川江航道BDS/GNSS船舶精密位速监测性能分析

采用精密单点定位和相位历元间差分法分别评估普通航段和库区航段BDS/GNSS的定位和测速性能。结果表明,在普通航段,BDS-2定位精度为0.1~0.2 m;GPS、BDS-3、BDS全系统的定位精度相对较高,水平方向优于0.07 m,垂直方向优于0.09 m,测速精度相当,均在mm/s级;BDS/GPS、GPS/GLONASS/BDS/Galileo组合后,定位和测速精度相较于单系统提升约30%。在库区航段,GPS定位精度严重下降,水平方向为0.6 m;BDS-3与BDS全系统定位精度略有下降;多系统组合后,定位和测速精度受周围环境影响程度较低,与普通航段基本相当。     

HY-2B星载GPS数据质量及简化动力学精密定轨分析

对HY-2B卫星星载GPS数据进行质量检查,分析伪随机脉冲先验值对简化动力学精密定轨的影响。结果发现,在所有时间间隔中,先验标准差为1×10^-8 m/s²时定轨精度最高,最优伪随机脉冲时间间隔为6 min。估计天线相位中心变化（PCV）,分析不同分辨率（10°×10°、5°×5°）PCV模型对定轨结果的影响,并使用载波相位残差、重叠轨道比较和SLR检核对定轨结果进行检验。结果表明,99%以上的历元能观测到4颗以上GPS卫星,数据完整率达到99.65%,L1、L2波段的多路径误差RMS均值分别为15.7 cm、9.5 cm,证明HY2国产接收机性能良好。轨道内符合精度均达到cm级;未加PCV模型时,SLR检核RMS值为27.8 mm,加入10°×10°、5°×5° PCV模型后,SLR检核RMS值分别提高0.9 mm和1.2 mm,说明轨道外符合精度也达到cm级。     

北斗三号卫星天线相位中心改正模型对精密定轨和定位的影响

基于实测数据分析天线相位中心PCO改正模型和观测值频点选择对北斗三号卫星精密定轨和定位的影响。结果表明,基于北斗官方CSNO发布的PCO模型定轨定位表现稍优于IGS协议模型。此外,相较于两者PCO模型差异的影响,B1C/B2a与B1I/B3I观测值频点的选择对精密定位影响更为显著。以IGS B1I/B3I PCO模型为参考,CSNO B1C/B2a PCO模型定位坐标在E、N、U方向上的精度分别提升约5%、13%、14%,可应用于北斗高精度数据处理。     

地磁逐日比异常电磁学成因的进一步分析

基于地磁逐日比异常期间地磁垂直分量日变化幅度变大或变小的统计结果,发现地磁逐日比高值异常是由异常日的地磁垂直分量日变化幅度变小和异常前一天的日变化幅度变大所致。其中,异常日的日变化幅度变小可能是地磁逐日比异常的主要因素,但异常前一天的日变化幅度变大也是异常成立的重要因素。此外,引用前人感应电流假说,结合统计结果进行了机理解释,研究结论进一步证实了前人对该方法的机理推测。     

波普尔科学哲学理论简介

波普尔是当今伟大的哲学家,他发明了科学增长的四段图式:P1→TT→EE→P2,其中P1代表问题,TT表示试探性理论,EE表示试探性排除错误,P2代表新的问题。波普尔对科学哲学有很多贡献,如他否定了培根的归纳法,主张证伪的方法而反对证实的方法。他颠覆了关于真理的概念,反对将理论与真理联系起来,即使是相对真理。他认为,人不能认识真理,只能探索真理,接近真理,并提出"逼真性"与"逼真度"两个概念,从而否定了相对真理与绝对真理这一对矛盾的关系。他提出,科学理论的发展不是一个量变递增的过程,而是新理论取代旧理论的质变过程,是新范式战胜旧范式的科学革命。他认为,可证伪性、可错性是科学的本质特征,同时也是区分科学与非科学的根本标准。传统的认识论将宇宙划分为物质的与精神的两个世界,波普尔认为宇宙是多元的,多层次进化的,其性质是多样的,可分为三个层次或三个世界。波普尔的三个世界理论,用最简洁的语言表述即:物理世界(世界1)、精神世界(世界2)和客观知识世界(世界3)。世界3是人类智力活动的产物,是人造的;另一方面,它同时也是超人类的,即超越了自己的创造者。波普尔石破天惊地提出了科学哲学的许多惊世骇俗的理论,将科学哲学推到了一个崭新的高度,打破了科学界传统的认识论和方法论。他的哲学理论的核心是证伪主义,证伪就是试错,反驳,批判。只有经过证伪的理论(猜测,假说)才能称之为理论。中国科学需要波普尔理论,中国科学上不去,与我们没有证伪思想有很大的关系。我们必须拨乱反正,改弦易辙,采取批判的态度,反驳的方法,敢于试错,这样,中国科学才有希望。     

