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71.
Automated Extraction of a Five‐Year LA‐ICP‐MS Trace Element Data Set of Ten Common Glass and Carbonate Reference Materials: Long‐Term Data Quality,Optimisation and Laser Cell Homogeneity
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LA‐ICP‐MS is increasingly applied to obtain quantitative multi‐element data with minimal sample preparation, usually achieved by calibration using reference materials (RMs). However, some ubiquitous RMs, for example the NIST SRM 61× series glasses, suffer from reported value uncertainties for certain elements. Moreover, no long‐term data set of analyses conducted over a range of ablation and tuning conditions exists. Thus, there has been little rigorous examination of the extent to which offsets between measured and reported values are the result of error in these values rather than analytically induced fractionation. We present new software (‘LA‐MINE’), capable of extracting LA‐ICP‐MS data with no user input, and apply this to our system, yielding over 5 years of data (~ 5700 analyses of ten glass and carbonate RMs). We examine the relative importance of systematic analytical bias and possible error in reported values through a mass‐specific breakdown of fourteen of the most commonly determined elements. Furthermore, these data, obtained under a wide range of different ablation conditions, enable specific recommendations of how data quality may be improved, for example the role of diatomic gas, the effect of differential inter‐glass fractionation factors and choice of transport tubing material. Finally, these data demonstrate that the two‐volume Laurin ablation cell is characterised by no discernible spatial heterogeneity in measured trace element ratios. 相似文献
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Reserves of some kinds of the crisis mines will be lack now or from now on, because of lacking seriously reserves of mineral resources and the crisis of exploring bases in support. So that it is urgent to predict, appraise, development and utilize the replaceable resources of the crisis mines. The mineral resources prediction software system of synthetic information is intelligent GIS which is used to quantitative prediction of large-scale synthetic information mineral target. It takes the geological body and the mineral resource body as a unit. And it analyzes the ore deposit genesis and metallotect, knows the spatial distribution laws of the ore deposit and ore body, and establish the prospecting model based on the concept of establishing the three-dimensional space of a mine. This paper will primarily discuss some important problems as follows: the secondary development of various kinds of data(including geology, geophysical prospecting, geochemical prospecting and remote sensing, etc); process synthetically and establish the synthetic information interpretative map base; correspond prospecting model with synthetic information of ore deposit; divided into statistical units of metallogenic information synthetic anomalies based on the synthetic information anomalies of ore control, then research the metallogenic information variable of unit synthetically and make quantitative prediction according to choose the quantitative prediction math model which is suitable to the demands of large-scale precision; at last, finish the target area optimization of ore deposit (body). 相似文献
75.
对土石方计算的几点技巧的探讨 总被引:2,自引:0,他引:2
在工程测量中,测量土石方是一件很普通的工作。但在计算土石方过程中,经常会遇到一些很难解决的问题。介绍了利用一种常用的土石方软件系统来计算土石方的技巧。 相似文献
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综合分析了中国数字地震台网(CDSN)改造后的5个长周期地震仪台站观测的3天的VHZ、VHE和VHN波形资料,利用功率谱密度估计方法,在没有对资料进行去固体潮处理的情况下,准确获得了2004年12月26日印度洋地震激发的0S3~0S78的基频球型振荡和部分谐频球型振荡和0T3~0T67的基频环型振荡,并与地球初步参考模型(PREM)的理论自由振荡周期进行了对比,发现实测振荡周期与PREM预测的振荡周期符合的很好.频率与PREM模型略微不一致的球型或环型振荡可以解释为地球介质的横向不均匀性和各向异性所致.因此地球自由振荡信息可用于揭示地球的三维不均匀结构信息或各向异性信息,并可能对区分地幔对流模式有所帮助. 相似文献
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软件开发是海洋监测技术与设备研究与开发的一个重要的环节,软件开发质量的高低直接关系到海洋监测仪器和设备的质量。文中阐释了以用户为中心的软件开发方法的概念、特点以及其实施中的基本原则和关键活动,并对传统的软件开发方法和以用户为中心的软件开发方法进行了比较研究。该方法不仅提高了用户的生产效率和生产质量,而且还减少了企业支持和培训方面的费用,提高了产品和服务的竞争力。 相似文献
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Second-order random interfacial wave solutions for two-layer fluid with a free surface 总被引:3,自引:3,他引:0
1 Introduction Interfacial waves travelling along the interface between two fluids of different densities can be often observed in subsurface layers of the ocean since the upper subsurface layer is warmer over much of the o- cean (Umeyama, 2002). They are… 相似文献