Occurrence and influence of residual gas released by crush methods on pore structure in Longmaxi shale in Yangtze Plate,Southern China

The composition of gas released under vacuum by crushing from the gas shale of Longmaxi Formation in Upper Yangtze Plate, Southern China was systematically investigated in this study. The effect of residual gas release on pore structures was checked using low-pressure nitrogen adsorption techniques. The influence of particle size on the determination of pore structure characteristics was considered. Using the Frenkel-Halsey-Hill method from low-pressure nitrogen adsorption data, the fractal dimensions were identified at relative pressures of 0−0.5 and 0.5−1 as D₁ and D₂, respectively, and the evolution of fractal features related to gas release was also discussed. The results showed that a variety component of residual gas was released from all shale samples, containing hydrocarbon gas of CH₄ (29.58% −92.53%), C₂H₆ (0.97% −2.89%), C₃H₈ (0.01% −0.65%), and also some non-hydrocarbon gas such as CO₂ (3.54% − 67.09%) and N₂ (1.88%−8.07%). The total yield of residual gas was in a range from 6.1 μL/g to 17.0 μL/g related to rock weight. The geochemical and mineralogical analysis suggested that the residual gas yield was positively correlated with quartz (R²=0.5480) content. The residual gas released shale sample has a higher surface area of 17.20−25.03 m²/g and the nitrogen adsorption capacity in a range of 27.32−40.86 ml/g that is relatively higher than the original samples (with 9.22−16.30 m²/g and 10.84−17.55 ml/g). Clearer hysteresis loop was observed for the original shale sample in nitrogen adsorption-desorption isotherms than residual gas released sample. Pore structure analysis showed that the proportions of micro-, meso- and macropores were changed as micropores decreased while meso- and macropores increased. The fractal dimensions D₁ were in range from 2.5466 to 2.6117 and D₂ from 2.6998 to 2.7119 for the residual gas released shale, which is smaller than the original shale. This factor may indicate that the pore in residual gas released shale was more homogeneous than the original shale. The results indicated that both residual gas and their pore space have few contributions to shale gas production and effective reservoir evaluation. The larger fragments samples of granular rather than powdery smaller than 60 mesh fraction of shale seem to be better for performing effective pore structure analysis to the Longmaxi shale.     

地层含金性评价的分数维研究———以琼西抱板群为例

摘 要　 利用分形理论研究了琼西抱板群金含量分布的分数维结构特征‚并对其含金性作出 评价。结果表明‚较小的分维及具有多标度分形‚有利于金矿化的产出。     

水文地质参数优选的一维寻查法

介绍了一维寻查法的基本原理,并给出了应用实例;实现了计算机自动优选水文地质参数,改变了过去人工凋参的传统方法;同时也指出了该方法的局限性。      

Stock Evaluation of Three Littoral Echinoid Species on the Catalan Coast North-Western Mediterranean

Abstract. We estimated the abundances of the three common littoral echinoid species Paracentrotus lividus, Arbacia lixula and Sphaerechinus granularis in a littoral zone between 0 and 10m depth on the Catalan shores NE Spain. Densities of each species were estimated from a total number of 11 571× 1 m² sampling units deployed at 152 sites along the 13 zones into which the coast was divided. The surface area available in each of these zones was estimated at the scale of the sampling unit 1 m² taking into account the fractal dimension of the shore. The stocks individuals > 2cm test diameter of these species for the whole Catalan shore ≅ 300 km, straight-line distance were estimated to be about 279.1 × 10⁶ individuals for P. lividus , 28.9 × 10⁶ individuals for A. lixula and 10.9 × 10⁶ individuals for S. granularis. These sea-urchins are key species in the regulation of algal communities and some of them P. lividus. S. granularis are of commercial interest. This information will provide a tool for the future monitoring and management of this resource, which now faces diverse pressures of human origin.     

