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361.
在 L i Br与水的物质量比分别为 1∶ 64、1∶ 32、1∶ 16、1∶ 8、1∶ 4和 1∶ 3的情况下 ,对 L i Br溶液从低温到高温的分子动力学模拟进行了研究。随浓度增加 ,锂离子的水合数量呈减少趋势但同时又从 L i+- Br-接触离子对的数量增加中得到补偿 ,而 L i离子的第一配位壳层的配位数量保持不变。在高浓度 Li Br溶液中 ,Br- O之间的距离有所增加 ,Br-- O的径向分布的形状更趋于非对称 ,从而很好地确定了 Br离子水合壳层 L i+- Br-接触离子对可以在更稀的溶液中产生 ,但随浓度增加而增加。L i+- Br-距离明显短于溶液中 Li离子与 Br离子的离子半径之和 ,也短于 L i Br晶体中两者离子半径之和。高浓度溶液中水分子的结构几乎被破坏 ,水分子间的氢键明显增加 ,但没有消失。对 L i+、Br-和水的扩数系数计算值与实验值进行了比较 相似文献
362.
本文根据岩石矿物组份质量分数值的定和特性 ,提出定量计算组份质量转移的新方法。该方法运用模糊动态聚类分析技术 ,通过计算复原定和差并判定差值类型 ,辅以相应的判别参数 ,逐步从中筛选出真恒量组份 ,再利用真恒量组份定值系数 ,计算出变组岩石矿物各组份的真实质量分数值和转移量值。笔者将该方法称为真恒量组份定值法 (TCF法 )。 相似文献
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Pre‐ and post‐test analyses of the structural response of a three‐storey asymmetric reinforced concrete frame building were performed, aimed at supporting test preparation and performance as well as studying mathematical modelling. The building was designed for gravity loads only. Full‐scale pseudo‐dynamic tests were performed in the ELSA laboratory in Ispra. In the paper the results of initial parametric studies, of the blind pre‐test predictions, and of the post‐test analysis are summarized. In all studies a simple mathematical model, with one‐component member models with concentrated plasticity was employed. The pre‐test analyses were performed using the CANNY program. After the test results became available, the mathematical model was improved using an approach based on a displacement‐controlled analysis. Basically, the same mathematical model was used as in pre‐test analyses, except that the values of some of the parameters were changed. The OpenSees program was employed. Fair agreement between the test and numerical results was obtained. The results prove that relatively simple mathematical models are able to adequately simulate the detailed seismic response of reinforced concrete frame structures to a known ground motion, provided that the input parameters are properly determined. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
365.
Approximate incremental dynamic analysis using the modal pushover analysis procedure 总被引:2,自引:0,他引:2
Incremental dynamic analysis (IDA)—a procedure developed for accurate estimation of seismic demand and capacity of structures—requires non‐linear response history analysis of the structure for an ensemble of ground motions, each scaled to many intensity levels, selected to cover the entire range of structural response—all the way from elastic behaviour to global dynamic instability. Recognizing that IDA of practical structures is computationally extremely demanding, an approximate procedure based on the modal pushover analysis procedure is developed. Presented are the IDA curves and limit state capacities for the SAC‐Los Angeles 3‐, 9‐, and 20‐storey buildings computed by the exact and approximate procedures for an ensemble of 20 ground motions. These results demonstrate that the MPA‐based approximate procedure reduces the computational effort by a factor of 30 (for the 9‐storey building), at the same time providing results to a useful degree of accuracy over the entire range of responses—all the way from elastic behaviour to global dynamic instability—provided a proper hysteretic model is selected for modal SDF systems. The accuracy of the approximate procedure does not deteriorate for 9‐ and 20‐storey buildings, although their dynamics is more complex, involving several ‘modes’ of vibration. For all three buildings, the accuracy of the MPA‐based approximate procedure is also satisfactory for estimating the structural capacities for the limit states of immediate occupancy, collapse prevention, and global dynamic instability. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
366.
《中国科学D辑(英文版)》2006,(Z2)
Seasonal metrics and environmental responses to forestry soil surface CO2 emission effluxes among three types of lower subtropical forests were consistently monitored over two years with static chamber-gas chromatograph techniques among three types of lower subtropical forests. Results showed that annual CO2 effluxes (S L) reached 3942.20, 3422.36 and 2163.02 CO2 g·m-2·a-1, respectively in the monsoon evergreen broadleaf forest, mixed broadleaf-coniferous forest and coniferous forest. All the three types of forests revealed the same characteristics of seasonal changes with the CO2 effluxes peaking throughout June to August. During this peaking period, the effluxes were 35.9%, 38.1% and 40.2% of the total annual effluxes, respectively. The CO2 emission process responding to the environmental factors displayed significantly different patterns in forestry soils of the three types of forests. The coniferous forest (CF) was more sensitive to temperature than the other two types. The Q10 values were higher, along with greater seasonal variations of the CO2 efflux, indicating that the structurally unique forestry ecosystem has disadvantage against interferences. All the three types of forestry CO2 effluxes showed significant correlation with the soil temperature (Ts), soil water content (Ms) and air pressure (Pa). However, stepwise regression analysis indicated no significant correlation between air pressure and the soil CO2 efflux. With an empirical model to measure soil temperature and water content in 5 cm beneath the soil surface, the CO2 effluxes accounting for 75.7%, 77.8% and 86.5% of the efflux variability respectively in soils of BF, MF and PF were calculated. This model can be better used to evaluate the CO2 emission of soils under water stress and arid or semi-arid conditions. 相似文献
367.
吉林伊通-大屯地区晚中生代-新生代玄武岩的地球化学特征及其意义 总被引:12,自引:7,他引:12
吉林伊通-大屯地区有长达80Ma的火山喷发历史,为探讨该区深部地质演化提供了条件。从晚白垩长春大屯火山(92.5±0.5Ma)到伊舒地堑内第三纪伊通火山群(31Ma、9~15Ma),玄武岩碱性逐渐增强,Dy/Yb比值逐渐升高,根据地幔动态熔融模型计算获得的玄武岩最终形成深度由约50km变深至110km。根据岩石圈盖效应推测该区晚白垩纪以来岩石圈厚度逐渐增厚。伊通第三纪碱性玄武岩显示了均一的地球化学组成;类似洋岛玄武岩(OIB)的微量元素分配模式和Nb/U比值,以及低(~(87)Sr/~(86)Sr)_i、正ε_(Nd)(t)同位素特征暗示它主要来源于软流圈。与第三纪碱性玄武岩相比,晚白垩大屯拉斑玄武岩具有相对偏高的Ni、Cr和Sc,高Ba/Th、Rb/Nb、Ba/Nb比值,高(~(87)Sr/~(86)Sr)_i和低(~(143)Nd/~(144)Nd)_i。这些特征可能与软流圈熔体与古老富集地幔之间的相互反应有关。伊通-大屯玄武岩的演化特征反映了岩石圈在板内岩浆作用中所担当的不同角色:第三纪时,岩石圈并没有在物质上直接参与岩浆作用,但岩石圈对上涌软流圈起到了机械阻挡作用;而在晚白垩岩浆作用中,岩石圈的间接和直接作用都得到了体现。 相似文献
368.
通过分析各种地壳运动假说,提出了地幔胀缩力和重力是地壳运动的主要动力来源,地球自转离心力和潮汐摩擦力是地壳运动的次要动力来源。地幔软流圈中放射性元素衰变热产生的膨胀使岩石圈产生拉裂,软流圈物质以岩浆形式喷出地表,岩浆柱散热收缩,产生负压,岩石圈在负压和重力作用下形成地壳运动。 相似文献
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370.