Excess silica in omphacite and the formation of free silica in eclogite

Silica lamellae in eclogitic clinopyroxene are widely interpreted as evidence of exsolution during decompression of eclogite. However, mechanisms other than exsolution might produce free silica, and the possible mechanisms depend in part on the nature and definition of excess silica. 'Excess' silica may occur in both stoichiometric and non-stoichiometric pyroxene. Although the issue has been debated, we show that all common definitions of excess silica in non-stoichiometric clinopyroxene are internally consistent, interchangeable, and therefore equivalent. The excess silica content of pyroxene is easily illustrated in a three-component, condensed composition space and may be plotted directly from a structural formula unit or recalculated end-members. In order to evaluate possible mechanisms for the formation of free silica in eclogite, we examined the net-transfer reactions in model eclogites using a Thompson reaction space. We show that there are at least three broad classes of reactions that release free silica in eclogite: (i) vacancy consumption in non-stoichiometric pyroxene; (ii) dissolution of Ti-phases in pyroxene or garnet; (iii) reactions between accessory phases and either pyroxene or garnet. We suggest that reliable interpretation of the significance of silica lamellae in natural clinopyroxene will require the evaluation not only of silica solubility, but also of titanium solubility, and the possible roles of accessory phases and inclusions on the balance of free silica.     

腾冲火山区上新世以来的火山活动

对腾冲火山区上新世以来的火山,尤其是具有最新活动的黑空山、打鹰山和鞍山进行了比较系统的Ｋ－年龄分析。去除样品中含有过剩氩的斜长石斑晶和橄榄石斑晶以后获得了一系列准确的基质Ｋ－Ａｒ年龄;根据火山活动的时空变化把腾冲火山活动分为三个期。第一期为上新世晚期,火山活动集中于火山区的西北和东南两端;第二期为早更新世期间,火山活动向腾冲盆地中心迁移和扩展,活动规模和分布面积最大;第三期为早更新世末期至全新世,     

小秦岭地区中深部含金石英脉的同位素地球化学特征及其意义

对小秦岭地区中深部含金石英脉的氢、氧、硫、氦和氩同位素地球化学研究表明，本区的成矿流体主要来源于深部，随着成矿过程的进行，表现出深源流体不断与浅部流体混合的演化趋势。结合前人的研究成果，根据成矿作用与区域伸展构造演化之间的耦合关系，指出小秦岭地区金的成矿作用主要发生于中生代晚期的后碰撞阶段，在由深部过程引发的伸展构造背景下，深部流体沿伸展构造系统向上运移，不断与浅部流体混合，与围岩发生水-岩相互作用，使流体系统中的成矿物质不断富集，最终在剪切扩容空间中富集成矿。     

淮河下游地区地表水与地下水同位素特征分析

为探明淮河下游地区地表水与地下水稳定同位素的组成特征,于2020年11月对该区域进行代表性采样,共采集地表水样13个,地下水样82个.结合全球大气降水同位素监测网(GNIP)公布的南京降水同位素数据,根据最小二乘法得出当地大气降水线(LMWL)方程为:δD=8.49δ18O+17.71,其斜率和截距高于全球大气降水线(...