鞍本地区鞍山群变质矿物及变质作用

鞍本地区鞍山群变质岩出露区可分为鞍山、辽阳、本溪三个小区。所有的变质岩均属角闪岩相,从西向东,变质程度递增。三个小区最先出现的特征变质矿物分别是铁铝榴石、十字石和夕线石。退化变质作用由西向东递减,在东-西鞍山矿区已退变为绿片岩相,在绿泥片岩中普通角闪石仅作为残留矿物出现在绿泥石的核心。鞍山小岭子矿区有紫苏辉石、红柱石和尖晶石组合,它们是燕山期花岗岩围岩中的接触变质矿物。     

伊朗珊瑚在新疆的发现

本文描述的伊朗珊瑚(Iranophyllum)是1971和1984年第一区调队在新疆南部昆仑山下二叠统黄羊岭群和叶桑岗组采集的,共4新种和1未定种,名单是:Iranophyllum xinjiangense(sp.nov).Ir.kunlunense(sp.nov.),Ir.clisiophylloides(sp.nov.),Ir.neoclisio-phylloides(sp.nov.),Ir.sp.A等.与其共生的有(?)类:Sumatrina annae,Verbeekina of.verbeeki,paraverbeekina of.umbi-lcata,Polydiexodina sp.,Yangchienia sp.,Neo-misellina sp.,parafusulina sp.,Chusenella sp.,Afghanella?sp.,腕足:Neospir-ifer sp.,Martinia sp.,Stenoscisma sp.,Waagenoconcha sp.,四射珊瑚:Amplexo-carinia sp.,Huangophyllum sp.,Lytvolasma sp.,plerophyllum sp.等.因此,含Ira-nophyllom的黄羊岭群和叶桑岗组应属同一层位,它们与新疆喀喇昆仑地区空喀山口组、西藏阿里地区龙格组及文部组是相当的.     

微波消解-双浊点萃取ICP-MS测定地球化学样品中的痕量铂钯钌铑

传统浊点萃取技术是将待测元素富集在黏稠的表面活性剂相中,溶液的黏度会对等离子体检测信号产生影响,通常使用甲醇作为稀释剂降低有机相黏度,有机成分也对等离子体的稳定性产生影响,同时有机物在进样管路上的吸附还会提高待测元素的记忆效应,因而限制了ICP-MS在浊点萃取中的应用。本文建立了双浊点萃取技术ICP-MS测定地球化学样品中铂钯钌铑的分析方法。样品用微波消解处理后,以DDTP为螯合剂,Triton X-114为表面活性剂,对消解溶液第一次浊点萃取,再在有机相中加入硝酸,通过加热完成第二次浊点萃取,使铂钯钌铑由有机相进入水相,铂钯钌铑的富集因子分别为45、33、18和35,高于单次浊点萃取的富集因子,ICP-MS检出限分别为0.05、0.02、0.10和0.03 μg/L。本方法通过两次浊点萃取过程实现了基体复杂的地球化学样品中痕量铂族元素的同时富集,提高了ICP-MS的稳定性。     

不同TEC分布模式对星载SAR立体定位精度的影响及校正

基于SAR成像模型和R-D定位模型,分析了电离层对星载SAR立体定位精度的影响,提出了相应的校正方法,并进行了仿真实验。实验表明对于特定波长的SAR信号,不同TEC分布模式组合对SAR立体像对定位精度的影响不同,校正效果也不同:当两幅影像对应的TEC分布均匀且大小相同时,电离层对SAR立体定位精度的影响小到可以忽略;当两幅影像由于拍摄季节不同导致TEC不同时,电离层影响很大,特别是距离向精度,其影响程度与两幅影像对应的TEC差值正相关,此时定向参数精化法校正效果很好;当电离层发生扰动时,电离层影响随着扰动程度的增大而增大,定向参数精化法有一定效果,但当电离层扰动很大时,校正效果明显减弱,还需要通过斜距直接校正法等其他方法予以校正。     

Application of Maximum Entropy Distribution to the Statistical Properties of Wave Groups

The new distributions of the statistics of wave groups based on the maximum entropy principle are presented.The maximum entropy distributions appear to be superior to conventional distributions when applied to a limited amount of information.Its applications to the wave group properties show the effectiveness of the maximum entropy distribution.FFT filtering method is employed to obtain the wave envelope fast and efficiently.Comparisons of both the maximum entropy distribution and the distribution of Longuet-Higgins(1984) with the laboratory wind-wave data show that the former gives a better fit     

