超声提取-固相萃取小柱净化-气相色谱法测定土壤中14种有机氯农药

对土壤中14种有机氯农药的超声提取技术和磺化、固相萃取小柱两种净化方法进行系统研究。结果表明,超声提取节省提取时间,提高分析效率;磺化法和固相萃取小柱法都有净化作用,但磺化法使样品中的艾氏剂、狄氏剂和异狄氏剂全部损失;固相萃取小柱净化当丙酮-正己烷淋洗液体积比为1∶9、淋洗液收集8 mL时回收率>90%,干扰最小。方法检出限为0.63~2.59μg/kg,精密度(RSD,n=7)为1.17%~14.66%,基体加标平均回收率为82.78%~106.94%。方法用于生态地球化学调查评价批量土壤样品的实际分析,检测结果满足评价工作需要。     

Bulk-rock Major and Trace Element Compositions of Abyssal Peridotites: Implications for Mantle Melting, Melt Extraction and Post-melting Processes Beneath Mid-Ocean Ridges

This paper presents the first comprehensive major and traceelement data for 130 abyssal peridotite samples from the Pacificand Indian ocean ridge–transform systems. The data revealimportant features about the petrogenesis of these rocks, mantlemelting and melt extraction processes beneath ocean ridges,and elemental behaviours. Although abyssal peridotites are serpentinized,and have also experienced seafloor weathering, magmatic signaturesremain well preserved in the bulk-rock compositions. The betterinverse correlation of MgO with progressively heavier rare earthelements (REE) reflects varying amounts of melt depletion. Thismelt depletion may result from recent sub-ridge mantle melting,but could also be inherited from previous melt extraction eventsfrom the fertile mantle source. Light REE (LREE) in bulk-rocksamples are more enriched, not more depleted, than in the constituentclinopyroxenes (cpx) of the same sample suites. If the cpx LREErecord sub-ridge mantle melting processes, then the bulk-rockLREE must reflect post-melting refertilization. The significantcorrelations of LREE (e.g. La, Ce, Pr, Nd) with immobile highfield strength elements (HFSE, e.g. Nb and Zr) suggest thatenrichments of both LREE and HFSE resulted from a common magmaticprocess. The refertilization takes place in the ‘cold’thermal boundary layer (TBL) beneath ridges through which theascending melts migrate and interact with the advanced residues.The refertilization apparently did not affect the cpx relicsanalyzed for trace elements. This observation suggests grain-boundaryporous melt migration in the TBL. The ascending melts may notbe thermally ‘reactive’, and thus may have affectedonly cpx rims, which, together with precipitated olivine, entrappedmelt, and the rest of the rock, were subsequently serpentinized.Very large variations in bulk-rock Zr/Hf and Nb/Ta ratios areobserved, which are unexpected. The correlation between thetwo ratios is consistent with observations on basalts that D_Zr/D_Hf< 1 and D_Nb/D_Ta < 1. Given the identical charges (5⁺ forNb and Ta; 4⁺ for Zr and Hf) and essentially the same ionicradii (R_Nb/R_Ta = 1·000 and R_Zr/R_Hf = 1·006–1·026),yet a factor of 2 mass differences (M_Zr/M_Hf = 0·511 andM_Nb/M_Ta = 0·513), it is hypothesized that mass-dependentD values, or diffusion or mass-transfer rates may be importantin causing elemental fractionations during porous melt migrationin the TBL. It is also possible that some ‘exotic’phases with highly fractionated Zr/Hf and Nb/Ta ratios may existin these rocks, thus having ‘nugget’ effects onthe bulk-rock analyses. All these hypotheses need testing byconstraining the storage and distribution of all the incompatibletrace elements in mantle peridotite. As serpentine containsup to 13 wt % H₂O, and is stable up to 7 GPa before it is transformedto dense hydrous magnesium silicate phases that are stable atpressures of 5–50 GPa, it is possible that the serpentinizedperidotites may survive, at least partly, subduction-zone dehydration,and transport large amounts of H₂O (also Ba, Rb, Cs, K, U, Sr,Pb, etc. with elevated U/Pb ratios) into the deep mantle. Thelatter may contribute to the HIMU component in the source regionsof some oceanic basalts. KEY WORDS: abyssal peridotites; serpentinization; seafloor weathering; bulk-rock major and trace element compositions; mantle melting; melt extraction; melt–residue interaction; porous flows; Nb/Ta and Zr/Hf fractionations; HIMU mantle sources     

