Production and Certification of a Unique Set of Isotope and Delta Reference Materials for Boron Isotope Determination in Geochemical,Environmental and Industrial Materials

Isotopic reference materials are essential to enable reliable and comparable isotope data. In the case of boron only a very limited number of such materials is available, thus preventing adequate quality control of measurement results and validation of analytical procedures. To address this situation a unique set of two boron isotope reference materials (ERM‐AE102a and ‐AE104a) and three offset δ¹¹B reference materials (ERM‐AE120, ‐AE121 and ‐AE122) were produced and certified. The present article describes the production and certification procedure in detail. The isotopic composition of all the materials was adjusted by mixing boron parent solutions enriched in ¹⁰B or ¹¹B with a boron parent solution having a natural isotopic composition under full gravimetric control. All parent solutions were analysed for their boron concentration as well as their boron isotopic composition by thermal ionisation mass spectrometry (TIMS) using isotope dilution as the calibration technique. For all five reference materials the isotopic composition obtained on the basis of the gravimetric data agreed very well with the isotopic composition obtained from different TIMS techniques. Stability and homogeneity studies that were performed showed no significant influence on the isotopic composition or on the related uncertainties. The three reference materials ERM‐AE120, ERM‐AE121 and ERM‐AE122 are the first reference materials with natural δ¹¹B values not equal to 0‰. The certified δ¹¹B values are ?20.2‰ for ERM‐AE120, 19.9‰ for ERM‐AE121 and 39.7‰ for ERM‐AE122, each with an expanded uncertainty (k = 2) of 0.6‰. These materials were produced to cover about three‐quarters of the known natural boron isotope variation. The ¹⁰B enriched isotope reference materials ERM‐AE102a and ERM‐AE104a were produced for industrial applications utilising ¹⁰B for neutron shielding purposes. The certified ¹⁰B isotope abundances are 0.29995 for ERM‐AE102a and 0.31488 for ERM‐AE104a with expanded uncertainties (k = 2) of 0.00027 and 0.00028, respectively. Together with the formerly certified ERM‐AE101 and ERM‐AE103 a unique set of four isotope reference materials and three offset δ¹¹B reference materials for boron isotope determination are now available from European Reference Materials.     

中国大陆地磁场Z分量日变幅的时空特征分析

In this paper, we use the daily ranges of the vertical magnetic intensity of approximately 76 geomagnetic stations from January 1, 2008 to December 31, 2010 to analyze the spatial and temporal characteristics of Z ranges. The results are summarized as follows: (1) Temporally, we use regressive analysis and FFT analysis to analyze the data. The results show that the Z component daily ranges of all stations have an obvious cyclical variation, the computed Fourier spectra of all data sets have clearly resolved the required periodicities in the data, in the form of distinct peaks at days 365, 183, 22, and 73, and the power spectra of day 365 is the highest in all periods. (2) In terms of spatial variation, the daily ranges show nonlinear variation with latitude in China. The results show the existence of a point of inflexion (maximal value point) nearby at about 25°N, the daily ranges of Z rise from 15°~25°N and have a good linear decrease variation along with 25°~50°N. (3) Compared with the spatial and temporal variations of Z daily ranges with the Sq current inversion, we found that the spatial and temporal characteristics of Z ranges are decided mainly by the spatio-temporal evolution of the Sq current system. (4) If the latitudes of the maximum amplitudes of variation of the vertical component in the geomagnetic quiet days are roughly taken as the latitudes corresponding to the foci of Sq overhead current system, we can see that these latitudes of foci become higher in summer, are lowest in winter and highest during Equinoxes, displaying conspicuous monthly and daily variations. For two successive geomagnetic quiet days, the latitudes of foci may vary ten degrees.     

基于偶极弯曲波频散的横波慢度径向分布反演

本文针对地层横波慢度径向分层模型,分析了地层横波慢度的径向非均匀性对弯曲波频散的影响.基于径向非均匀与均匀模型之间弯曲波频散的差异,结合微扰法和Backus-Gilbert(BG)理论建立了反演横波慢度径向分布的方程,求取了地层横波慢度的径向分布.在无噪声和参数误差时,反演结果较好地反映了实际地层横波慢度的径向分布,当井孔流体或井外地层纵波慢度的选取误差在10%内变化时,反演结果基本保持不变;存在信噪比(SNR)为20 dB(信号的功率为噪声的100倍)或10 dB(信号的功率为噪声的10倍)噪声时,反演结果没有发生明显的改变,其相对误差基本控制在10%以内,可见噪声对反演结果的影响不大.以上反演结果说明,本文采用的结合微扰法和BG理论的反演方法来估测地层横波慢度的径向分布时,具有很好的鲁棒性,可以被用于现场了解井壁周围的地层性质.     

DISTORTIONS IN PRESETTLEMENT LAND EVALUATION: THE CASE OF SWAN RIVER,WESTERN AUSTRALIA∗

The United States Department of Energy is required by law to plan, acquire, store, and maintain a Strategic Petroleum Reserve of crude oil and petroleum products. This is to be used if there is an interruption in crude oil supply. The plan is described and then analyzed with a linear programming model. The results show that the plan is generally well formulated.     

