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111.
112.
An infrared routine has been developed to estimate the aliphatic portion of kerogen carbon in sedimentary rocks. The procedure does not require isolation of the organic matter and is based on a computer-assisted determination of global band areas in the region of the aliphatic carbon-hydrogen stretching vibrations around 2900cm−1. From these integrated absorptions the amount of aliphatic carbon Cal (mg of aliphatic carbon per gram of solvent-extracted rock) is calculated by means of a calibration with model rocks. Carbonate overtones which interfere in the case of limestones are eliminated by comparison to a CaCO3 standard.The method has been applied to rocks containing kerogens of different types and maturities at TOC levels of 0.5 to 12%. The aliphatic carbon concentrations range from 0.5 to 60mg·g−1 and correlate reasonably well with the residual genetic potentials of the rocks as measured by S2 values from Rock-Eval pyrolysis. The ratio S2/Cal is found to decrease with burial depth reflecting a maturity enhanced conversion of aliphatic carbon to fixed aromatic carbon under Rock-Eval conditions. 相似文献
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Wang Hongmei Ma Xiangru Liu Deng Yang Xiaofen Li Jihong 《Frontiers of Earth Science》2007,1(4):399-404
Understanding the dynamics of organic matter in modern marine water columns greatly favors the geobiological evaluation of
hydrocarbon source rocks. Biolipids could make great contribution to petroleum hydrocarbons due to their comparable chemical
components and the slightly refractory characteristics of biolipids during the microbial/thermal degradation. A variety of
environmental factors such as temperature, CO2 and salinity could affect the biochemical contents in microorganisms. As a result, microorganisms living in a changing environmental
condition might have a different contribution to the petroleum formation. Organic carbon flux is shown to bear a positive
correlation with the primary productivity only within a certain range of biomass volumes in a specific biohabitat. Furthermore,
organic matter is degraded much quickly in a water column with oxic conditions. Therefore, the anoxic condition, along with
the enhanced biological productivity, would be one of the significant factors in the formation of high-quality hydrocarbon
source rocks. The formation of biofilms and microbial mats favors the preservation of sedimentary organic matter by decreasing
the degradation rate of organic matter. Identification of biofilms and microbial mats in sedimentary rocks will thus greatly
help to understand the depositional processes of organic matter finally preserved in hydrocarbon source rocks.
__________
Translated from Earth Science—Journal of China University of Geosciences, 2007, 32(6): 748–754 [译自: 地球科学—中国地质大学学报 相似文献
115.
沉积有机质激光热裂解色谱质谱探针分析技术的尝试及其前景探讨 总被引:1,自引:1,他引:1
激光热裂解-色谱-质谱分析方法具有从技术层面上融合分子地球化学方法和有机岩石学方法的潜能。通过抚顺煤镜质组分和树脂体的研究实例,介绍了激光热裂解-色谱-质谱探针分析的基本原理及测试方法。抚顺煤显微组分的微区热裂解产物特征中,镜质组和树脂体热解产物的正烷烃、烷基萘和四氢化萘的总体面貌相似,但树脂体中正烷烃含量较低,而烷基四氢化萘明显较高,这可能反映显微组分形成过程中发生过低分子烃类在各显微组分之间的混合作用。除此之外,还把激光热裂解-色谱-质谱探针技术与传统的分子地球化学方法、有机岩石学方法进行比较。探讨了激光热裂解-色谱-质谱探针技术的应用前景以及尚待解决的技术问题。落射到样品表面的激光束能量(温度)和控制和激光辐射时间的,激光束斑大小、热解产物量、色谱-质谱检验灵敏度极限三者关系等,都是限制新技术应用的技术问题。 相似文献
116.
Harris J. R. Wilkinson L. Heather K. Fumerton S. Bernier M. A. Ayer J. Dahn R. 《Natural Resources Research》2001,10(2):91-124
A Geographic Information System (GIS) is used to prepare and process digital geoscience data in a variety of ways for producing gold prospectivity maps of the Swayze greenstone belt, Ontario, Canada. Data used to produce these maps include geologic, geochemical, geophysical, and remotely sensed (Landsat). A number of modeling methods are used and are grouped into data-driven (weights of evidence, logistic regression) and knowledge-driven (index and Boolean overlay) methods. The weights of evidence (WofE) technique compares the spatial association of known gold prospects with various indicators (evidence maps) of gold mineralization, to derive a set of weights used to produce the final gold prospectivity map. Logistic regression derives statistical information from evidence maps over each known gold prospect and the coefficients derived from regression analysis are used to weight each evidence map. The gold prospectivity map produced from the index overlay process uses a weighting scheme that is derived from input by the geologist, whereas the Boolean method uses equally weighted binary evidence maps.The resultant gold prospectivity maps are somewhat different in this study as the data comprising the evidence maps were processed purposely differently for each modeling method. Several areas of high gold potential, some of which are coincident with known gold prospects, are evident on the gold prospectivity maps produced using all modeling methods. The majority of these occur in mafic rocks within high strain zones, which is typical of many Archean greenstone belts. 相似文献
117.
118.
沥青质傅里叶变换红外光谱 (FT IR)分析及其在有机地球化学研究中的应用 总被引:5,自引:0,他引:5
沥青质傅里叶变换红外光谱(FT-IR)分析可以反映出其分子结构上的特征,红外吸收因子Z[I(1380cm^-1)/I(720cm^-1)]能指示不同来源沥青质的母质类型;吸收因子Y[I(1600cm^-1)/I(1450cm^-1)]可以较好地讨论沥青质的成熟度演化状况;沥青质的红外研究认为,所有的沥青质都具有较好的再生烃潜力,其中Ⅲ型母质来源的沥青质具有较好的再生气潜力。而Ⅰ和Ⅱ型母质来源的沥青质具有高的再生油潜力。 相似文献
119.
吐哈盆地侏罗系层序地层学研究 总被引:13,自引:3,他引:13
吐哈盆地侏罗系是一个盆地充填层序 (一级层序 ),包括 4个构造层序 (二级层序 ),分别与侏罗纪湖盆的 4个演化阶段 (稳定沉降阶段、短期收缩阶段、扩张阶段和萎缩阶段 )相对应,其中又分为 13个 (三级 )层序。与海相地层不同的是,本区识别出了 4种层序边界类型 (A型、B型、C型和D型 ),其对应的层序本文分别称之为冲积层序、淹没层序、类Ⅰ型层序和类Ⅱ型层序。冲积层序形成于构造剧烈抬升时的盆地萎缩阶段,淹没层序形成于构造沉降迅速时的盆地扩张阶段. 相似文献
120.