Certification of ERM‐EB400, the First Matrix Reference Material for Lead Isotope Amount Ratios,and ERM‐AE142, a Lead Solution Providing a Lead Isotopic Composition at the Edge of Natural Variation

Lead isotope amount ratios are commonly used in diverse fields such as archaeometry, geochemistry and forensic science. Currently, five reference materials with certified lead isotope amount ratios are available, namely NIST SRM 981, 982 and 983, GBW‐04442 and NMIJ 3681‐a. Only NIST SRM 981 and NMIJ 3681‐a have approximately natural isotopic compositions, and NIST SRM 981 is predominantly used for correcting mass discrimination/mass fractionation in the applied mass spectrometric procedures. Consequently, there is no other certified reference material available to be used for validation and/or quality control of the analytical procedures applied to lead isotope amount ratio measurements. To fill this gap, two new reference materials have been produced and certified for their lead isotope amount ratios. For both certified reference materials, complete uncertainty budgets have been calculated and SI traceability has been established. This provides the users with independent means for validating and verifying their analytical procedures and for conducting quality control measures. ERM‐EB400 is a bronze material with a nominal lead mass fraction of 45 mg kg^?1 and certified lead isotope amount ratios of n(²⁰⁶Pb)/n(²⁰⁴Pb) = 18.072(17) mol mol^?1, n(²⁰⁷Pb)/n(²⁰⁴Pb) = 15.578(18) mol mol^?1 and n(²⁰⁸Pb)/n(²⁰⁴Pb) = 38.075(46) mol mol^?1 with the associated expanded uncertainties (k = 2) given in brackets. ERM‐AE142 is a high‐purity solution of lead in 2% nitric acid with a nominal mass fraction of 100 mg kg^?1 and certified Pb isotope amount ratios of n(²⁰⁶Pb)/n(²⁰⁴Pb) = 21.114(17) mol mol^?1, n(²⁰⁷Pb)/n(²⁰⁴Pb) = 15.944(17) mol mol^?1 and n(²⁰⁸Pb)/n(²⁰⁴Pb) = 39.850(44) mol mol^?1 with the associated expanded uncertainties (k = 2) given in brackets. Both materials are specifically designed to fall within the natural lead isotopic variation and to assist users with the validation and verification of their analytical procedures. Note that while one of these reference materials requires the chemical separation of Pb from its matrix (ERM‐EB400), the other does not (ERM‐AE142). As additional information, δ^208/206Pb_{NIST SRM981} values are provided for both materials. For ERM‐AE142, a delta value of δ^208/206Pb_{NIST SRM981} = ?28.21(30)‰ was obtained, and for ERM‐EB400, a delta value of δ^208/206Pb_NIST SRM981= ?129.47(38)‰ was obtained, with the associated expanded uncertainties (k = 2) given in brackets.     

Estimation of diffuse photosynthetically active radiation and the spatiotemporal variation analysis in China from 1981 to 2010

Photosynthetically active radiation (PAR) is the energy source of plant photosynthesis, and the diffuse component can enhance canopy light use efficiency, thereby increasing the carbon uptake. Therefore, diffuse PAR is an important driving factor of ecosystem productivity models. In this study, we estimated the diffuse PAR of over 700 meteorological sites in China from 1981 to 2010 using an empirical model based on observational data from Chinese Ecosystem Research Network (CERN) and China Meteorology Administration. Then we derived the spatial data set of 10 km monthly diffuse PAR using ANUSPLIN software, and analyzed the spatiotemporal variation characteristics of diffuse PAR through GIS and trend analysis techniques. The results showed that: (1) The spatial patterns of annual average diffuse PAR during 1981-2010 are heterogeneous across China, lower in the northeast and higher in the west and south. The nationwide average value for 30 years ranges from 6.66 mol m^-2 d^-1 to 15.27 mol m^-2 d^-1, and the value in summer is the biggest while the value in winter is the smallest. (2) There is an evident increasing trend of annual diffuse PAR during recent 30 years, with the increasing amplitude at 0.03 mol m^-2 d^-1/10a. But a significant declining trend is shown in the first 10 years, and obvious anomalies can be seen in 1982, 1983, 1991 and 1992. And there is a downtrend in spring and an uptrend in all the other seasons. (3) The spatial distribution of temporal variation rates of diffuse PAR is inhomogeneous across the country, generally decreasing in the north and increasing in the south.     

