非饱和土毛细滞回内变量模型的修正

土-水特征关系是基质吸力和含水率之间关系。在反复干湿循环路径下土-水特征曲线呈现出毛细滞回特性。基于毛细滞回内变量理论和传统的土-水特征关系经验模型,提出了能模拟在任意干湿循环路径下土-水特征关系的修正模型。该模型比原模型增加了一个可逆参数,考虑了含水率的可逆变化,使扫描线在靠近边界线的时候斜率不会无限大,同时保留了原模型精度。通过与文献中的试验结果进行比较,修正模型可以更好地模拟非饱和土的土-水特征关系的循环滞回特性,并讨论了可逆参数的确定方法。     

塔北雅克拉地区油气藏上方"烟筒效应”的磁学与矿物学证据

依据位于塔北雅克拉油气田内的沙田井、沙七井、沙十五井及位于油水边界的沙六井岩屑与岩心的磁学（包括磁化率、磁滞回线及热磁分析）与矿物学（包括重矿物、电子探针及扫描电子显微镜）的综合分析测试结果，获得了已知油气井内生、储、盖层与地表第四纪土壤中与烃运移相关的蚀变矿化作用（即烟筒效应）的物质证据．本区位于油气藏上方的蚀变矿化作用以磁铁矿化与菱铁矿化作用为主；而位于油水边界处的沙六井则以磁铁矿化与黄铁矿化为主．随着地层深度的减小，虽然“烟筒效应”的强度明显减北，但在地表仍可检测到明显的磁学与矿物学异常．综合磁学与矿物学研究结果表明，本区岩屑中发现的球粒状磁铁矿是“烟筒效应”的产物，它是与烃运移相关的次生低温磁性矿物重要的形貌特征     

Concentration–discharge relationships describe solute and sediment mobilization,reaction, and transport at event and longer timescales

Concentration–discharge (C‐Q) relationships reflect material sources, storage, reaction, proximity, and transport in catchments. Differences in hydrologic pathways and connectivity influence observed C‐Q patterns at the catchment outlet. We examined solute and sediment C‐Q relationships at event and interannual timescales in a small mid‐Atlantic (USA) catchment. We found systematic differences in the C‐Q behaviour of geogenic/exogenous solutes (e.g., calcium and nitrate), biologically associated solutes (e.g., dissolved organic carbon), and particulate materials (e.g., total suspended solids). Negative log(C)–log(Q) regression slopes, indicating dilution, were common for geogenic solutes whereas positive slopes, indicating concentration increase, were common for biologically associated solutes. Biologically associated solutes often exhibited counterclockwise hysteresis during events whereas geogenic solutes exhibited clockwise hysteresis. Across event and interannual timescales, solute C‐Q patterns are linked to the spatial distribution of hydrologic sources and the timing and sequence of hydro‐biogeochemical source contributions to the stream. Groundwater is the primary source of stormflow during the earliest and latest stages of events, whereas precipitation and soil water become increasingly connected to the stream near peakflow. This sequence and timing of flowpath connectivity results in dilution and clockwise hysteresis for geogenic/exogenous solutes and concentration increase and counterclockwise hysteresis for biologically associated solutes. Particulate materials demonstrated positive C‐Q slopes over the long‐term and clockwise hysteresis during individual events. Drivers of particulate and solute C‐Q relationships differ, based on longitudinal and lateral expansion of active channels and changing shear stresses with increasing flows. Although important distinctions exist between the drivers of solute and sediment C‐Q relationships, overall solute and sediment C‐Q patterns at event and interannual timescales reflect consistent catchment hydro‐biogeochemical processes.     

Transpiration and subsurface controls of streamflow recession characteristics

In headwater catchments, streamflow recedes between periods of rainfall at a predictable rate generally defined by a power–law relationship relating streamflow decay to streamflow. Research over the last four decades has applied this relationship to predictions of water resource availability as well as estimations of basin‐wide physiographic characteristics and ecohydrologic conditions. However, the interaction of biophysical processes giving rise to the form of these power–law relationships remains poorly understood, and recent investigations into the variability of streamflow recession characteristics between discrete events have alternatively suggested evapotranspiration, water table elevation, and stream network contraction as dominant factors, without consensus. To assess potential temporal variability and interactions in the mechanism(s) driving streamflow recession, we combine long‐term observational data from a headwater stream in the southern Appalachian Mountains with state and flux conditions from a process‐based ecohydrologic model. Streamflow recession characteristics are nonunique and vary systematically with seasonal fluctuations in both rates of transpiration and watershed wetness conditions, such that transpiration dominates recession signals in the early growing season and diminishes in effect as the water table elevation progressively drops below and decouples with the root zone with topographic position. As a result of this decoupling, there exists a seasonal hysteretic relationship between streamflow decay and both evapotranspiration and watershed wetness conditions. Results indicate that for portions of the year, forest transpiration may actively compete with subsurface drainage for the same water resource that supplies streamflow, though for extended time periods, these processes exploit distinct water stores. Our analysis raises concerns about the efficacy of assessing humid headwater systems using traditional recession analysis, with recession curve parameters treated as static features of the watershed, and we provide novel alternatives for evaluating interacting biological and geophysical drivers of streamflow recession.     

