210Pb in a tropical coastal lagoon sediment core

Excess ²¹⁰Pb in a core from a Mexican Coastal Lagoon, which has no connection with the sea shows a small but measurable decay over the length of the core, when different approaches were compared (excess and corrected ²¹⁰Pb activity with depth, total and inorganic cumulative weights) significant differences in the values for the sedimentation rate are obtained. The best coefficient correlation was calculated when corrected ²¹⁰Pb activity for the uneven distribution of organic matter and cumulative inorganic weight is considered ($\text{ω}\text{= 0·93 cm yr}{}^{\mathrm{?1}}$, R = ?0·86; ω = 0·51 cm yr^?1 for the top 13 cm, R = ?0·90 and 1·52 cm yr^?1 for the interval 14–46 with R = ?0·96).Time frames in the sedimentary column were in agreement between the ²¹⁰Pb calculated time and the appearance of shells fragments probably associated with the disturbances caused by the 1961 hurricane Tara.The surface accumulation rate is equivalent to a mean deposition of 262·5 g m^?2 yr^?1 or organic matter which is minor but comparable to some salt marshes of United States.     

云南元阳大坪金矿铅同位素化探评价

通过对云南元阳大坪金矿某切穿矿脉剖面、不同海拔高程矿脉的矿石和围岩的铅同位素组成分析，采用铅同位素系统剖面化探方法对大坪金矿进行了化探评价和隐伏矿的预测分析，指出大坪金矿已进入主矿体的中心部位，深部隐伏矿潜力不大，找矿战略应以扩大横向为主。金矿化与闪长岩铅同位素组成的一致性，表明金矿化受闪长岩的控制。     

兰坪铅锌矿可持续发展问题探讨

兰坪铅锌矿床是世界上第三大铅锌矿床,文章对兰坪铅锌矿的信息化现状进行了简要分析,指出目前存在的主要问题及信息化建设的紧迫性,并在此基础上提出了矿山数字化信息系统建设的具体措施.这对推动兰坪铅锌矿的数字化信息系统建设,实现兰坪铅锌矿的可持续开发利用有着重要的现实意义.     

阿尔泰山南缘克朗盆地泥盆纪火山沉积与矿产

新疆阿尔泰山南缘克朗晚古生代火山-沉积盆地盆地，位于西伯利亚板块南缘泥盆纪陆缘裂谷带中，在早泥盆世发生了大规模多期次的火山活动，在康布铁堡组火山沉积地层中形成了恰夏、铁木尔特和阿巴宫多个VMS型铜铅锌铁多金属矿床;中泥盆世火山作用减弱，在阿勒泰镇组沉积地层中形成SEDEX型红墩铅锌矿床。     

火试金捕集等离子体发射光谱法测定铜铅电解阳极泥中铂和钯

采用火试金分离捕集,电感耦合等离子体发射光谱法分析了铜铅电解阳极泥中的铂和钯,重点试验了银的沉淀分离条件,方法应用于实际样品的分析,加标回收率大于95%。用贫铂矿国家一级标准物质和铜阳极泥管理样分析验证方法,其结果与标准值相符。方法的精密度(RSD,n=5)分别为Pt2.68%~3.04%,Pd4.55%~8.36%。     

火法试金控制铅扣的氧化还原平衡方程探讨

根据分析物料的性质及在高温熔融过程中的主要反应,运用数学方法确立控制铅扣的氧化还原平衡方程式,并以此推导出几种矿物的应用公式。对影响铅扣大小的其他因素进行了探讨。     

大气颗粒物中铅的序列提取与分析表征

用石英纤维滤膜采集大气颗粒物样品,采用序列提取的方法把铅的总量分成环境可迁移态、碳酸盐和氧化物态、有机质和残渣态3个分量,用石墨炉原子吸收分光光度法测定铅的浓度,仪器检出限为1μg/L。对实际大气颗粒物样品进行序列提取,5份平行的序列提取3个分量测定及加和值的RSD分别为7.1%、3.3%、7.3%、5.0%。该样品三级序列提取的加和值(756μg/g)约为总量测定(738μg/g)的102%,两组数据一致性良好,且环境可迁移态、碳酸盐和氧化物态、有机质和残渣态的铅分别为加和值的64%、17%和20%。对几种典型的铅污染源排放样品进行序列提取和分析测定,不同源排放样品的形态特征各有特点,说明该序列提取的方案是可行的,达到了将不同形态的铅化合物分开的目的。     