Interannual variability in the North Pacific meridional overturning circulation

We analyzed the temporal and spatial variation, and interannual variability of the North Pacific meridional overturning circulation using an empirical orthogonal function method, and calculated mass transport using Simple Ocean Data Assimilation Data from 1958–2008. The meridional streamfunction field in the North Pacific tilts N-S; the Tropical Cell (TC), Subtropical Cell (STC), and Deep Tropical Cell (DTC) may be in phase on an annual time scale; the TC and the STC are out of phase on an interannual time scale, but the interannual variability of the DTC is complex. The TC and STC interannual variability is associated with ENSO (El Niño-Southern Oscillation). The TC northward, southward, upward, and downward transports all weaken in El Niños and strengthen in La Niñas. The STC northward and southward transports are out of phase, while the STC northward and downward transports are in phase. Sea-surface water that reaches the middle latitude and is subducted may not completely return to the tropics. The zonal wind anomalies over the central North Pacific, which control Ekman transport, and the east-west slope of the sea level may be major factors causing the TC northward and southward transport interannual variability and the STC northward and southward transports on the interannual time scale. The DTC northward and southward transports decrease during strong El Niños and increase during strong La Niñas. DTC upward and downward transports are not strongly correlated with the Niño-3 index and may not be completely controlled by ENSO.     

2002-2010年长江流域GRACE水储量时空变化特征

利用高斯平滑滤波对2002年4月-2010年12月逐月GRACE卫星的时变重力场数据反演得到长江流域大尺度陆地水储量变化,对其时空变化进行研究,并将结果与全球陆面同化数据(GLDAS)模拟结果进行比较。其结论为:根据GRACE数据反演与GGLDAS模拟得到的水储量结果在大多数区域变化趋势相同,两者具有一致性,相关性达到0.89(P<0.05)。GRACE水储量研究结果表明:①2002-2010年长江流域水储量呈增加趋势,平均增长速率为0.43mm/月,相当于约95.04亿m³/年。长江上游增长速率为0.53mm/月,相当于约67.13亿m³/年;中游增长速率为0.51mm/月,相当于25.73亿m³/年;下游增长速率为0.36mm/月,相当于9.14亿m³/年。近9年长江流域水储量共增加约855.33亿m³。②从多年平均水储量空间分布来看,长江流域冬季月份(12、1、2、3月)水储量处于亏损状态,7-9月水储量处于盈余状态,4-6月下游至上游地区由亏损向盈余状态过渡,而10-11月则从上游至下游地区由盈余向亏损状态过渡。③全流域、上游及中游水储量逐月增长速率最大值出现在9月,分别为1.01cm/a、1.37cm/a、1.05cm/a;而下游地区则出现在7月,增长速率为1.62cm/a。     

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Trend,periodicity and abrupt change in streamflow of the East River,the Pearl River basin

The East River in the Pearl River basin, China, plays a vital role in the water supply for mega‐cities within and in the vicinity of the Pearl River Delta. Knowledge of statistical variability of streamflow is therefore important for water resources management in the basin. This study analyzed streamflow from four hydrological stations on the East River for a period of 1951–2009, using ensemble empirical mode decomposition (EEMD), continuous wavelet transform (CWT) technique, scanning t and F tests. Results indicated increasing/decreasing streamflow in the East River basin before/after the 1980s. After the early 1970s, the high/low flow components were decreasing/increasing. CWT‐based analysis demonstrates a significant impact of water reservoirs on the periodicity of streamflow. Scanning t and F test indicates that significantly abrupt changes in streamflow are largely influenced by both water reservoirs construction and precipitation changes. Thus, changes of streamflow, which are reflected by variations of trend, periodicity and abrupt change, are due to both water reservoir construction and precipitation changes. Further, the changes of volume of streamflow in the East River are in good agreement with precipitation changes. Copyright © 2012 John Wiley & Sons, Ltd.     