DDT residue in soil and water in and around the abounded area of DDT manufacturing factory

Due to the persistent nature of DDT, a persistent organic pollutant and its adverse environmental and health impacts, the present study was undertaken to examine the residual DDT in and around DDT manufacturing factory in Amman Gharh, Nowshera, NWFP. The factory was established in 1963 and remained in operation till 1994. Composite samples of soil, sediments and water were collected in and around the factory area, nearby DDT stores, main factory drain leading to river and nearby villages. Standard procedures were used for the collection, transportation and storage of samples for analysis. Physical parameters for the collected water samples measured were temperature, pH and conductance. Extraction of each sample for DDT analyses was carried out in triplicates using soxhlet extraction apparatus. The extract was transferred to well washed, clean; dry glass vial, sealed and put in the refrigerator. Gas Chromatograph with electron capture detector and capillary column was used for analysis. DDT in the samples was identified on the basis of their retention time and quantified on the basis of peak areas. It is evident from the analytical data obtained in the present study that both water and soil in and around the factory area are still contaminated with DDT, despite the closure of the factory since the past few years.     

环境样品中痕量元素的化学形态分析Ⅰ．分析技术在化学形态分析中的应用

文章介绍了形态分析的基本概念,常用的联用分析技术,如气相色谱原子吸收光谱、气相色谱原子荧光光谱、气相色谱微波诱导等离子体原子发射光谱、气相色谱电感耦合等离子体质谱、高效液相色谱电感耦合等离子体质谱等在环境样品(水、土壤、沉积物)中痕量元素化学形态(价态、金属有机化合物等)分析中的应用,土壤和沉积物中污染元素的顺序提取步骤,以形态分析发展动态。引用文献72篇。     

利用遥感信息决策树方法分层提取荒漠化土地类型的研究探讨

选择甘肃省民勤县绿洲作为典型荒漠化区域,根据荒漠化土地分类体系确定决策树的结构及各类地物在树形中的位置。基于各类地物的光谱反射特性和图象数据反映的综合特征,采取相应的识别和提取方法,以最大限度地利用遥感数据源。对于非荒漠化土地分类,利用土壤调节植被指数、阈值数字信号统计可以分离成一类树枝;而重点讨论的3种荒漠化土地类型的分层分类,则相继采用光谱特征提取、几何特征提取、纹理特征提取、监督分类以及植被指数等复合识别指标进行分枝。结果表明:利用决策树分层提取法可以有效地排除和避免提取地物时所有多余信息的干扰及影响,目标明确。同时,为提高分类的精度,开展野外遥感调查和特征分析是极其重要的。     

微囊藻群体总RNA提取方法的比较

微囊藻群体富含多糖类物质是影响微囊藻RNA提取的关键因素.为了获得高质量的微囊藻群体总RNA,对比分析4种针对多糖含量较高的方法——方法 1 PGTX-bead法、方法 2 CTAB-bead法、方法 3 Fast RNAPro Blue Kit和方法 4RNeasy Mini Kit对微囊藻群体总RNA的提取效果.采用琼脂糖凝胶电泳检测微囊藻群体RNA的完整性,Nanodrop ND1000分光光度计检测RNA纯度及浓度,并采用q PCR检测DNA污染情况.结果表明,4种方法都能从微囊藻群体中提取获得RNA,并在去除DNA后都可以进行RT-PCR等后续实验.方法 1 PGTX-bead提取的RNA产量最高,纯度好,DNA污染小,成本低,适合从微囊藻群体中大量提取RNA;方法 2 CTAB-bead提取的RNA样品产量也较高,但DNA污染严重,适合需要同时提取DNA和RNA的样本;方法 3 Fast RNAPro Blue Kit和方法 4 RNeasy Mini Kit提取的RNA产量都较低,但方法 4操作简单,耗时短,所检测目的基因的相对表达量较高,更适合从少量的微囊藻群体中提取总RNA.     

