西藏谢通门县邦弄含铁电英岩脉的地质特征及成因分析

文章介绍了西藏谢通门县邦弄地区含铁电英岩脉的地质特征.电英岩脉的延伸方向大致与区内的断层平行,围岩为中粒斑状角闪黑云二长花岗岩.电英岩脉中见有不同程度的铁矿化,共有23条矿化较好的含铁电英岩脉.含铁电英岩脉中矿石矿物为赤铁矿(镜铁矿),脉石矿物为石英、电气石及少量的白云母和长石.矿石具叶片状、鳞片状结构,块状构造,矿石...     

赣南崇义淘锡坑钨矿床氢、氧、硫同位素地球化学研究

赣南崇义县淘锡坑钨矿位于南岭东西向构造带东段与武夷山NE-NNE向构造带南段的复合部位,属于以石英脉型黑钨矿为主的钨多金属矿床.文章通过氧、氧、硫同位素地球化学特征的研究,探讨了淘锡坑钨矿成矿流体的来源及演化.研究结果显示:δD值介于-77‰～-45‰之间;石英矿物的δ18O值介于+7.3‰～+12.2‰之间,计算给出...     

The Impact of Aqueous Medium on Gas Yields and Kinetic Behaviors of Hydrogen Isotope Fractionation during Organic Matter Thermal Degradation

In order to recognize the impact of aqueous medium on gas yields and the kinetic behaviors of hydrogen isotope fractionation during organic matter thermal degradation, the gold tube apparatus was used to conduct thermal simulation experiments by mixing the nC18 with the water of different properties and proportions. The yields of natural gas components, the relation among hydrogen isotope composition of each component and the experimental temperatures vs. heating rates have been obtained, and the results indicate that under the higher temperature conditions, the hydrous experiment has obvious impact on gas yields, such as when more water is added, higher amounts of hydrocarbon gas and H2 are yielded, and the existence of water obviously prolongs the temperature interval with the existence of heavy hydrocarbon gas. It also shows that the hydrogen isotope of hydrocarbon gas generated by the hydrous experiment is obviously lighter than that generated by the anhydrous experiment, and with the increasing amount of added water, the δD value of hydrocarbon gas gradually decreases. Compared with gas yields, the variation of δD value is more sensitive to aqueous medium in the thermal simulation experiment. However, compared with the amount of the added water, the aqueous medium property has smaller impact on the gas yields, which still shows the inherit effect on hydrogen isotope composition of aqueous medium. Through the model simulation and the isotope fractionation behavior analysis, it is validated that the hydrogen isotope fractionation process can be well described by the chemical kinetic model. The difference of reaction fraction of normal methane and D-containing methane is large, corresponding to the same activation energy. The content of normal methane is obviously higher in the part with lower activation energy, while the content of D-containing methane is higher in the part with higher activation energy. Therefore, it will result in larger hydrogen isotope fractionation amplitude, and the δD values will be more sensitive to the variation of maturity. Meanwhile, the average activation energy of methane generation from nC18 in the hydrous experiment is higher than that in the anhydrous experiment, and the greater amount of added water, the larger the average activation energy of methane generation reaction. This has laid foundation for its exploratory application in the study of gas reservoir forming history and the gas-source correlation, which indicates the research and application prospects in this orientation.     

Water Role and Its Influence on Hydrogen Isotopic Composition of Natural Gas during Gas Generation

In order to discuss the role and influence of water during the generation of natural gas, the participation mechanism of water during the evolution of organic matter and its influences were summarized. In addition, we carried out an anhydrous cracking experiment of oil extracted from the Feixianguan Formation source rock in a closed system, which led to the establishment of the kinetic models for describing carbon and hydrogen isotopic fractionation during gas generation from organic matter. The models were calibrated and then applied to the northeastern Sichuan Basin. By combining a series of gas generation experiments from octadecane pyrolysis without water or with distilled water in varying mass proportions, several results were proved: (1) the hydrogen isotopic composition of natural gas becomes lighter with the participation of formation water; (2) we can quantitatively study the hydrogen isotopic fractionation with the kinetic model for describing carbon isotopic fractionation; (3) more abundant and reliable geological information can be obtained through the combined application of carbon and hydrogen isotopic indices.     