Characteristics of intraseasonal variations in the mixed layer of “warm pool” areas

Observational data obtained during the TOGA-COARE IOP in the “warm pool” area of the Western Tropical Pacific were used to analyze some characteristics of the intraseasonal variations in the mixed layer. The influence of westerly burst and rainfall on SST, salinity and mixed layer depth are discussed. There are two pairs of counteracting processes in the “warm pool” mixed layer: (1) The increase of mixed layer depth caused by local westerly bursts and the decrease of mixed layer depth caused by larger scale easterly relaxation; (2) the vertical mixing by local wind and the strong stratification due to rainfall in the mixed layer. Some possible mechanisms through the interactions between the intraseasonal time scale variations of the oceanic mixed layer and atmospheric low frequency oscillations are revealed. Supported by National Natural Science Foundation of China (49276250) and LASG of Beijing.     

Temporal Variations in the Second-Degree Stokes Tesseral Geopotential Coefficients from Topex/Poseidon Altimetry

The TOPEX/POSEIDON (T/P) altimetry data set covering the periodof January 1, 1993 to January 3, 2001 was used to derive monthlyseries of the second-degree tesseral geopotential coefficients.To account for the sea water temperature variations, rathersimple models have been devised and discussed, describinglocalized as well as areal variations of sea water temperatureand heights. The second-degree tesseral coefficients have alsobeen shown to be proportional to the pressureportions of the oceanic equatorial effective excitation functions,used in Ocean Angular Momentum (OAM) data. OAM datatogether with Atmospheric Angular Momentum (AAM) data canbe used to study observed polar motion (PM) series.The excess PM rates, derived from the T/P effective excitationfunctions, were compared to the corresponding observed PM rates,derived from the International Earth Rotation Service (IERS)Bulletin A and corrected with AAM also obtainedfrom IERS. The noise of the T/P derived PM rate series was foundto be significantly larger than the corresponding Bulletin A/AAMPM rate residuals as well as the PM rates derived from anindependent OAM series that was also available for the1993–2000 period.     

Seasonal and intraseasonal variations of the surface Taiwan Warm Current

To study seasonal and intraseasonal variations of the Taiwan Warm Current (TWC) in detail Rotated Empirical Orthogonal Function (REOF) and Extended Associate Pattern Analysis (EAPA) are jointly adopted with daily sea surface salinity (SSS), sea surface temperature (SST) and sea surface height (SSH) datasets covering 1126 days from American Navy Experimental Real-Time East Asian Seas Ocean Nowcast System in the present paper. Results show that the first and second REOFs of SST in the southern East China Sea (SECS) account for 50.8% and 39.8% of the total variance. The surface TWC contains persistent (multi-year mean), seasonal and intraseasonal components. The persistent one mainly inosculates with the Kuroshio but the seasonal and intraseasonal ones are usually active only on the continental shelf. Its persistent component is produced by inertial flow of the Kuroshio, however its seasonal and intraseasonal ones seems coming from seasonal and intraseasonal oscillations of monsoon force. The seasonal one reaches its maximum in late summer,lasting about four months and the intraseasonal one takes place at any seasons, lasting more than 40 days.     

Influence of the Convection over the South China Sea on the Summer Precipitation of Shandong Province

1　Introduction　ShandongProvince ,whichislocatedintheeastofChina ,consistspartlyofpeninsulaandpartlyofinlandwithatotalareaofabout 1 5 0 0 0 0km2 .Lyingfrom34°2 0′Nto 38°2 0′Nandfrom 1 1 4°4 0′Eto 1 2 2°4 0′E ,alltheareabelongstothemoderateregionandtothetypicalAsianmonsoonclimate .SoShandong’ssum merprecipitationaccountsforover 6 0 %oftheannualrainfall,andaccordinglyflood droughtdisastersmain lyoccurinsummer.Moreover,becauseitisgeographi callylocatedinthetransitionalareabetweenthe…     

EFFECTS OF SEASONALITY ON STREAMFLOW AND WATER QUALITY OF THE PINANG RIVER IN PENANG ISLAND, MALAYSIA

For the Pinang River, originating in the western highlands of Penang Island, the nature, sources and extent of pollution were studied. The river water samples collected at five selected sites were analyzed for various physical and chemical parameters, namely temperature, DO, BOD, COD, SS, pH, ammoniac nitrogen (AN), and conductance. Long-term data of rainfall and temperature were analyzed to determine the seasonal variations of the streamflow.The streamflow during the dry season is extremely low compared to the wet season, thus concentrations of contaminants derived from point pollution source increase due to lack of rainfall and runoff events. On the contrary, in the predominantly urban and agricultural catchments, non-point pollution source increases during rainy season through seepage and runoff. Effects of seasonal variations consequently deterrnine the quantity and quality of the water parameters.The Jelutong River, the Dondang River and the Air Itam River carry the seepage from widely urban and residential areas to the main Pinang River systems. Water quality of the Pinang River at different points assessed by the water quality indices was compared. According to the quality indices during the study period, water quality in the upper reaches of the river is medium to good. It dwindled in the plains, due to the seepage from urban areas and discharges from the industrial and agricultural lands.