基于恒速压汞技术研究页岩气储层孔隙结构:以湘西北地区五峰组页岩为例

页岩气储层孔隙结构是页岩气富集成藏、储层评价和优选有利区的关键参数,区分孔隙和喉道是表征页岩气储层孔隙结构的关键。本文选择4块具有不同渗透率的湘西北地区奥陶系五峰组页岩为研究对象,基于恒速压汞实验讨论孔隙和喉道的大小、分布特征及其相互关系以及与渗透率的联系。结果表明:具有不同渗透率的页岩样品表现为较为相近的孔径分布特征但差异较大的喉道分布特征。页岩样品渗透率的大小与孔隙半径没有明显相关关系;喉道大小及其分布特征是控制低渗储层孔隙结构的关键要素之一。渗透率较低页岩样品的喉道以喉道半径小且集中分布为特征,而渗透率较大页岩样品的喉道以喉道半径大呈分散分布但主要以大喉道为特征。喉道特征是研究页岩气储层储集空间和吸附能力的重要部分,在以后对页岩气的勘探开发中应特别注意及重视。     

雅鲁藏布江流域极端降水模拟及预估

为了解雅鲁藏布江流域汛期极端降水的变化规律,推算一定重现期的极端降水量分位数,通过百分位法、Hill图法、年交叉率法选取阈值,借助广义帕累托分布函数（GPD）对流域极端降水频率进行了分析。结果表明：99百分位时的阈值为流域内各站点的最佳阈值,且各站点超阈值序列通过了M-K的平稳性检验,无明显突变。拟合效果通过K-S检验,各站点拟合的极端降水理论频数和实测频数基本相符。尺度参数的大值区位于流域下游,表明该地区的极值波动大;形状参数正值区位于流域中上游地区,说明发生破纪录降水事件的概率较大,拟合结果与实际观测一致。从5年一遇和10年一遇的极端降水值来看,雅江流域除拉孜站外,其他地区降水极值均超过30 mm,日喀则地区的降水极值达50 mm;各地区20年一遇和30年一遇的降水极值增长的非常缓慢。通过与实际极端降水值对比分析得出,GPD拟合计算出的重现期水平基本符合实际,即具有一定的合理性。     

Geoarchaeological evidence on a Late Bronze Age earthquake,Ohrid Basin (North Macedonia)

Geoarchaeological investigations on the northeastern shore of Lake Ohrid revealed 3.5 m thick deepwater lacustrine sediments overlying terrestrial vegetation macrofossils, worked wood and abundant potsherds dated to the Late Bronze Age (LBA). Distinct contact of deepwater sediment with the sub-aerial weathered limestone bedrock point to a sudden increase in lake level. According to radiocarbon data, catastrophic flooding occurred shortly after 1214 yr bc. Because the area is located in a highly active seismic zone, we propose that this event was caused by tectonically induced, metre-scale coseismic subsidence related to faults bordering the Ohrid alluvial plain. Moreover, this event coincides well with a dramatic switch in the habitation and settlement strategy in the region. More important, however, is the finding that the age of the proposed massive tectonic event and change in habitation lies within the interval of the proposed ‘earthquake storm’ in the eastern Mediterranean dated to 1225–1175 bc. As the Ohrid-Korça zone belongs to the same tectonic province, a relationship between the abovementioned earthquakes and the proposed event can be expected. This research therefore might provide the first direct evidence of a large-scale earthquake event linkable to the LBA collapse of Europe's first urban civilisation in the Aegean.     

KT178型取心钻具在共和干热岩钻井中的应用

共和干热岩资源富集于花岗岩地层,硬度高,研磨性强,部分层段裂隙发育,取心困难。针对干热岩地层和取心需求特点,研制一套KT178取心钻具,并配套设计了孕镶金刚石取心钻头。该钻具为单动双管取心钻具,可配套井底动力钻具使用,设计中注重对钻具外管、卡簧等关键部件的强度校核。在GH-01井和GH-02井中,经过两轮实验和优化,钻具逐渐成熟,获取了较完整的岩心样本,满足干热岩勘探取心要求,具备了向页岩气、水资源勘察等具有间断取心需求的同类工程推广应用的条件。     

高温硬岩空气潜孔锤钻头设计

干热岩试验性开发井钻井施工,在高温硬岩的地层条件下,如何实现高效钻进仍存在很多技术难点。空气潜孔锤钻进技术是解决硬岩地层钻进的有效方法之一,潜孔锤钻头是空气潜孔锤钻进的关键器具。根据青海共和干热岩GH-01井空气潜孔锤钻进技术应用情况,分析探讨了空气潜孔锤钻头断齿、掉齿、磨损严重、使用寿命短等问题,从钻头结构设计、钻头材料选取、钻头冷压固齿工艺等几个方面对空气潜孔锤钻头进行了优化。固齿优化过程中采用有限元分析方法,对钻头冷压固齿过盈量进行仿真分析计算,根据分析计算结果确定最优固齿过盈量。通过对潜孔锤钻头结构、材料、加工等优化,为适用于高温硬岩的空气潜孔锤钻头研制提供了借鉴。为提高空气潜孔锤钻进综合效率,为干热岩钻探开发提供了技术支持和技术储备。     

复合动力钻进工艺在干热岩钻井中的应用研究

2011年山东省地矿局在山东省利津县实施了国内第一个干热岩调查评价项目,采用转盘回转钻进,但钻效低、能耗高。为提高在高温硬岩条件下的钻进效率、缩短钻井周期、降低生产成本,2015年在福建省漳州市实施的中国地质调查局东南沿海深部地热HDR-1干热岩科学钻探工程井（井深4000.86 m,孔底温度109 ℃）和2017年在青海省共和县完成的GR1干热岩科学勘探井（井深3705 m,孔底温度236 ℃）,在施工中均探索使用了“转盘+螺杆钻具”复合钻进工艺,并在高温取心段首次测试应用了“转盘+涡轮钻具”复合取心钻进工艺,取得了良好的效果并就下一步研究方向提出了意见和建议,为螺杆钻具和涡轮钻具的深入研究提供了宝贵的高温施工经验,也将为我国干热岩科学钻探与深部地热资源勘探提供新的技术支撑。     