Quality Control and Evaluation of the Observed Daily Data in the North American Soil Moisture Database

The North American Soil Moisture Database (NASMD) was initiated in 2011 to assemble and homogenize in situ soil moisture measurements from 32 observational networks in the United States and Canada encompassing more than 1800 stations. Although statistical quality control (QC) procedures have been applied in the NASMD, the soil moisture content tends to be systematically underestimated by in situ sensors in frozen soils, and using a single maximum threshold (i.e., 0.6 m3 m-3) may not be sufficient for robust QC because of the diverse soil textures in North America. In this study, based on the in situ soil porosity and North American Land Data Assimilation System phase 2 (NLDAS-2) Noah soil temperature, the simple automated QC method is revised to supplement the existing QC approach. This revised QC method is first validated based on the assessment at 78 of the Soil Climate Analysis Network (SCAN) stations where the manually checked data are available, and is then applied to all stations in the NASMD to produce a more strict quality-controlled dataset. The results show that the revised automated QC procedure can flag the spurious and erroneous soil moisture measurements for the SCAN stations, especially for those located in high altitudes and latitudes. Relative to station measurements in the original NASMD, the quality-controlled data show a slightly better agreement with the manually checked soil moisture content. It should be noted that this quality-controlled dataset may be over-flagged for some valid soil moisture measurements due to potential errors of the soil temperature and soil porosity data, and validation in this study is limited by the availability of benchmark soil moisture data. The updated QC and additional validation will be desirable to boost confidence in the product when high-quality data become available in the future.     

水体中主要阴离子及pH值对双氯芬酸液相色谱定量的影响

双氯芬酸(DCF)是一种常用的非甾体消炎药,随着生产量和使用量的不断增大,其在环境中被频繁检出。DCF能在生物体内富集,对生物具有潜在毒性,已经引起了广大学者的关注。DCF的准确定量是开展其相关研究的基础,在应用液相色谱测试DCF的过程中,通常通过前处理消除样品基质干扰,但关于基质如何干扰DCF测量并没有详细研究。为了满足野外及实验室测试需要,本文针对高效液相色谱-紫外检测DCF过程中,水体中常见的阴离子SO_4~(2-)、Cl~-和NO_3~-,液相色谱流动相组成和水样pH对DCF准确定量的影响展开研究。结果表明:(1)SO_4~(2-)和Cl~-对DCF的最大吸收波长(277 nm)没有影响,但是NO_3~-的存在会使DCF的最大吸收峰发生偏移,产生红移现象,并且使吸光度略微增大;(2)同等条件下,在酸性介质(pH5)中DCF的定量结果比在碱性介质中的低。与碱性介质(pH=7.26)中DCF的峰面积相比,样品在pH=2.01的酸性介质中测得的峰面积减少73.14%,因此在碱性条件下DCF定量更为准确。     

The effects of stress on reactions in the Earth: Sometimes rather mean,usually normal,always important