陕西柞山地区穆家庄铜矿铅同位素地球化学与成矿物质来源

穆家庄铜矿床位于南秦岭造山带柞（水）山（阳）地区的泥盆系中.矿体产于红岩寺-黑山复式向斜南翼金井河-胡家沟次级背斜南翼近轴部断裂中,赋矿岩石为泥盆系青石垭组中上部白云质岩,其空间展布明显受背斜陡倾南翼（倒转翼）近轴部的层间断裂-裂隙带构造控制,矿石主要有团块状和网脉状,其后生成矿现象非常明显.本文从铅同位素地球化学出发,来探讨产于秦岭泥盆系中铜矿的成矿物质来源和矿床成因等问题.研究表明,穆家庄铜矿矿石铅和近矿围岩岩石铅具有极高的放射性成因铅特点.通过对矿石铅、近矿围岩岩石铅与测定的寒武系碳硅质岩岩石全岩铅进行综合对比,发现它们的组成特征类似,说明穆家庄铜矿铅源来自于寒武系.     

A multi-isotope approach （Pb, S, N, O and Sr） to estimate the impact of long distance air pollution

The impact of air pollution is a substantial European and global problem which has been observed even in the most remote areas of our planet. Not only surface water, but also groundwater resources are partly endangered by dry and wet deposition from the air. Karst and other sensitive aquifers contribute up to 90 % to the total drinking water supply in some European regions. However, they are more vulnerable to contamination than other aquifers due to short transfer times from recharge to source. Therefore, the main objective of this paper is to show possibilities to quantify the impact of air pollution on sensitive water resources （e.g. karst）, to develop an innovative surveillance tool based on isotopes and meteorological considerations. Comparisons of lead isotope measurements in precipitation, spring waters, soil profiles and dolomite bedrock in a relatively pristine and remote area at the front-range of the Northern Calcareous Alps in Austria with literature data indicate that radiogenic Australian gasoline-lead still dominates with 60%-80% the composition of the trace lead in the spring waters. In addition to the lead leached from the dolomite bedrock a third source contributes about 5%-10%. This second long distance Pb-contribution may originate from coal burning and/or Ag-Pb-ore smelting in central Europe in the past. The monthly precipitation （May and September 2005） samples show ^18O-rich sulphate ions, whereas the soil sulphates change in the direction to lower ^18O- and higher ^34S values with depth. The spring waters and bedrock dolomites show relatively low delta ^34S values （4‰-9 ‰）. Assuming the precipitation samples and the dolomite bed rocks are end-members the contribution of atmospheric sulphate can estimated to be 20% in the spring waters and between 10% to 45% in the soil samples. The ^87Sr/^86Sr-isotope results in the precipitation （0.7092） support at least a more radiogeradiogenic, far transported source in addition to a possible recycling of local dolomite and limestone （0.7080-0.7083） dust.     

Transformation of organic carbon and its potential impact on lead weathering in firing range soils

Lead （Pb） is normally considered as a trace element in soils and sediments for geochemical study. However, the concentration of Pb in firing range soils is generally so high that it should be considered as a major element during the evaluation of the soil geochemical properties. Soil organic matter （SOM） has been reported as one of the major factors to expedite the corrosion of metallic lead （Pb） in acidic and organic-rich soils. The main impacts of SOM on the fate and transport of Pb in firing range soils lie in the following two aspects; （1） the complexation of organic matter with Pb, which has received lots of attention, and; （2） changes in soil redox potential due to the transformation of SOM and its subsequent impact on Pb speciation, which has rarely been investigated. Soils from 6 different firing ranges are selected for this study. These samples have been stored under a closed condition for more than 3 years. The soil moisture contents were well-retained, as all the samples were kept in closed plastic buckets. The analytical data showed that the summation of the soil total organic carbon content （TOC） and inorganic carbon contents （TIC） were consistent with soil total carbon contents （TC） measured in previous years, although the TOC and TIC contents have changed respectively after years of storage. In general, it is observed that the soil TOC decreased against an increase of TIC. The mass balance on such a transformation suggested a major conversion of organic carbon （Corg） to inorganic carbon （CO3^2-） in the stored soils.