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51.
A core from the Cambay Shale Formation of the Cambay Basin, containing immature Type III organic matter, was pyrolysed at 300°C for different durations of time to different maturation levels. Fractionation effects were studied employing a three-step extraction technique after removal of the expelled pyrolysate. The extractable organic matter (EOM) obtained on extraction of the whole core is assumed to be that present in open pores, while that obtained on finely crushing the sample is assumed to be that present in closed pores. The EOM obtained from 1 cm chips is termed EOM from semi-open pores. The gross composition of the pyrolysates expelled during pyrolysis is not similar to the oils reservoired in the area, and there is no significant fractionation observed between expelled pyrolysates and unexpelled EOM. Our study indicates movement of fluids between closed, semi-open and open pores. In both systems, there is a higher concentration of EOM in open pores than in semi-open and closed pores, and the fraction of EOM in open pores is much greater in the artificial system than in the natural system. Fractionation effects on n-alkane and isoprenoid hydrocarbon-based parameters were also studied. n-Alkenes are present in semi-open and closed pores of the immature core and in the core after it was pyrolysed to 300°C for 6 and 48 h, but are absent in the open pores. n-Alkenes are present in closed pores in the naturally matured core. Presence of n-alkenes in the pyrolysates expelled during the 6 and 48 h experiments, but their absence in the open pores of the core, indicates that expulsion also occurs through temporary microfractures during laboratory pyrolysis, whereas in the natural system expulsion from closed pores seems to be only via semi-open and open pores. 相似文献
52.
53.
The hydrocarbon generation mechanism and the three-stage type model of hydrocarbon generation for carbonate source rocks 总被引:1,自引:0,他引:1
The diagenetic mechanism and process of carbonate rocks, which is different to that of clastic rocks, decides the existence
of different existing state organic matters in carbonate rocks. This has been verified by both the microscopic observation
of organic petrology and the analysis of organic geochemistry of many samples. Based on the hydrous pyrolysis simulation experiment
of the low-mature carbonate rocks, the contrasting study on the yield and their geochemistry characteristics of different
existing state soluble organic matters of a series of various maturity samples shows that the different existing state organic
matters make different contributions to hydrocarbon generation during every evolution state. So that, the hydrocarbon generation
process of carbonate rocks can be summarized as the following three stages: the first is the direct degradation of biogenic
bitumen macromolecules during the immature stage, the second is the thermal degradation of a large amount of kerogen at the
mature stage, the last stage is the expulsion or release of inclusion organic matter owing to the increased thermal expansion
pressure during the high evolution stage.
Part of achievements of the Eighth Five-Year National Science-Technology Key-Task Project “85-102-02-07”. 相似文献
54.
The Zoige Basin is located in the eastern margin of the Qinghai-Xizang Plateau, in which two cores, RH and RM, have been drilled,
with the depths of 120 m and 310 m respectively. The former with the bottom age of 826 kaB. P. has been divided into 21 stages
according to the multi-proxy analysis, which could be basically compared with the oxygen isotope record of deep-sea core.
The palaeoclimatic and palaeoenvironmental process of the Zoigê Basin over the past 900 kaB. P. is reconstructed, and the
comparison of core RH with the Luochuan Loess record is made. 相似文献
55.
Evolution model and formation mechanism of bio-thermocatalytic transitional zone gas 总被引:1,自引:0,他引:1
As a new genetic type of natural gas exploration area, the bio-thermocatalytic transitional zone gas (BTTZG) has been highly
stressed by geologists both at home and abroad. Systematic study on the generation mechanism of hydrocarbon at the transitional
zone is presented. Based on simulating experiments and geochemistry analysis of the source rock with lower evolution, a hydrocarbon-forming
model at the transitional zone has been established. The mechanism is proposed that under the condition of low temperature
and pressure combining with extremely active structural stress and clay mineral catalysis, BTTZG is formed by de-group of
soluble organic matter and polarized compositions through orthocarbon ion as well as by condensation polymerization of aromatic
ring-rich insoluble organic matter. This mechanism controls the formation of BTTZG, and furthermore, BTTZG is the product
of superimposition and interaction of all the factors mentioned above. 相似文献
56.