Stress affects chemical processes on all scales in the Earth but the magnitude of its effect is debated. Here, I give a new synthesis of the theory that describes the effects of stress on chemistry, elaborating upon work in Materials Science which is built from fundamental thermodynamic laws, and show its significance in Earth Science. There are separate but compatible relationships describing what happens (1) at interfaces and (2) within grains. (1) The main chemical effects of stress in the Earth are due to variations in normal stress along grain interfaces and between interfaces with different orientations. For reactions involving diffusion these variations give effects on mineral stability broadly equivalent to pressure changes of (molar volume)/(molar volume change during reaction) × (stress variation). The volume ratio is generally large and so the effects of normal stress variations are always important since all stressed rocks have interfaces supporting different normal stresses. There is no global chemical equilibrium in a stressed system, so reaction kinetics contribute to ongoing evolution until stresses relax: this evolution can include deformation by diffusion creep and pressure solution, possibly with new mineral growth. These effects are relevant for predicting the conditions for reactions involving fluids, such as serpentinite formation and breakdown (relevant for the Earth's volatile cycles) and for other reactions such as ringwoodite breakdown (relevant for understanding the 660 km mantle discontinuity). (2) Within stressed solid solution grains it is not possible to define chemical potentials of all chemical components since one has to be specified as “immobile.” The chemical potential of a “mobile” component such as an exchange vector can be defined. It depends on the “partial molar strain,” a second rank tensor defining the variation in unit cell geometry with composition. In cubic crystals the partial molar strain is isotropic and the chemical potential of a mobile component depends on mean stress. In other crystal systems the partial molar strain is anisotropic and the chemical potential depends on a “weighted” mean stress; orientation as well as magnitude of stress has an influence. I propose “chemical palaeopiezometry”—the possibility of measuring past stress levels via chemistry. Examples show that stress variations in hundreds of MPa to GPa are required to produce 2% variations in composition but high stresses and/or precise chemical analyses will allow this proposal to be tested. High stresses around inclusions and dislocations could be targeted. So, the weighted mean stress inside grains has an effect which is relatively minor although potentially valuable in explaining chemical variations; the normal stress at interfaces plays the main role in chemical processes and its effects are of significant magnitude.     

Th/U ratios in metamorphic zircon

The Th/U ratios of zircon crystals are routinely used to help understand their growth mechanism. Despite the wide application of Th/U ratios in understanding the geological significance of zircon U–Pb ages, the main controls on the Th/U ratio in metamorphic zircon are poorly understood. Here, phase equilibria modelling coupled with solubility expressions for accessory minerals are used to investigate the controls on the Th/U ratios of suprasolidus metamorphic zircon in an average amphibolite facies metapelite composition. We also present a new database of metamorphic Th/U ratios in zircon from Western Australia. Several factors affecting the Th/U ratio are investigated, including the bulk rock concentrations of Th and U, the amount of monazite in the system, and open v. closed system behaviour. Our modelling predicts that the main controls on the Th/U ratio of suprasolidus metamorphic zircon are the concentrations of Th and U in the system, and the breakdown and growth of monazite in equilibrium with zircon. Furthermore, the relative timing of zircon and monazite growth during cooling and melt crystallization has an important role in the Th/U ratio of zircon. Early grown zircon near the peak of metamorphism is expected to have elevated Th/U ratios whereas zircon that grew near the solidus is predicted to have relatively low Th/U ratios, which reflects the coeval growth of monazite during cooling and melt crystallization. Our modelling approach aims to provide an improved understanding of the main controls of Th/U in metamorphic zircon in migmatites and hence better apply this geochemical ratio as a tool to assist in interpretation of the genesis of metamorphic zircon.     

Permo-Triassic high-pressure metamorphism in the central western Korean Peninsula,and its link to Paleo-Tethyan Ocean closure: Key issues revisited

Permo-Triassic high-pressure(HP) mafic granulites, together with the Bibong retrogressed eclogite,preserved along the central western Korean Peninsula provide important insights into the Late Permian to Triassic collisional orogeny in northeast Asia. The metamorphic pressureetemperatureetime(P-T-t)paths of these rocks, however, remain poorly constrained and even overestimated, owing to outdated geothermobarometers and inaccurate isopleth techniques. Here we evaluate the metamorphic Pe T conditions of Triassic HP mafic granulites including those in Baekdong, Sinri and Daepan and the Bibong Triassic retrogressed eclogite in the Hongseong area, and the Permo-Triassic Samgot mafic granulite in the Imjingang Belt of the central western Korean Peninsula through the application of modern phase equilibria techniques. The Baekdong and Samgot mafic granulites and the Bibong retrogressed eclogite yield a range of 12.0 -16.0 kbar and 800 -900℃, representing HP granulite facies conditions. The Sinri and Daepan granulites from the Hongseong area show relatively lower grade metamorphic conditions between HP granulite and normal granulite facies, and are characterized by sub-isothermal decompression during exhumation. The similarities in the metamorphic ages and the post-collisional igneous activity from the central western Korean Peninsula indicate that the Triassic ages represent the retrograde stage of the metamorphic Pe T paths. In contrast, the Late Permian metamorphic ages, which are older than protolith ages of the post-collisional igneous rocks, correspond to the possible prograde stage of metamorphism. The P-T-t paths presented in this paper, together with the metamorphic ages and post-orogenic igneous events reported from these areas suggest trace of the subduction, accretion and exhumation history, and indicate a tectonic linkage among the northeast Asian continents during the Paleo-Tethyan Ocean closure.