Sulfur Determination in Geological Samples Based on Coupled Analytical Techniques: Electric Furnace-IC and TGA-EGA

A study has been undertaken to determine sulfur in geological samples by coupled analytical techniques. Two measurement methods have been developed: one using an electric furnace coupled to an ion chromatograph (electric furnace-IC) and another using infrared (IR) and quadrupole mass spectrometry (QMS) for evolved gas analysis (EGA) coupled with a thermogravimetric analyser (TGA). In the electric furnace-IC method, measurement was performed without any sample pre-treatment. The measurement conditions were optimised by varying sample quantity, type of catalyst (WO₃, Cu, W and V₂O₅) and sample/catalyst ratio, and the detection limit was 10 μg g⁻¹. Sulfur ores decompose at different temperatures. However, TGA-EGA allowed identification of the different forms of sulfur in the sample, even when they were found in very low concentrations, because the sulfur was continuously analysed. The developed chromatographic method allowed simultaneous analysis of several sample components, such as S, Cl and F, with a low detection limit. The method was much faster and more specific than the methods described in the literature. The results of the sulfur determination had low scatter, possibly because the samples underwent little handling during analysis: the operator only weighed and placed the sample in the furnace, the rest of the measurement process was fully automated. The results obtained by both the developed methods have been validated by using reference materials and comparison with combustion-IR spectroscopy, a standard method for determining total sulfur in a sample.     

MT方法在冀东迁安铁矿区深部找矿中的异常识别

文章叙述了通过MT方法在已知矿体上的剖面试验,结合钻探验证的3个钻孔的见矿情况,以及电偶极子人工场源对观测数据影响的对比、分析,指出依据航磁异常布设、采集的大地电磁剖面测深数据,尽管测点位于生产矿区,数据受到较严重的人文噪声干扰,且其部分频段异常形态与近区特征非常相似,实际上应为数据反演过程中所用软件未曾考虑铁矿石磁导率所致,而非近区效应;当一维视电阻率和相位曲线自几千赫兹以上即出现类似近区特征,二维反演剖面中的假象视电阻率异常高达几千至几万欧姆米时,应为有较强磁性的岩石和磁铁矿的反映;具有一定磁性的岩石和磁铁石英岩（包括磁铁石英辉石岩）在假象视电阻率异常强度、异常梯度变化上具有不同特征,可结合岩、矿石的电性、磁性特征予以识别.     

层状含水系统R—C电网络模拟方法

本文论述了R-C电网络模型的基本原理及模拟装置,分析了不同类型的层状含水系统。根据榴似性原理,建立了不同类型的电网络模型。在此基础上,预测了内蒙古某露天煤矿的矿坑疏干涌水量,取得了比较满意的结果。     

Letter to the editor Electric field fluctuations (25–35 min) in the midnight dip equatorial ionosphere

Measurements with a HF Doppler sounder at Kodaikanal (10.2°N, 77.5°E, geomagnetic latitude 0.8°N) showed conspicuous quasi-periodic fluctuations (period 25/35 min) in F region vertical plasma drift, V_z in the interval 0047/0210 IST on the night of 23/24 December, 1991 (A_p = 14, K_p < 4^–). The fluctuations in F region vertical drift are found to be coherent with variations in B_z (north-south) component of interplanetary magnetic field (IMF), in geomagnetic H/X components at high-mid latitude locations both in the sunlit and dark hemispheres and near the dayside dip equator, suggestive of DP2 origin. But the polarity of the electric field fluctuations at the midnight dip equator (eastward) is the same as the dayside equator inferred from magnetic variations, contrary to what is expected of equatorial DP2. The origin of the coherent occurrence of equatorial electric field fluctuations in the DP2 range of the same sign in the day and night hemispheres is unclear and merits further investigations.     

基于多源监测数据的雷电预警方法

以浙江省气象台已经业务运行多年的基于雷达数据的雷电预警产品(预警时效为60min,分辨率为1km×1km,4个预警等级)为基础,融合闪电定位系统数据和大气电场数据,提出一种基于多源监测数据的雷电预警方法。使用2018年的观测数据进行预警效果检验,结果表明:雷电预警的漏报率为31.89%,空报率为30.54%,临界成功指数为60.53%,比使用单一监测数据的雷电预警效果有所提高。由此可见,该雷电预警方法对浙江省雷电天气的预警具有参考价值和指示意义。     

中国房间空气调节器行业节能减排潜力分析

2012年,中国房间空气调节器（空调器）保有量约为3.57亿台,依据抽样调查数据计算得到保有量装机容量,采用各省市夏季平均温度估算超过26℃的时间作为运行时间计算得出年电力消耗约3.28×1011 kW?h,折合碳排放约为318 Mt CO₂当量。由于空调器国内需求量将进一步增长,预计到2030年保有量将达到当前的4～5倍。在电力结构不变情景下,空调器总体能效提高1倍,2030年空调器电力消耗产生的温室气体排放约为603 Mt CO₂当量。假设空调器总体能效提高1倍、高能效产品消费比例进一步提高并伴随中国能源结构调整,如水电、核电、太阳能等低碳能源比例不断提高,在满足中国空调器需求的前提下,2030年中国空调器电力消耗产生的温室气体排放可以争取控制在当前的水平。     

南宁市大气电场雷电预警系统的原理及应用

介绍南宁市大气电场雷电预警系统的原理及运行机制,通过一次成功的雷电预警过程,验证了系统的可用性,同时对系统的使用提出一些建议。     

浙江省雷击跳闸数据与闪电定位数据统计分析

利用浙江省电力部门雷击跳闸数据、浙江省气象局闪电定位数据,统计分析了2007—2011年电力雷击跳闸事故与地闪数据之间的时空分布特点、雷击跳闸事故与地闪参数及距离之间的关系。结果表明:电力雷击跳闸事故与地闪数据的日分布和月分布均为单峰结构,相关系数分别为0.9905和0.9881;空间分布虽有一定对应,但并非显著相关;导致110kV、220kV及500kV输电线路雷击跳闸的地闪强度主要集中在90kA以下,并且500kV输电线路雷击跳闸对应的电流强度相对较小;地闪与雷击跳闸事故杆塔距离、地闪与雷击跳闸杆塔对应输电线路的距离均主要集中在2km以下。     

青藏高原雷暴云降水与地面电场的观测和数值模拟

在2003年青藏高原那曲地区夏季雷暴云的观测试验中,三次伴有降水的过程中都出现了地面电场(Egnd)随降水的漂移现象,而且固态和液态降水对Egnd的极性改变并不相同。为了模拟再现高原雷暴云降水和Egnd之间的关系,选取了8月13日这次具有高原雷暴代表性特征的过程,模拟了雷暴云移经观测点上空期间,测站固、液态降水与Egnd的变化以及雷暴云下部正电荷区的空间分布。模拟的Egnd及固、液态降水与其的对应关系与观测事实较一致。分析结果表明,固态降水主要携带正电荷,液态降水主要携带负电荷,各类带不同极性和数量电荷的降水粒子常共存在雷暴云中,Egnd主要受携带电荷量占主导地位的降水粒子的影响,地面出现强正电场时正好是云在当顶并且地面出现强固态降水的时间。     

气象综合信息电子屏在新农村建设中的应用及思考

通过对气象综合信息电子屏应用情况进行分析和探讨,得出一些应用初步结论和思考,以期抛砖引玉,使该项工作能在新农村建设中加快应用步伐,为真正解决农村信息覆盖"最后一公里"的瓶颈提供参考.