太湖沉积物中重金属的地球化学形态及特征分析

用连续提取法分析了太湖沉积物5种重金属的地球化学形态,对地球化学形态的组成和地理特征进行了分析研究.重金属地球化学形态配分的共同特点是可交换态最低,残渣态最高.两种形态中Cd的可交换态最高,Cr的残渣态最高,可交换态最低.Cd的碳酸盐态较高,Cr的最低;Pb、Cd的Fe-Mn氧化态较高,Cu的偏低;Cu的有机态最高,Cd的最低;Zn的地球化学形态比例大都处于中间.地域上变化较大的元素是Cd和Cu,变化不明显的元素有Pb和Zn.化学成分中Fe2O3、MnO与重金属地球化学形态的相关性最好,TOC与Cu的形态相关系数最高.综合对比分析表明,太湖沉积物重金属的生物有效性以Cd为最高,其次为Pb.     

面向带电作业的手臂末端输出力评估方法

为了解决带电作业时手臂末端输出力的准确控制,提出一种基于表面肌电信号（sEMG信号）和支持向量机回归（SVR）实现对手臂末端施力的评估方法.通过手握机械手臂末端的手柄,做往复推拉运动,记录此时手柄处的力传感器的数据F,同时利用3组肌电信号传感器同步采集手臂的肌电信号.将肌电信号提取特征后,与力F组合成样本集合S,在样本集合中随机抽取50%的样本数据作为训练集,分别训练BP神经网络、GRNN神经网络以及SVR神经网络.最后用训练好的神经网络对整个样本集中的力F进行预测,并用均方根误差和相关系数评估模型的预测效果.结果显示,SVR神经网络的预测效果较好,其均方根误差为3.074 0,相关系数为0.951 7.     

遥感模式分类中的空间统计学应用——以面向对象的遥感影像农田提取为例

如何有效地从遥感图像中提取所需信息,是遥感图像处理和应用的关键,而尺度选择问题一直是影响遥感信息提取精度的关键问题之一。本文论述了利用空间统计学方法解决遥感影像模式分类中的尺度问题的理论基础。针对面向对象影像分析问题,将影响遥感影像多尺度分割的尺度分割参数概括为空间属性分割参数、光谱属性分割参数和影像对象面积阈值参数,并分别提出了基于统计学的尺度参数估计方法。以SPOT-5影像面向对象农田提取为例,基于变异函数方法进行了尺度优选试验,系列尺度分类试验结果表明基于空间统计学尺度估计得到的尺度分割结果进行分类能得到最高的精度,进而证明了基于空间统计学方法进行面向对象信息提取尺度估计的有效性。该方法是完全数据驱动的方法,基本不需要先验知识参与。不同于以往分割后评价的尺度选择方法会占用大量计算资源且耗费大量时间,本文提出的方法不仅能在一定程度上保证面向对象信息提取的精度,而且在一定程度上也提高了面向对象信息提取的效率和自动化程度。     

基于谱间关系的MODIS遥感影像水体提取研究

水是地球上万物的命脉所在,水体提取对于水资源调查、洪水灾害预测评估和环境监测等有着重要作用。而可见光和近红外波段水体与植被、城市和土壤光谱反射率的差异是利用遥感手段提取水体的基本原理。本文利用谱间关系法进行MOD IS图像的水体提取。结果表明,用于提取水体的谱间关系法比归一化植被指数(NDVI)法快速,但谱间关系法有把云错误地当作水体提取的缺点。