三维复杂介质的块状建模和试射射线追踪

为了解决三维复杂介质的射线追踪,本文改变了传统的三维层状地层的建模描述方式,提出了块状结构的建模描述方法,结合三角形面片来描述地质界面,可以构造非常复杂的三维地质模型．为了满足射线追踪的需要,本文对模型界面内的法向量进行光滑处理,光滑后的法向量在界面内是连续变化的．在块状模型的基础上,本文运用三角形的面积坐标,提出了几种试射角度的修正方法：细分三角形法、分割三角形法和子三角形法,计算表明子三角形法最好．文中给出了三维块状模型和射线追踪实例．     

三维复杂介质中转换波走时快速计算

复杂介质中转换波走时计算是多波勘探地震学中重要内容之一.本项研究利用惠更斯原理和费玛原理,获得了三维复杂介质中转换波快速计算的改进型最小走时树方法.其中,在保证精度的条件下,为了提高三维转换波走时计算效率,首先对初至波最小走时树基本算法进行了改进.本方法通过将转换波分为上、下行波分别进行射线追踪以实现三维转换波走时的快速计算.模型计算表明,方法的计算速度快,而且稳定性强,对多波地震勘探具有较大的应用价值.     

Traveling wavefront ray tracing and its applications

The current discussion of whether marine geodesy is something entirely new or part of oceanography or geodesy can be clarified by re‐examining our notions about the basic business of geodesy. This paper contends that the same basic geodetic services, which were needed for millenia to chart and control new territory, are being adapted now to the marine environment to suit modern accuracy standards. In a brief historical review it is shown that conceptually, the oceanic regions were always an integral part of geodetic concern. The oceans were certainly part of the world for the ancient map makers and for Pythagoras’ spherical earth model. Notions connected with the marine geoid were implied in ancient speculations. Distances and directions at sea, even depths, were determined to meet the requirements of the times. With the modern sophistication in geodetic theory and measuring techniques, these ideas became more refined and demanding in turn, but they were there all the time. For obvious reasons, land geodesy developed faster; marine geodesy will catch up now, because only now there is the technical capability and also an urgent economic motivation.     

傅里叶变换离子回旋共振质谱的地球化学意义及其在油气勘探中的应用前景

NSO杂原子化合物在烃源岩和原油中通常只占很小的一部分,但其包含重要的地质地球化学信息。由于组成复杂且难以分离,对该类化合物的组成研究相对薄弱。电喷雾电离源（ESI）结合傅里叶变换离子回旋共振质谱（FT-ICR MS）是一种新型检测石油组分的手段,具有选择性电离、超高质谱分辨率和质量精度等特征,非常适合检测石油复杂基质中微量NSO极性杂原子化合物分子组成,近年来开始应用于油气勘探领域。结合对塔里木盆地海相油与陆相油、辽河稠油等样品的FT-ICR MS分析,发现原油中NSO化合物受母源岩与油气成因类型、成熟度、油气运移示踪及硫酸盐热化学还原反应（TSR）控制,可提供相关的识别与评价信息,显示FT-ICR MS在油气地球化学理论研究和油气勘探中具有潜在的应用价值。     

高逼真度虚拟森林环境的半球成像方法模拟分析

半球成像方法可广泛应用于植被结构参数及冠层光合有效辐射测量等领域。高逼真度虚拟森林环境的半球成像方法模拟及验证可用于定量评估半球成像方法测量精度及地面验证研究。但高逼真度虚拟森林环境下半球成像方法模拟面临场景复杂度高、面片数巨大、模拟效率低等难题。首先,论文以高逼真度虚拟森林环境构建原理建立了不同林分密度、树木分布模式、场景大小及树木种类等特征的虚拟森林环境库;然后,在采用光线跟踪算法开展半球成像方法模拟时,对比分析了4种数据结构分割平面搜索方法,即空间中分法、对象中分法、启发式排序法和启发式BIN分区法,结果表明,启发式排序法性能最佳;最后,以高逼真度虚拟森林环境库,对比分析了传统方法、Kdtree、BVH、Octree 4种数据结构方案组织、管理单树几何模型及虚拟森林场景两级数据集效率,并选择场景节点遍历数、单树几何模型节点遍历数、单树几何模型遍历数、面片遍历数及平均计算时间等参数作为衡量数据结构组织方案性能的定量化指标,研究发现Kdtree数据结构方案较其他3种数据结构方案更为优越,因此,其可作为高逼真度虚拟森林环境库的半球成像方法模拟之首选。     

Adsorption of Heavy Metal Ions, Dyes and Proteins by Chitosan Composites and Derivatives- A Review

Chitosan composites and derivatives have gained wide attentions as effective biosorbents due to their low costs and high contents of amino and hydroxyl functional groups. They have showed significant potentials of removing metal ions, dyes and pro- teins from various media. Chemical modifications that lead to the formation of the chitosan derivatives and chitosan composites have been extensively studied and widely reported in literatures. The aims of this review were to summarize the important information of the bioactivities of chitosan, highlight the various preparation methods of chitosan-based active biosorbents, and outline its potential applications in the adsorption of heavy metal ions, dyes and proteins from wastewater and aqueous solutions.     