The influence of fire and permafrost on sub‐arctic stream chemistry during storms

Permafrost and fire are important regulators of hydrochemistry and landscape structure in the discontinuous permafrost region of interior Alaska. We examined the influence of permafrost and a prescribed burn on concentrations of dissolved organic carbon (DOC), dissolved organic nitrogen (DON) and other solutes ( , Ca²⁺, K⁺, Mg²⁺, Na⁺) in streams of an experimentally burned watershed and two reference watersheds with varying extents of permafrost in the Caribou–Poker Creeks Research Watershed in interior Alaska. The low‐permafrost watershed has limited permafrost (3%), the high‐permafrost watershed has extensive permafrost (53%), and the burn watershed has intermediate permafrost coverage (18%). A three end‐member mixing model revealed fundamental hydrologic and chemical differences between watersheds due to the presence of permafrost. Stormflow in the low‐permafrost watershed was dominated by precipitation and overland flow, whereas the high‐permafrost watershed was dominated by flow through the active layer. In all watersheds, organic and groundwater flow paths controlled stream chemistry: DOC and DON increased with discharge (organic source) and base cations and (from weathering processes) decreased. Thawing of the active layer increased soil water storage in the high‐permafrost watershed from July to September, and attenuated the hydrologic response and solute flux to the stream. The FROSTFIRE prescribed burn, initiated on 8 July 1999, elevated nitrate concentrations for a short period after the first post‐fire storm on 25 July, but there was no increase after a second storm in September. During the July storm, nitrate export lagged behind the storm discharge peak, indicating a flushing of soluble nitrate that likely originated from burned soils. Copyright © 2006 John Wiley & Sons, Ltd.     

Hydrological and catchment controls on event-scale dissolved organic carbon dynamics in boreal headwater streams

Hydrological events transport large proportions of annual or seasonal dissolved organic carbon (DOC) loads from catchments to streams. The timing, magnitude and intensity of these events are very sensitive to changes in temperature and precipitation patterns, particularly across the boreal region where snowpacks are declining and summer droughts are increasing. It is important to understand how landscape characteristics modulate event-scale DOC dynamics in order to scale up predictions from sites across regions, and to understand how climatic changes will influence DOC dynamics across the boreal forest. The goal of this study was to assess variability in DOC concentrations in boreal headwater streams across catchments with varying physiographic characteristics (e.g., size, proportion of wetland) during a range of hydrological events (e.g., spring snowmelt, summer/fall storm events). From 2016 to 2017, continuous discharge and sub-daily chemistry grab samples were collected from three adjacent study catchments located at the International Institute for Sustainable Development-Experimental Lakes Area in northwestern Ontario, Canada. Catchment differences were more apparent in summer and fall events and less apparent during early spring melt events. Hysteresis analysis suggested that DOC sources were proximal to the stream for all events at a catchment dominated by a large wetland near the outlet, but distal from the stream at the catchments that lacked significant wetland coverage during the summer and fall. Wetland coverage also influenced responses of DOC export to antecedent moisture; at the wetland-dominated catchment, there were consistent negative relationships between DOC concentrations and antecedent moisture, while at the catchments without large wetlands, the relationships were positive or not significant. These results emphasize the utility of sub-daily sampling for inferring catchment DOC transport processes, and the importance of considering catchment-specific factors when predicting event-scale DOC behaviour.     

Cavity expansion in unsaturated soils exhibiting hydraulic hysteresis considering three drainage conditions

Cavity expansion theory assists in the interpretation of in situ tests including the cone penetration test and pressuremeter test. In this paper, a cavity expansion analysis is presented for unsaturated silty sand exhibiting hydraulic hysteresis. The similarity technique is used in the analysis. The soil stress–strain behaviour is described by a bounding surface plasticity model. Results of oedometric compression tests, isotropic compression tests and triaxial shear tests for both saturated and unsaturated states are used to calibrate the model. The void ratio, suction, degree of saturation and effective stress are fully coupled in the analysis. The influence of where the initial hydraulic state is located on the soil–water characteristic curve on the cavity wall pressure is investigated and found to be significant. Also, the effects of three different drainage conditions (constant suction, constant moisture content and constant contribution of suction to the effective stress) on cavity wall pressure are studied. It is found that the drainage condition in which the contribution of suction to the effective stress is constant offers a good approximation to the other two. This may simplify interpretation of in situ tests. When testing occurs quickly, meaning a constant moisture content condition prevails, a constant contribution of suction condition can be assumed without loss of significant accuracy. The contribution of suction assumed in the interpretation can be taken as being equal to the in situ value, although this discovery may not be applicable to all soil types, constitutive models and soil–water characteristic curves. Copyright © 2015 John Wiley & Sons, Ltd.     

