国外天然气水合物岩心处理分析技术综述

分析了国外天然气水合物岩心研究现状,并从钻井液和实时监控两方面讨论分析了钻进和取心中存在的安全问题.对于岩心取样和保存,主要探讨了压力和温度的保持与现场取心和取样的方法,然后结合取心上存在的主要差异、关键岩心性质以及MALLIK和ODP Joides决心号钻探船上岩心的实验室研究,探讨了天然气水合物的岩心分析.最后针对国内研究现状提出了几点建议.     

古巴前陆盆地三区块油气成藏条件及有利区带预测

古巴前陆盆地三区块是2005年中国石油化工股份有限公司登记的风险勘探开发合同区块,位于墨西哥湾西南部,属古巴西部前陆盆地中租赁区块之一。结合该盆地的勘探现状及盆地内的钻井、物探以及地球化学等相关资料,分析了该盆地的油气成藏条件及其勘探潜力,预测了有利区带。三区块主要发育上侏罗统—下白垩统泥灰岩、泥质灰岩和中—下侏罗统泥页岩两套主要烃源岩,储层以泥晶灰岩、灰岩和砂砾岩为主,区内早期形成的圈闭在造山期基本遭到破坏,有效的圈闭主要形成于古近纪晚期,圈闭类型以背斜、断鼻、断块为主,推测可能发育多套储盖组合。盆地内有两大潜力勘探区域:北部前陆冲断带发育古近系盖层,是下一步勘探的首选区域;南部盆地北缘发育较厚的古近系和新近系,属南部盆地系统,推测是有利远景区。     

鄂尔多斯盆地靖边气田沟槽与裂缝的配置关系对天然气富集程度的影响

陕200井区是在鄂尔多斯盆地靖边气田发现的一批具有潜在储量的区块,对该井区天然气富集规律的认识有助于更好地进行勘探开发。研究认为:沟槽与裂缝的不同配置关系对马五段各小层天然气的富集程度产生不同的影响,上古生界天然气首先沿沟槽垂向穿层运移至奥陶系下古生界马五段各个小层中,然后再沿裂缝转为小层内的侧向运移;沟槽发育越完善,裂缝密度越大,则天然气富集程度越好。马五1亚段、马五2亚段在沟槽和裂缝的双重作用下,其含气饱和度高于仅有裂缝的马五41小层,研究区各层段天然气富集程度从小至大依次为马五1亚段、马五2亚段和马五41小层。     

金属矿气体地球化学测量技术新进展

气体地球化学测量方法由于气体的强穿透性,可将大量的与深部矿化作用有关的物质携带到地表,可直接或间接指示各种地质成矿过程,而受到勘查地球化学的重视。经历数十年的发展之后,气体地球化学测量在测量指标、方法及影响因素研究方面都取得了长足进展。特别是近年来由于分析技术提高,使得很多超微含量的气体测定成为可能,一些新的气体测量方法相继提出,在寻找隐伏矿或盲矿方面获得了较好的效果。笔者对气体测量发展史、气体测量方法、指标及影响因素进行了简单总结,并重点介绍了一种新的气体测量技术（SDP）的测量原理、使用方法及应用实例。     

Low-mature gases and their resource potentiality

In the 80’s of last century, based on the advances in natural gas exploration practice, the concepts of bio-thermocatalytic transitional-zone gas and early thermogenetic gas were proposed, and the lower limit Ro values for the formation and accumulation of thermogenetic natural gases of industrial importance have been extended to 0.3%–0.4%. In accordance with the two-stage model established on the basis of carbon isotope fractionation involved in the formation of coal-type natural gases, the upper limit Ro ...     

On the scavenging of SO2 by cloud and raindrops: II. An experimental study of SO2 absorption and desorption for water drops in air