储层致密化与油气充注的关系:以三肇凹陷白垩系扶余油层为例

为了明确松辽盆地三肇凹陷扶余油层储层致密化与油气充注相关性,利用微米CT、流体包裹体显微分析、盆地模拟等方法,研究了该储层微观孔喉特征,且定量分析了其成藏期。根据储层孔隙演化信息分析了研究区储层致密化过程和油气成藏的关系。结果发现:三肇凹陷扶余致密储层岩石类型以长石岩屑砂岩和岩屑长石砂岩为主,孔喉特征表现为窄喉道、宽孔隙、孔喉配置差、微细喉道总体积大等特征。压实作用和胶结作用为储层致密化重要成因,储层致密时间应该在嫩江组末之前。流体包裹体分析结果表明三肇凹陷扶余储层油充注分为早期和晚期,相应的充注时间分别距今77~74 Ma、67~65 Ma,分别对应于嫩江组沉积期和明水组沉积末期。综合对比扶余油层油气成藏历史和储层孔隙演化特征,认为原油充注发生储层致密化之后,即先致密后成藏。     

Comparative Study of Acid and Alkaline Stimulants with Granite in an Enhanced Geothermal System

The Enhanced Geothermal System (EGS) is an artificial geothermal system that aims to economically extract heat from hot dry rock (HDR) through the creation of an artificial geothermal reservoir. Chemical stimulation is thought to be an effective method to create fracture networks and open existing fractures in hot dry rocks by injecting chemical agents into the reservoir to dissolve the minerals. Granite is a common type of hot dry rock. In this paper, a series of chemical stimulation experiments were implemented using acid and alkaline agents under high temperature and pressure conditions that mimic the environment of formation. Granite rock samples used in the experiments are collected from the potential EGS reservoir in the Matouying area, Hebei, China. Laboratory experimental results show that the corrosion ratio per unit area of rock is 3.2% in static acid chemical experiments and 0.51% in static alkaline chemical experiments. The permeability of the core is increased by 1.62 times in dynamic acid chemical experiments and 2.45 times in dynamic alkaline chemical experiments. A scanning electron microscope analysis of the core illustrates that secondary minerals, such as chlorite, spherical silica, and montmorillonite, were formed, due to acid-rock interaction with plagioclase being precipitated by alkaline-rock interactions. Masking agents in alkaline chemical agents can slightly reduce the degree of plagioclase formation. A chemical simulation model was built using TOUGHREACT, the mineral dissolution and associated ion concentration variation being reproduced by this reactive transport model.     

Effect of the Dry Ashing Method on Cadmium Isotope Measurements in Soil and Plant Samples

A dry ashing method is commonly used to remove organic material from samples prior to geochemical analysis. In the course of this study, the Cd isotope ratios of a series of soil and plant reference materials and samples were studied to evaluate the effect of the dry ashing method on measurement results of Cd isotope ratios. The samples were pre‐treated using the dry ashing method and high‐pressure bomb for comparison. The results show that the digestion using high‐pressure bombs did not lead to Cd loss, but using the dry ashing method would cause different proportions of Cd loss. The whole range of Cd isotope difference between two methods was from ?0.07‰ to 3.01‰. There was also an obvious difference in measured Cd isotope ratios from the same leaf sample pre‐treated independently by the dry ashing method, indicating that the amount of Cd loss and the effect on Cd isotope measurement during dry ashing is related to the properties of the samples. Therefore, dry ashing may not be appropriate for the removal of organic material in Cd isotope ratio measurement, especially for samples with high organic contents. The δ^114/110Cd values of reference materials NIST SRM 1573a and GSD‐30 are reported for the first time in this study.     

滇西漕涧地区崇山杂岩带始新世花岗岩的发现及其地质意义

崇山杂岩带为滇西三江造山系西侧边缘的一条重要边界构造,属青藏高原造山带的南东缘.带内岩浆活动强烈,前人认为其主要由晚元古代、中生代的花岗岩组成;而据地质调查发现,带内新生代的岩浆作用十分发育.本文对带内新发现的灰白色黑云二花岗岩进行研究,获得了锆石U-Pb LA-ICP-MS年龄为34.88 Ma和35.25 Ma,表明其侵位于古近纪始新世.岩石地球化学表明,黑云二花岗岩为钾玄质-高钾钙碱性系列的过铝质花岗岩类,稀土元素配分曲线为右倾,其中LREE明显富集,HREE为不同程度亏损,具明显的负Eu异常;富集Rb、Th、Ce、Sm和亏损K、Ba、Ta、Hf、Y等元素,且为淡色花岗岩特征;据锆石Hf同位素测试分析,εHf(t)值为–2.35～+2.33和TDM2为962～1259 Ma,表明了花岗岩岩浆源区为壳幔混合的产物,以及源岩主要源自中元古代—新元古代陆壳基底物质的部分熔融.综合研究认为,始新世黑云二长花岗岩形成于喜马拉雅期碰撞造山向造山晚期转换阶段,是一套典型的"超厚地壳"部分熔融和壳幔相互作用的淡色花岗岩;以及其侵位时间代表了漕涧地区喜马拉雅碰撞造山阶段的完成和造山晚期阶段的开始,且转换时间约为35 Ma.