Mathematical model for hydraulically aided electrokinetic remediation of aquifer and removal of nonanionic copper

One of the most cost-effective in situ technologies for soil and groundwater (i.e., aquifer) remediation is electrokinetic remediation. In electrokinetic remediation, electromigration due to electric field is combined with hydromigration due to hydraulic flow by purge water to remove pollutants from aquifers through the pore water. This study aims at investigating theoretically the role of electromigration (as active movement) of pollutants and the role of hydromigration (as passive movement) of pollutants in electrokinetic remediation, and making it clear that the control variables for electrokinetic remediation are the applied voltage and the hydraulic flow rate. These aims are pursued by construction of a mathematical model based on physico-chemical considerations and by model simulations of the electrokinetic remediation applied to the virtual aquifer polluted by heavy metals of copper sulfate. According to numerical simulations with the model: (1) heavy metal (nonanionic copper) is removed from the upstream anode region and accumulated in the downstream cathode region; (2) to carry away the heavy metal outside the aquifer (global removal), hydromigration by purge water flow is essential; and (3) electromigration contributes mainly to the redistribution of heavy metals within the aquifer (local removal and local accumulation).     

A size classification for debris flows

A 10-fold classification for debris flow size is proposed based on total volume, peak discharge and area inundated by debris. Size classes can be used for regional overview studies where detailed site investigations are either unnecessary, too costly or where the highest hazard and risk creeks need to be identified for further study. They are also useful to compare the regional impact between affected areas and the effects of rainstorms, and they allow lay-people to obtain an understanding of debris flow magnitude and consequences. Finally, different size classes allow the estimation of travel times to points of interest based on empirically derived equations. It is proposed that agencies concerned with debris flows should establish a documentation of debris flow size according to this classification, which serves as a data base for hazard and risk planning.     

泥石流运动衰减动力学初步研究

我国公路泥石流病害严重，泥石流淤埋公路构建筑物是一类常见的公路泥石流病害类型。泥石流衰减动力学是防治泥石流淤埋病害的重要关键技术，也是泥石流运动学、动力学研究的核心问题之一。本文作者运用泥沙运动力学及流体力学原理，初步建立了泥石流固相颗粒和液相浆体的能量衰减条件，把泥石流衰减模式概化为两类，即能量抑制衰减和能量自由衰减；通过泥石流沉积模型试验，得到了不同粘度泥石流体的沉积扇变化形态，随着泥石流体粘度的增大，沉积扇边缘变陡、扩展范围变小、纵轴线长度减小等结论与实际情况吻合；初步建立了泥石流能量衰减速率计算方法。研究成果为防治公路泥石流病害奠定了基础。     

Experimental evidences and numerical modelling of debris flow initiated by channel runoff

Debris flow initiation by channel bed mobilization is a common process in high mountainous areas. Initiation is more likely to occur at the outlet of small, steeply sloping basins where concentrated overland flow feeds an ephemeral channel incised in slope deposits. Such geological conditions are typical of the Dolomite region (Italian Alps), which is characterized by widespread debris flow activity triggered by severe summer thunderstorms. Real-time data and field observations for one of these catchments (Acquabona catchment, Belluno, Italian Alps) were used to characterize the hydrological response of the initiation area to rainfalls of varying intensity and duration. The observed behaviour was then reproduced by means of a simple hydrological model, based on the kinematic wave assumption, to simulate the generation of channel runoff. The model is capable of predicting the observed hydrological response for a wide range of rainfall impulses, thus providing a physical basis for the understanding of the debris flow triggering threshold.     

Temporal and spatial variations in water flow and sediment load in Narmada River Basin, India: natural and man-made factors

The Narmada River flows through the Deccan volcanics and transports water and sediments to the adjacent Arabian Sea. In a first-ever attempt, spatial and temporal (annual, seasonal, monthly and daily) variations in water discharge and sediment loads of Narmada River and its tributaries and the probable causes for these variations are discussed. The study has been carried out with data from twenty-two years of daily water discharge at nineteen locations and sediment concentrations data at fourteen locations in the entire Narmada River Basin. Water flow in the river is a major factor influencing sediment loads in the river. The monsoon season, which accounts for 85 to 95% of total annual rainfall in the basin, is the main source of water flow in the river. Almost 85 to 98% of annual sediment loads in the river are transported during the monsoon season (June to November). The average annual sediment flux to the Arabian Sea at Garudeshwar (farthest downstream location) is 34.29×10⁶ t year⁻¹ with a water discharge of 23.57 km³ year⁻¹. These numbers are the latest and revised estimates for Narmada River. Water flow in the river is influenced by rainfall, catchment area and groundwater inputs, whereas rainfall intensity, geology/soil characteristics of the catchment area and presence of reservoirs/dams play a major role in sediment discharge. The largest dam in the basin, namely Sardar Sarovar Dam, traps almost 60–80% of sediments carried by the river before it reaches the Arabian Sea.     