Particulate carbon and nitrogen dynamics in a headwater catchment in Northern Thailand: hysteresis,high yields,and hot spots

Rivers of South and Southeast Asia disgorge large suspended sediment loads, reflecting exceptionally high rates of erosion promoted by natural processes (tectonic and climatic) and anthropogenic (land‐use change) activities that are characteristic of the region. While particulate carbon and nitrogen fluxes have been characterized in some large Asian rivers, less is known about the headwater systems where much sediment and organic material are initially mobilized. This study, conducted in the 74‐km² Mae Sa Experimental Catchment in northern Thailand, shows that the Sa River is an important source for particulate organic carbon (POC) and particulate organic nitrogen (PON) transported to larger river systems and downstream reservoirs. However, the yields during three years of investigation varied greatly: 5.0–22.3 Mg POC km^?2 y^?1 and 0.48–2.02 Mg PON km^?2 y^?1. The 22.3 Mg POC km^?2 y^?1 yield is the highest reported for any river on the Asian continent. Stream samples collected during 12 storms showed that almost 3% of the total suspended solid load is POC 0.7 µm to 2.0 mm in size. This percentage is higher than other values for most large rivers on the continent. Further, we documented a strong pulse hysteretic behaviour in the stream, whereby peak fluxes of POC and PON are often delayed (anticlockwise hysteresis) or accelerated (clockwise hysteresis) relative to stream flow peaks (or are complex), complicating the prediction of storm‐based or annual particulate carbon and nitrogen fluxes. Stream turbidity and total suspended sediment are reasonable proxies for POC and PON concentrations, while stream discharge is not a good predictor variable. Observed C:N ratios for measured particulate samples range from 3 to 83, with the high‐end values likely associated with fresh (non‐decomposed) vegetative material greater than 2 mm in diameter. The C:N ratio (weighted based on three sediment sizes) for 12 events ranges from 7.5 to 15.3. These modest values reflect the relatively low C:N ratios for small size fractions (0.7–0.63 µm) that comprise 50–90% of the TSS load in the events. Overall, organic material <0.63 µm contribute about 75% of the total POC load and 80% of the PON load. The annual C:N ratio for the river is approximately 10–11. Collectively, our findings indicate the occasionally high yields make the Sa River—and potentially other similar headwater rivers—a hot spot for POC and PON transported to downstream water bodies. Complex hysteresis patterns and high year‐to‐year variability hinders our ability to calculate and predict these yields without continuous, automated monitoring of discharge and turbidity. Copyright © 2016 John Wiley & Sons, Ltd.     

Suspended sediment dynamics associated with snowmelt runoff in a small mountain stream of Lake Tahoe (Nevada)

The Lake Tahoe basin is experiencing an environmental decline that is partly due to sediment intakes from its tributaries. Many studies have estimated suspended sediment loads in these streams with a discrete sampling programme by collecting water samples and using a rating technique. However, the relationship between stream discharge and suspended sediment concentration (SSC) in these tributaries is known to differ during the rising and falling limbs of the snowmelt‐dominated hydrograph. Because of this hysteresis effect, sediment rating curves are poor predictors of suspended sediment dynamics in the stream. In this study, suspended sediment transport was investigated using a turbidity meter to provide a continuous record of sediment concentration during the snowmelt period. Hysteresis in suspended sediment transport was also investigated and is quantified with an H index, which is the ratio of the areas under the curve at different stages of the hydrograph. The temporal lag between the peak of SSC and the peak of stream discharge was quantified using cross‐correlation analysis. For almost all events, SSCs were higher during the rising limb of the hydrograph for a given discharge, with SSC peaks occurring before discharge peaks, resulting in clockwise hysteresis (H > 1). The H indices increased (looser hysteresis loop) as the availability of sediments increased and as the lag between peaks in SSC and discharge was larger. A restriction of the proposed H index was that it could only be computed when stream discharge increased by more than 30% during a melt event. Copyright © 2005 John Wiley & Sons, Ltd.