古气候变化与地下热水中氢氧稳定同位的关系

关中盆地地下热水中氢氧稳定同位素的研究表明：研究区地下热水中氢氧稳定同位素组成变化与当地古气候变化具有良好的对应关系,古气候变化直接影响了地下热水接受补给时的氢氧稳定同位素组成。研究区地下热水的补给为更新世前古代大气降水。大约在8.2～10.2 kaB.P.和18.1～19.2 kaB.P.这两个时间段,可能是由于当时温度较低导致关中盆地地下热水补给偏少;关中盆地地下热水的补给过程受古气候的变化影响呈现非等速补给特征,可能存在一定的古地下水形成期。     

溶质类型与矿化度对土壤水分扩散率的影响

以甘肃省秦安县果园石灰性土壤为研究对象,采用水平土柱入渗法,探讨了不同矿化度下(lg/L、3g/L、5g/L、10g/L)的三种钠盐(Nacl、Na2SO4和Na2CO3)对石灰性土壤水分扩散率的影响.结果表明:在水盐复合迁移体系中盐分与水分迁移具有不同步性,影响不同步性的因子与盐分类型有很大关系.NaCl对水分移动速...     

Implications of trace element composition of syntaxial quartz cements for the geochemical conditions during quartz precipitation in sandstones

A petrographic investigation revealed polyphase quartz cementation in the Finefrau Sandstone (Upper Carboniferous, Western Germany) and the Solling Sandstone (Lower Triassic, Central Germany). Three different cements could be distinguished in each sandstone based on their cathodoluminescence and trace element composition. The first quartz generation is suggested to have been formed during eogenesis due to dissolution and replacement of feldspar. The mesogenetic paragenesis comprises two generations of quartz and illite, which are accompanied by albite in the Solling Sandstone. Sharp luminescence zoning in quartz overgrowths points to distinct episodes of cementation in both sandstones. Significant amounts of Al, Li and H and traces of Ge and B have been detected in the quartz overgrowths. The Al‐content of the quartz cements in the Finefrau Sandstones exceeds that in the quartz cements in the Solling Sandstone by a factor of five. It is suggested that this compositional variation reflects the conditions in the pore‐water, such as temperature and pH. The Al‐concentration is generally correlated to the Li‐content with the exception of the latest quartz generation in the Finefrau Sandstones which is also most enriched in trace elements. The ratio of Li/Al varies between 0·11 and 0·25 in the two sandstones. The Li/H‐ratio, which ranges from 0·12 to 0·3, is controlled by the activity ratio of Li and H in the pore fluid. Clay minerals are the most important source for Li and high salinities favour the mobilization of Li during diagenesis. Thus, a relatively low salinity and low pH are responsible for the low Li/H‐ratio in the Finefrau Sandstone, while high salinity and neutral to alkaline pH results in a high Li/H‐ratio for the Solling Sandstone. The Ge‐contents are generally near the average of detrital quartz and indicate that pressure dissolution is a major source for quartz cementation. Different chemical compositions of distinct quartz generations indicate changes in the physico‐chemical conditions and point to mobilization of silica from different sources (for example, pressure solution and clay mineral transformations).     

北京西山鹫峰地区氢氧稳定同位素特征分析

以北京西山鹫峰低山区为研究对象,通过对降水、土壤水、泉水氢氧同位素的变化特征分析,研究低山区的降水-土壤水-泉水的转化关系。研究结果表明:该地区的雨季降水线与北京地区的地区降水线有明显区别,斜率和截距偏小;随降雨的进行氢氧同位素特征有时程变化和降雨量效应,而降雨的时程变化也对土壤水的同位素特征产生了影响;土壤水分同位素分布特征相对集中,蒸发线方程的斜率和截距相对于当地大气降水线和雨季降水线都偏小,栓皮栎混交林土壤水对于小雨量次降雨事件反应不敏感,而侧柏林的土壤水分运动较栓皮栎混交林快,说明林分类型和土壤特性对不同水体之间的转化有影响;泉水的同位素特征比较稳定,主要分布在地区降水线的右下方与雨季降水线的交点附近;不同水体中降雨的δD、δ18O变化范围较大,土壤水次之,泉水变化最小;而沿着大气降水-土壤水-地下水(泉水)这一水循环路径,水体中的δD、δ18O值总体上呈下降趋势。     