在分散度不同的区域内进行区域采样用于水中硫酸根离子的测定,结果令人满意。应用此方法测定硫酸根离子的线性范围为200.0~3000mg/L;进样频率为120次/h;相对标准偏差为1.70% 相似文献
57.
58.
用冲绳海槽地区地质、地球物理、地球化学数据与资料,对横跨大陆边缘—大洋板块的中国东部—冲绳海槽—琉球岛弧地区进行综合研究. 根据地震体波、面波成像结果,空间与布格重力异常及磁力异常的综合解释等结果,利用调和系数法对该研究区的地壳厚度进行了计算,并对地壳属性进行分析. 同时,选择中国东部东北地区的宽甸、华北地区的汉诺坝、华南的闵溪和台湾海峡的澎湖列岛与冲绳海槽和日本岛弧的新生代玄武岩开展元素—同位素对比研究. 结果认为冲绳海槽岩石层明显减薄,上地幔低速层已达到莫霍面,在地幔中已形成交代软流层. 元素—同位素研究表明:它不同于中国东部,与琉球岛弧地区的特点也不相同. 综合分析认为:冲绳海槽地壳属于过渡型地壳,与大洋地壳的许多特点颇为相似. 相似文献
59.
鄂尔多斯盆地奥陶系海相碳酸盐岩生烃性能与中部长庆气田气源成因研究 总被引:15,自引:0,他引:15
用激光 -荧光显微镜等有机岩石学方法 ,挑选样品中有明显生、排烃现象的碳酸盐岩 ,再以测定的这类碳酸盐岩的有机碳含量为依据 ,确定本区高成熟碳酸盐气源岩残余有机碳的下限指标用 0 .13%~ 0 .14 %比较合理。根据碳酸盐岩储层孔隙中充填沥青和皮膜状残余沥青的分布和含量 ,论证了陕参 1井等奥陶系碳酸盐岩地层在地质历史中 ,存在若干油气有效储层。采用连续升温 ,步进取样的热模拟实验方法 ,揭示了本区煤与碳酸盐岩干酪根随热演化作用增强 ,烃类气体产物的干燥系数增大 ,δ1 3C1 、δ1 3C2 明显变重的规律 ,并根据样品实验结果推算 ,本区石炭系—二叠系煤最大生气阶段的δ1 3C1 应为 - 2 7‰~ - 2 8‰ ,碳酸盐岩最大生气阶段的δ1 3C1 应为- 31.7‰~ - 33‰。在气源成因判识中 ,根据主生气期阶段对天然气成藏储聚的贡献最大、甲烷碳同位素较重以及长庆气田风化壳气藏天然气δ1 3C1 重值区并不与石炭系—二叠系煤的镜质组反射率高值区匹配的现象等进行气源判识 ,认为长庆奥陶系风化壳气藏 ,具有下古生界海相碳酸盐岩气与上古生界石炭系—二叠系煤成气的混源成因 相似文献
60.
HAO Fang JIANG Jianqun ZOU Huayao FANG Yong & ZENG Zhiping . Key Lab for Hydrocarbon Accumulation Mechanism in the Ministry of Education Petroleum University Beijing China . Department of Petroleum Geology China University of Geosciences Wuhan China 《中国科学D辑(英文版)》2004,47(9)
Thetraditionalhydrocarbongenerationmodeldoesnottakeintoaccounttheeffectofpressure[1].Astotheroleofpressureinorganicmattermaturationandpetroleumgeneration,threeconflictingopinionshaveeverbeenproposed:(1)Increasingpressurehasnodetectableeffectonorganic-mattermaturation[1,2];(2)increasingpressureenhanceshydrocarbon-thermaldestruction[3];(3)increasingpressuresignificantlyretardsorganic-mattermaturationandhydrocarbongeneration[4,5].Therearemorethan180overpressuredbasinsintheworld.Theroleofoverpress… 相似文献