新构造分异的地学信息分析--以山东半岛北部为例

水系图像空间特征与几何空间特征是新构造运动地表综合信息的反映,也是区域新构造差异的两种新的分析手段。新构造运动差异分析表明,山东半岛新构造运动受控于西侧的郯(城)-庐(江)大断裂,次级的NE-NNE向断裂则控制了整个半岛地区的E-W向差异运动。以NE向青(岛)-牟(平)断裂束为界,分为东、西两个新构造活动亚区。西部相对东部在新构造时期抬升,相对抬升幅度达30m以上。     

遥感与GIS的青海湖岸线分维研究

讨论了TM图像以及分形几何学对青海湖岸线问题的求解算法,同时估算了不同像元尺度下,青海湖的岸线长度得出青海湖岸线的分形维数为1.0237,并探讨了其地学意义,研究表明,分形维数不仅是一种可行的表达岸线特征的方法,而且岸线分维数的计算可大大减少工作量和提高工作效率,可见遥感与GIS技术在岸线分维数的计算中,具有十分良好的应用前景。     

闽台建设用地图像数据空间特征分形对比研究

利用2002年闽、台ASTER影像数据,运用分形几何学理论、数理统计方法,对闽台建设用地分布的空间特征进行分析。研究结果表明,分维值是定量刻画土地利用类型空间格局的重要参数,对遥感影像中直接提取土地利用类型的图形因子进行不同区域土地利用分形结构的差异研究,具有快速、方便、准确的性质。闽、台建设用地斑块的空间分布具有分形特征,其空间形态受自然和人文两方面因素,特别是地形地貌和交通的影响十分明显。同时台湾建设用地的平均斑块面积、分维值和规模大的斑块比重均高于福建,反映了闽、台建设用地空间特征的区域差异,这对闽、台两地,特别是福建省加强建设用地规划,合理配置空间资源,及福建省加强中心城市建设和交通规划等方面具有重要的指导意义。     

西秦岭夏河-合作地区断裂构造分形结构特征及成矿预测

西秦岭夏河-合作地区是中国重要的金矿及多金属矿床开发地带,区内断裂构造复杂,构造控矿作用显著。文章利用分形理论方法对夏河-合作地区不同方向断裂构造作定量分析,统计计算断裂构造容量维和信息维,结合矿床空间分布分形特征和矿床Fry分析,探讨研究区构造分形特征及断裂与矿床的空间展布关系。研究结果表明,研究区全部断裂容量维1.2374,北东向断裂容量维0.8229,北西向断裂容量维1.2296,近东西向断裂容量维1.0312,全部断裂容量和北西向断裂容量维处于断裂分形临界值（1.22~1.38）区域,显示研究区断裂构造连通性较好。研究区全部断裂信息维1.1118,北东向断裂信息维1.018,北西向断裂信息维1.2296,近东西向断裂信息维1.0217,北西向断裂信息维处于断裂分形临界值区域,反映北西向对矿床的控制最强。断裂构造分形维数可以表征矿床的沉积部位,以容量维、信息维等值线图以及Fry图划分出3个有利成矿区。     

差异水动力导致黄河口粉质土微结构分形特征变化实例研究

在黄河三角洲北部潮坪上选择典型研究区。区内通向油井的道路的修建使北侧水动力条件明显强于南侧。对两侧原状土样进行粒度成分测试和微观结构观测,并利用分形理论进行分析。结果发现,在水动力作用强区中,粒度分维值随深度的变化曲线大致呈反“S”型,颗粒分布分维值随深度单调递增(表层除外),颗粒定向性分维值随深度的变化曲线呈“S”型;在水动力作用弱区,粒度分维值和颗粒分布分维值随深度单调增大,颗粒定向性分维值随深度的变化曲线呈平缓的反“S”型。这些参数的变化较好地反映了不同深度处沉积物的层化现象。     

黄河三角洲潮滩潮沟近期变化遥感监测

作者选用1986年和2001年两个时相的Landsat TM/ETM+影像,结合遥感、地理信息系统 (GIS) 和分形理论研究了黄河三角洲典型河口岸段潮滩潮沟的发育演变。结果表明：近15年来,挑河口~106站和现行水河口(1976~1996年黄河入海口,下同)~甜水沟岸段分维值D增大,呈顺向演替;其余岸段分维值均减小,表现为逆向演替。人工围垦挤占了大面积潮滩,人工岸线不断向海扩展,其最大推进速率达0.8 km/yr;同时,潮沟长度缩短,最严重的岸段每年减少14.9 km。通过分析表明,人类活动已成为影响三角洲潮滩发育的重要因子,其导致整个三角洲的潮滩体系严重退化,自然形成的潮沟时空谱系不复存在;另外,发育时间长短、入海泥沙、海浪和潮流对潮滩发育演变亦非常重要。目前,黄河三角洲潮滩可分为河口滩、潮控滩、浪控滩和人控滩4大类型。