For the purpose of testing our previously described theory of SO₂ scavenging a laboratory investigation was carried out in the UCLA 33 m long rainshaft. Drops with radii between 250 and 2500 m were allowed to come to terminal velocity, after which they passed through a chamber of variable length filled with various SO₂ concentrations in air. After falling through a gas separating chamber consisting of a fluorocarbon gas the drops were collected and analyzed for their total S content in order to determine the rate of SO ₂ absorption.The SO₂ concentration in air studied ranged between 1 and 60% (v). Such relatively large concentrations were necessary due to the short times the drops were exposed to SO₂ in the present setup. The present experimental results were therefore not used to simulate atmospheric conditions but rather to test our previously derived theory which is applicable to any laboratory or atmospheric condition. Comparison of our studies with the results from our theory applied to our laboratory conditions led to predicted values for the S concentration in the drops which agreed well with those observed if the drops had radii smaller than 500 m. In order to obtain agreement between predicted and observed S concentrations in larger drops, an empirically derived eddy diffusivity for SO₂ in water had to be included in the theory to take into account the effect of turbulent mixing inside such large drops.In a subsequent set of experiments, drops initially saturated with S (IV) were allowed to fall through S-free air to determine the rate of SO ₂ desorption. The results of these studies also agreed well with the results of our theoretical model, thus justifying the reversibility assumption made in our theoretical models.In a final set of experiments, the effects of oxidation on SO₂ absorption was studied by means of drops containing various amounts of H₂O₂. For comparable exposure times to SO₂, the S concentration in drops with H₂O₂ was found to be up to 10 times higher than the concentration in drops in which no oxidation occurred.     

中国油气页岩分布与存储潜能和前景分析

基于当今化石油气能源的需求还在扩展,它的紧缺势态波及全球,而我国的确需要更多的页岩油气.为此,非常规油气能源,特别是页岩油气的勘探、开发和利用就必然地提到社会进步和经济发展的议程上,并得到世界各个国家的高度重视.因此,页岩油气现已成为我国能源界和科技界及政府部门的热门话题.在经过了一段时间的"热炒"和依据尚不充分的评估后,本文通过对中外有关资料的分析和讨论认为:1)必须在了解世界各国、特别是北美页岩油气赋存与开发的条件下,认识我国页岩的分布状态和页岩油气潜能;2)在理解其它国家页岩属性、页岩油气的前景和勘查及储存背景下,在我国较全面的进行页岩和页岩油气存储的勘探和对其进行要素匹配,并选择远景好的典型地区进行示范研究与探索;3)集理念与实践综合研究制定页岩油气在我国的发展方案和路线图.     

页岩气藏评价中的岩石物理方法

岩石物理在页岩气勘探开发中非常重要,而文献中至今缺少足够的重视.本文分别从页岩气藏的地质特征、评价参数、岩心分析工作流程及测井工作流程等4个方面探讨页岩气储层的固有特征及岩石物理所起的关键作用.从生烃潜力、储存性能、流动特性和力学性质讨论相关评价参数的岩石物理方法,重点讨论吸附气含量的计算、力学性质及基质渗透率的测量.在页岩气储层测井评价方面,重点探讨有机质含量的测井评价方法、页岩气层孔隙度的评价方法、随钻测井用于水平井的地质导向、及测井评价在制定压裂方案中的应用.     

岷县漳县6.6级地震后申都乡地窖宏观异常现象及其机理探讨

2013年7月22日甘肃岷县漳县M_s6.6地震后岷县申都乡某地窖出现冒白色烟雾的宏观异常现象。本文通过土壤气Rn、Hg现场检测和采样后气相色谱检测、生物显微镜观察结果,探讨了气体来源、赋存和运移机理以及异常形成的物理化学机制。认为该点具有灵敏的断层活动响应,可作为今后开展断层活动及未来甘东南地震趋势预测判定的断层土壤气监测点进行长期监测。     

裂隙充填型天然气水合物的各向异性分析及饱和度估算——以印度东海岸NGHP01-10D井为例

沿裂隙发育的天然气水合物是印度深水盆地细粒沉积物中水合物的重要产出方式,水合物以结核状或脉状充填在高角度裂隙中.天然气水合物主要沿着构造主应力方向生成,由于裂隙的存在,含水合物的沉积物层呈现各向异性.利用孔隙介质中水合物呈均匀分布的速度模型计算的NGHP01-10D井水合物饱和度高达40%,而压力取芯表明水合物饱和度占孔隙空间的20%左右.为了研究水合物饱和度差异,基于层状介质的各向异性模型计算了裂隙充填型水合物的饱和度.在垂直井孔中,由于波入射角与裂隙倾角有关,考虑裂隙倾角变化,利用纵波和横波速度同时反演水合物饱和度和裂隙倾角.利用层状介质模型计算的水合物占孔隙空间的15%～25%,裂隙的倾角在60°～90°,多为高角度裂隙.在NGHP01-10D井中,纵横波速度联合计算的饱和度与压力取芯结果吻合更好.