Cd~(2+)、Cr~(3+)、Hg~(2+)、Pb~(2+)和As~(3+)等7种重金属离子的特性,同时探索利用重组铁蛋白修饰丝网印刷电极,设计和制备重组铁蛋白检测Pb~(2+)和Cd~(2+)浓度的电化学生物传感器。结果表明复性成功的铁蛋白多为完整的?-螺旋结构,而复性不成功的蛋白聚集体则多为无规卷曲。重组铁蛋白的直径和形态与富集的离子种类有关。泥蚶铁蛋白对单一金属离子Fe~(2+)和Mn~(2+)的富集凸显优势。对两种混合金属离子的富集大多表现为竞争关系。但重组铁蛋白对Hg~(2+)和As~(3+)混合组的富集量明显高于单一金属离子组的富集量,对Hg~(2+)和As~(3+)混合组的富集表现出协同促进作用。重组铁蛋白传感器对Pb~(2+)和Cd~(2+)溶液的最低检测限为10μg/L。     

Fluid Inclusions and Hydrogen,Oxygen, and Lead Isotopes of the Antuoling Molybdenum Deposit,Northern Taihang Mountains,China

The Antuoling Mo deposit is a major porphyry‐type deposit in the polymetallic metallogenic belt of the northern Taihang Mountains, China. The processes of mineralization in this deposit can be divided into three stages: an early quartz–pyrite stage, a middle quartz–polymetallic sulfide stage, and a late quartz–carbonate stage. Four types of primary fluid inclusions are found in the deposit: two‐phase aqueous inclusions, daughter‐mineral‐bearing multiphase inclusions, CO₂–H₂O inclusions, and pure CO₂ inclusions. From the early to the late ore‐forming stages, the homogenization temperatures of the fluid inclusions are 300 to >500°C, 270–425°C, and 195–330°C, respectively, with salinities of up to 50.2 wt%, 5.3–47.3 wt%, and 2.2–10.4 wt% NaCl equivalent, revealing that the ore‐forming fluids changed from high temperature and high salinity to lower temperature and lower salinity. Moreover, based on the laser Raman spectra, the compositions of the fluid inclusions evolved from the NaCl–CO₂–H₂O to the NaCl–H₂O system. The δ¹⁸O_H2O and δD values of quartz in the deposit range from +3.9‰ to +7.0‰ and ?117.5‰ to ?134.2‰, respectively, reflecting the δD of local meteoric water after oxygen isotopic exchange with host rocks. The Pb isotope values of the sulfides (²⁰⁸Pb/²⁰⁴Pb, 36.320–37.428; ²⁰⁷Pb/²⁰⁴Pb, 15.210–15.495; ²⁰⁶Pb/²⁰⁴Pb, 16.366–17.822) indicate that the ore‐forming materials originated from a mixed upper mantle–lower crust source.     

关于滇东北MVT型铅锌矿成矿时代的讨论

滇东北地区是我国重要的铅锌矿产品生产基地,区内发育多个大型密西西比河谷型(Mississippi valley-type,MVT型)铅锌矿床,个别矿床(会泽)达到超大型.前人对该区域的铅锌矿床开展了大量的年代学研究工作,获得了一大批成矿年龄,本文在通过对各类同位素测年方法在该类型矿床中使用存在的弊端进行分析后,基于滇东...     

河南省华北陆块南缘铅金成矿系统

华北陆块南缘是我国重要的多金属成矿带之一,可划分为两个成矿集中区:小秦岭-熊耳山金成矿带和栾川陆缘凹陷钼、钨、铅、锌成矿带.在其演化过程中形成不同的成矿系统,与铅成矿带有关的成矿系统为中新元古代拉张构造体制被动陆缘成矿系统:MVT型铅锌成矿系列和Sedex型铅锌成矿系列;中生代陆内碰撞成矿系统:与岩浆岩有关的热液充填交代型铅锌成矿系列.与金成矿带有关的成矿系统为古元古代古陆核边缘成矿系统:小秦岭石英脉型金矿成矿系列;中新元古代拉张构造体制被动陆缘成矿系统:熊耳山蚀变岩型金矿成矿系列.