Imaging 3-D crustal P-wave velocity structure of western Yunnan with bulletin data

Western Yunnan is a region with intensive tectonic activity and serious earthquake risk. It is of significant importance to study three dimensional crustal structure of this region to understand the tectonic setting and disaster mechanism. Densification and digitalization of seismic networks in this region provides an opportunity to study the velocity structure with bulletin data. In this study, we collect P-wave data of 10 403 regional earthquakes recorded by 79 seismic stations from January 2008 to December 2010. In addition to first arrivals data (Pg with epicentral distance less than 200 km and Pn), the Pg (or P) data with epicentral distance more than 200 km are also considered as later direct arrivals in the tomographic inversion. We also compare the quantity and the quality of the seismic data before 2010 and after 2010. The test results show that adding the follow-up Pg phase can effectively improve the inversion ability of crustal imaging, and quantity and the data quality are significantly improved since 2010. The tomographic results show that: (1) The Honghe fault zone, which is the major fault systems in this region, may cut through the entire crust, and the velocity contrasts between two sides at lower crust beneath the Honghe fault are estimated at higher than 10%, while the velocity difference below Nujiang fault zone extends only in the upper crust; (2) Most of the earthquakes in the region occurred at the interface of high-velocity media and low-velocity media, i.e., the areas with high velocity gradient, which has been validated in other areas.     

Alternate bars in a sandy gravel bed river: generation,migration and interactions with superimposed dunes

A field study was carried out to investigate the development of alternate bars in a secondary channel of the Loire River (France) as a function of discharge variations. We combined frequent bathymetric surveys, scour chains and stratigraphical analysis of deposits with measurements and modelling of flow dynamics. The channel exhibited migrating bars, non‐migrating bars and superimposed dunes. Possible mechanisms of bar initiation were found to be chutes associated with changes of bank direction and instability resulting from interactions between existing bars during the fall in water level after floods. We propose that the reworking of bar sediments during low flows (high width‐to‐depth ratio β), reinforced by high values of the Shields mobility parameter, can explain the formation or re‐generation of new alternate migrating bars during a subsequent flood. The migration pattern of the bars was found to be cyclic and to depend mainly on (i) channel layout and (ii) the dynamics of superimposed dunes with heights and lengths depending on location and discharge value. For instance, the hysteresis affecting the steepness of dunes influences the flow resistance of the dunes as well as the celerity of migrating bars during flood events. We compare the findings from the field with results from theoretical studies on alternate bars. This gives insight in the phenomena occurring in the complex setting of real rivers, but it also sheds light on the extent to which bar theories based on idealized cases can predict those phenomena. Copyright © 2014 John Wiley & Sons, Ltd.     

Surface velocity estimations of ice shelves in the northern Antarctic Peninsula derived from MODIS data

The ice shelves in the northern Antarctic Peninsula are highly sensitive to variations of temperature and have therefore served as indicators of global warming. In this study, we estimate the velocities of the ice shelves in the northern Antarctic Peninsula using co-registration of optically sensed images and correlation module (COSI-Corr) in the Environment for Visualizing Images (ENVI) based on Moderate Resolution Imaging Spectroradiometer (MODIS) images during 2000-2012, from which we conclude that the ice ?ow directions generally match the peninsulas pattern and the crevasse, ice flows mainly eastward into the Weddell Sea. The spatial pattern of velocity field exhibits an increasing trend from the western grounding line to the maximum at the middle part of the ice shelf front on Larsen C with a velocity of approximately 700 ma^-1, and the velocity field shows relatively higher values in its southerly neighboring ice shelf (e.g. Smith Inlet). Additionally, ice ?ows are relatively quicker in the outer part of the ice shelf than in the inner parts. Temporal changes in surface velocities show a continuous increase from 2000 to 2012. It is worth noting that, the acceleration rate during 2000-2009 is relatively higher than that during 2009-2012, while the ice movement on the southern Larsen C and Smith Inlet shows a deceleration from 2009 to 2012.