Volatile emissions and gas geochemistry of Hot Spring Basin,Yellowstone National Park,USA

We characterize and quantify volatile emissions at Hot Spring Basin (HSB), a large acid-sulfate region that lies just outside the northeastern edge of the 640 ka Yellowstone Caldera. Relative to other thermal areas in Yellowstone, HSB gases are rich in He and H₂, and mildly enriched in CH₄ and H₂S. Gas compositions are consistent with boiling directly off a deep geothermal liquid at depth as it migrates toward the surface. This fluid, and the gases evolved from it, carries geochemical signatures of magmatic volatiles and water–rock reactions with multiple crustal sources, including limestones or quartz-rich sediments with low K/U (or ^40?Ar/^4?He). Variations in gas chemistry across the region reflect reservoir heterogeneity and variable degrees of boiling. Gas-geothermometer temperatures approach 300 °C and suggest that the reservoir feeding HSB is one of the hottest at Yellowstone. Diffuse CO₂ flux in the western basin of HSB, as measured by accumulation-chamber methods, is similar in magnitude to other acid-sulfate areas of Yellowstone and is well correlated to shallow soil temperatures. The extrapolation of diffuse CO₂ fluxes across all the thermal/altered area suggests that 410 ± 140 t d^− 1 CO₂ are emitted at HSB (vent emissions not included). Diffuse fluxes of H₂S were measured in Yellowstone for the first time and likely exceed 2.4 t d^− 1 at HSB. Comparing estimates of the total estimated diffuse H₂S emission to the amount of sulfur as SO₄²⁻ in streams indicates ~ 50% of the original H₂S in the gas emission is lost into shallow groundwater, precipitated as native sulfur, or vented through fumaroles. We estimate the heat output of HSB as ~ 140–370 MW using CO₂ as a tracer for steam condensate, but not including the contribution from fumaroles and hydrothermal vents. Overall, the diffuse heat and volatile fluxes of HSB are as great as some active volcanoes, but they are a small fraction (1–3% for CO₂, 2–8% for heat) of that estimated for the entire Yellowstone system.     

Hydrogen isotope composition of natural gases from the Tarim Basin and its indication of depositional environments of the source rocks

By measuring carbon and hydrogen isotope compositions for C1, C2 and C3 of 74 gas samples, natural gases from the Tarim Basin can be divided into six groups on the basis of their origins: (1) coal-type gas derived from coal measures; (2) coal-type gas generated from the T-J lacustrine mudstones; (3) oil-type gas derived from the Cambrian and low Ordovician marine source rocks; (4) oil-type gas from the source rocks deposited in the marine-transitional facies; (5) mixing gas between gas derived from the Carboniferous transitional source rocks and the Mesozoic humic gas, and (6) mixing gases of thermal genetic gas and little deep gas in the Southwest depression of the Tarim Basin. The δ D values of methane in natural gases originating from different type kerogens are affected by both palaeo-environments of the source rock formation (kerogen types) and thermal maturity, with sedimentary environment (kerogen type) as the main controlling factor. Under the similar thermal maturity, the hydrogen isotope composition of methane is more enriched in deuterium in marine environments than lacustrine one. With the increase of thermal maturity and the increase of carbon atomic numbers of gaseous alkanes, the hydrogen isotopes become enriched in deuterium. The δ D values of ethane and propane (δ D2, δ D3) are controlled mainly by thermal maturity and to a lesser degree by sedimentary environment of the source rock formation. The partial reversal of hydrogen isotopes for gaseous alkanes would be related to the microbial oxidation, mixing of sapropelic and humic gases and / or mixing of gases from similar kerogen sources with various thermal maturities. In the oil-type gas, the sulfate reduction reaction would result in the reversed order of δ D1 and δ D2 (e.g. δ D1>δ D2).