利用重复地震研究新疆阿合奇—伽师—乌恰地区地壳介质变化

利用射线追踪方法对新疆伽师地区的重复地震进行位置归一处理,提高走时精度以达到观测伽师—乌恰和伽师—阿合奇地区地壳介质变化的目的。计算了伽师地区2005年1月至2011年3月ML≥2.5重复地震序列经射线追踪和波形互相关方法校正后的P波走时差。结果显示,在2009年2月20日柯坪5.4级地震前阿合奇台的记录观察到该地区短期的地壳介质速度明显升高现象,2010年6月10日乌恰5.2级地震前乌恰台也同样记录观察到该现象。     

The Seashell Wastes as Biosorbent for Reactive Dye Removal from Textile Effluents

This study investigates structural and adsorption properties of the powdered waste shells of Rapana gastropod and their use as a new cheap adsorbent to remove reactive dye Brilliant Red HE‐3B from aqueous solutions under batch conditions. For the powder shells characterization, solubility tests in acidic solutions and X‐ray diffraction (XRD), scanning electron microscopy (SEM), energy‐dispersive X‐ray spectroscopy (EDX), Fourier transform IR spectroscopy (FT‐IR) and thermogravimetric analyses were performed. The results revealed that the adsorbent surface is heterogeneous consisting mainly from calcium carbonate layers (either calcite or aragonite) and a small amount of organic macromolecules (proteins and polysaccharides). The dye adsorptive potential of gastropod shells powder was evaluated as function of initial solution pH (1–5), adsorbent dose (6–40 g L^?1), dye concentration (50–300 mg L^?1), temperature (5–60°C), and contact time (0–24 h). It was observed that the maximum values of dye percentage removal were obtained at the initial pH of solution 1.2, shells dose of 40 g L^?1, dye initial concentration of 50–50 mg L^?1 and higher temperatures; the equilibrium time decreases with increasing of dye concentration. It is proved that the waste seashell powder can be used as low cost bioinorganic adsorbent for dyes removal from textile wastewaters.     

A Novel Method for Dye Removal: Ionic Liquid‐Based Dispersive Liquid–Liquid Extraction (IL‐DLLE)

A novel, simple, fast, and efficient ionic liquid‐based dispersive liquid–liquid extraction (IL‐DLLE) has been applied to extract and remove Congo Red (CR; a carcinogenic textile dye) from aqueous solutions. In this methodology a binary solution, containing the extraction solvent (1‐hexyl‐3‐methylimmidazolium bis(trifluormethylsulfonyl) imid) and a suitable disperser solvent, was rapidly injected into the water sample containing CR dye. Therewith, a cloudy solution was formed, and most of the dye molecules were extracted into fine IL droplets and removed from aqueous phase. The effects of pH, type, and amount of IL, initial concentration of the dye, type and volume of the dispersant, and concentrations of salt on the extraction of the dye were studied. Experimental surveys were also accomplished for recovery of the IL by applying a reverse dispersive liquid–liquid extraction using acidic stripping solutions.     

山东半岛东部海域表层沉积物元素组成及物源指示意义

通过对山东半岛东部海域表层沉积物常量、微量元素、有机碳(TOC)以及碳酸盐(CaCO₃)等指标的分析,研究了该海域表层沉积物元素组成特征及其控制因素,并对物质来源进行了探讨。结果表明,山东半岛东部海域表层沉积物元素的平均组成与上陆壳(UCC)相比Al,K,Na,Mg,Fe,Ca,Cu和Zn等元素,相对较低,而Mn,Co,Ni,Cr以及REE元素含量较高,Si和Ti与UCC的含量相当。研究区砂粒级沉积物轻重稀土分异明显,(La/Yb)_N值与韩国河流的非常相近;其余粒级沉积物LREE分异较弱,标准化曲线与黄河沉积物的具有相似性。研究区沉积物的元素含量主要受控于源岩组成,存在明显的"粒级效应"。除此之外,Fe-Mn氧化物、生物碳酸盐等因素对元素组成产生一定影响。沉积物物源判别结果显示,山东半岛近岸及其东南部沉积物主要来源于黄河,该区域沉积物分布受山东半岛沿岸流及近岸潮流影响。研究区东北部为残留砂,其沉积物元素组成特征与朝鲜半岛和鸭绿江沉积物组成相近,表明研究区东北部砂质区沉积物代末次冰期低海平面时可能由朝鲜半岛或鸭绿江供应。