Uptake of platinum group elements by the marine macroalga, Ulva lactuca

Uptake of environmentally relevant platinum group elements (PGE) by the marine macroalga, Ulva lactuca, has been studied. Removal of nM concentrations of Rh(III), Pd(II) and Pt(IV) added to filtered sea water appeared to proceed via pseudo-first-order kinetics, with respective forward rate constants of either 0.0039 or 0.0042 h^− 1, 0.0058 or 0.0096 h^− 1 and 0.0017 or 0.0032 h^− 1, depending on whether an irreversible or reversible reaction was invoked. The (quasi-) equilibrium distribution coefficients, derived from linear fits to uptake (sorption) isotherms, were about 1400, 900 and 350 mL g^− 1 on a dry mass basis for Rh, Pd and Pt, respectively. With increasing sea water pH, over the range 7.9 to 8.4, uptake of Rh by Ulva increased considerably, whereas a small increase in Pt removal was observed; in contrast, uptake of Pd exhibited no clear dependence on pH. The percentage of metal taken up that was internalised within cells, evaluated by washing selected algal samples in 3 mM EDTA, was about 40% for Rh, 80% for Pd and 95% for Pt. Results of this study were interpreted in terms of what is known about the aqueous speciation of PGE in sea water. Thus, Rh exists as cationic hydrated chloride complexes which are readily adsorbed at the algal surface. Palladium has an exceptional affinity for organic ligands, and uptake (and internalisation) appears to be governed by competition for Pd²⁺ from aqueous and algal binding sites. Platinum (IV) exists predominantly as a series of (mainly) negatively charged chloride and mixed hydroxychloride complexes that have little propensity to interact with the algal surface; however, its high degree of internalisation requires at least some interaction with specific and perhaps physiologically active sites.     

Groupiness of Sea Waves and Their Characteristic Parameters

Three methods for studying wave groups and their main parameters for describing wave groupiness are reviewed in this paper. Then they are analyzed and compared combined with field data from both aspects of group height and group length. A method and two parameters that can describe wave groupiness are suggested. The groupiness parameters of sea waves at three field stations are given. The effects of groupiness on both distributions of the wave height and the phase of component waves are investigated. The effects of datum length on the calculated value of grouping parameters are also discussed.     

Experimental Study on the Interaction Mechanism of Cap—Pile Group—Soil

Static load tests on pile group with prototype size were carried out in order to study the behavior and the working properties of the cap—pile group—soil interaction in the pile group foundation. The soil resistance under the cap, the pile shaft resistance and the tip resistance were measured by installing various measuring gauges. Based on these test results, the cap—pile group—soil interaction characteristics were analyzed. The regulations of the soil reaction on the cap, the shaft resistance and the tip resistance of pile, the mechanism of load transfer have been discussed with comparison to the result of the single pile tests. The bearing capacity of pile group is greater than the sum of the bearing capacity of the single pile obtained from testing in the same site in pile group foundation in the case presented here.     

富Co铁锰结壳铂族元素与铼-锇同位素组成及其意义

用ICP－MS测定了太平洋富Co铁锰结壳铂族元素和铼－锇同位素组成。富Co铁锰结壳不仅异常富集铂族元素，而且铂族元素及其它亲铁元素的配发与陨石特征非常相似。铁锰结壳的铼－锇同位素组成明显有别于大陆地壳岩石，和K－T界线沉积物相似，接近陨石值。世界大洋范围内的富Co铁锰结壳均产于远离海底构造热液活动区，几乎不可能受到地幔源热液作用的直接影响。因此，富Co铁锰结壳中的铂族元素可能部分来源于地外物质。     

东海北部海域虾类不同生态类群分布及其渔业

本文根据1986～1991年对东海北部海域（26°00’～326°00’N，100m水深以浅）虾是调查资料，研究了不同虾类的栖息水深与调查区水系分布之间的关系，把本海区的虾类资源划分为广温低盐，广温广盐和高温高盐三个生态类群，并阐明各生态类群及主要种类的分布特点。文中还叙述了东海区拖虾渔业的发展现状，讨论了今后的发展对策。