Mixing of event and pre‐event water in a shallow Entisol in sloping farmland based on isotopic and hydrometric measurements,SW China

Water percolation and flow processes in subsurface geologic media play an important role in determining the water source for plants and the transport of contaminants or nutrients, which is essential for water resource management and the development of measures for pollution mitigation. During June 2013, the dynamics of the rainwater, soil water, subsurface flows and groundwater in a shallow Entisol on sloping farmland were monitored using a hydrometric and isotopic approach. The results showed that effective mixing of rainwater and soil water occurred in hours. The rebound phenomenon of δD profiles in soils showed that most isotope‐depleted rainwater largely bypassed the soil matrix when the water saturation in the soil was high. Preferential‐flow, which was the dominant water movement pattern in the vadose zone, occurred through the whole soil profile, and infrequent piston‐flow was mainly found at 20–40 cm in depth. The interflow in the soil layer, composed of 75.2% rainwater, was only generated when the soil profile had been saturated. Underflow in the fractured mudrock was the dominant flow type in this hillslope, and outflow was dominated by base flow (groundwater flow) with a mean contribution of 76.7%. The generation mechanism of underflow was groundwater ridging, which was superimposed upon preferential‐flow composed mainly of rainwater. The quick mixing process of rainwater and soil water and the rapid movement of the mixture through preferential channels in the study soil, which shows a typical bimodal pore size distribution, can explain the prompt release of pre‐event water in subsurface flow. Water sources of subsurface flows at peak discharge could be affected by the antecedent soil water content, rain characteristics and antecedent groundwater levels. Copyright © 2016 John Wiley & Sons, Ltd.     

Impacts of groundwater flow on the evolution of a thermokarst lake in the permafrost–dominated region on the Qinghai–Tibet plateau

As a result of global warming induced permafrost degradation in recent decades, thermokarst lakes in the Qinghai–Tibet plateau (QTP) have been regulating local hydrological and ecological processes. Simulations with coupled moisture–heat numerical models in the Beiluhe basin (located in the hinterland of permafrost regions on the QTP) have provided insights into the interaction between groundwater flow and the freeze–thaw process. A total of 30 modified SUTRA scenarios were established to examine the effects of hydrodynamic forces, permeability, and climate on thermokarst lakes. The results indicate that the hydrodynamic condition variables regulate the permafrost degradation around the lakes. In case groundwater recharges to the lake, a low–temperature groundwater flow stimulates the expansion of the surrounding thawing regions through thermal convection. The thawing rate of the permafrost underlying the lake intensifies when groundwater is discharged from the lake. Under different permeability conditions, spatiotemporal variations in the active layer thickness significantly influence the occurrence of an open talik at the lake bottom. A warmer and wetter climate will inevitably lead to a sharp decrease in the upper limit of the surrounding permafrost, with a continual decrease in the duration of open talik events. Overall, our results underscore that comprehensive consideration of the relevant hydrologic processes is critical for improving the understanding of environmental and ecological changes in cold environments.     

An Eocene/Oligocene blueschist‐/greenschist facies P–T loop from the Cycladic Blueschist Unit on Naxos Island,Greece: Deformation‐related re‐equilibration vs. thermal relaxation

Geothermobarometric and geochronological work indicates a complete Eocene/early Oligocene blueschist/greenschist facies metamorphic cycle of the Cycladic Blueschist Unit on Naxos Island in the Aegean Sea region. Using the average pressure–temperature (P–T) method of thermocalc coupled with detailed textural work, we separate an early blueschist facies event at 576 ± 16 to 619 ± 32°C and 15.5 ± 0.5 to 16.3 ± 0.9 kbar from a subsequent greenschist facies overprint at 384 ± 30°C and 3.8 ± 1.1 kbar. Multi‐mineral Rb–Sr isochron dating yields crystallization ages for near peak‐pressure blueschist facies assemblages between 40.5 ± 1.0 and 38.3 ± 0.5 Ma. The greenschist facies overprint commonly did not result in complete resetting of age signatures. Maximum ages for the end of greenschist facies reworking, obtained from disequilibrium patterns, cluster near c. 32 Ma, with one sample showing rejuvenation at c. 27 Ma. We conclude that the high‐P rocks from south Naxos were exhumed to upper mid‐crustal levels in the late Eocene and early Oligocene at rates of 7.4 ± 4.6 km/Ma, completing a full blueschist‐/greenschist facies metamorphic cycle soon after subduction within c. 8 Ma. The greenschist facies overprint of the blueschist facies rocks from south Naxos resulted from rapid exhumation and associated deformation/fluid‐controlled metamorphic re‐equilibration, and is unrelated to the strong high‐T metamorphism associated with the Miocene formation of the Naxos migmatite dome. It follows that the Miocene thermal overprint had no impact on rock textures or Sr isotopic signatures, and that the rocks of south Naxos underwent three metamorphic events, one more than hitherto envisaged.     

Transient seepage analysis in zoned anisotropic soils based on the scaled boundary finite‐element method

The scaled boundary finite‐element method, a semi‐analytical computational scheme primarily developed for dynamic stiffness of unbounded domains, is applied to the analysis of unsteady seepage flow problems. This method is based on the finite‐element technology and gains the advantages of the boundary element method as well. Only boundary of the domain is discretized, no fundamental solution is required and singularity problems can be modeled rigorously. Anisotropic and non‐homogeneous materials satisfying similarity are modeled with no additional efforts. In this study, firstly, formulation of the method for the transient seepage flow problems is derived followed by its solution procedures. The accuracy, simplicity and applicability of the method are demonstrated via four numerical examples of transient seepage flow – three of them are available in the literature. Homogenous, non‐homogenous, isotropic and anisotropic material properties are considered to show the versatility of the technique. Excellent agreement with the finite‐element method is observed. The method out‐performs the finite‐element method in modeling singularity points. Copyright © 2014 John Wiley & Sons, Ltd.