Enrichissement en uranium authigène dans les sédiments glaciaires de l'océan AustralEnrichments in authigenic uranium in glacial sediments of the Southern Ocean

Four sediment cores from the Polar frontal zone and the Antarctic zone in the Indian sector of the Southern Ocean present an increase of authigenic uranium during glacial periods. We show that this increase in uranium is due to a combination of (i) an increase in the lateral transport of organic matter, (ii) a decrease in the oxygen in deep waters, and (iii) a process of diagenesis. It appears that uranium concentration cannot be used as a proxy of palaeoproductivity in the Southern Ocean, as previously suggested by Kumar et al. in 1995. To cite this article: L. Dezileau et al., C. R. Geoscience 334 (2002) 1039–1046.     

准噶尔盆地车拐地区三叠系成岩作用与孔隙演化

通过岩芯观察、薄片鉴定以及测井和录井资料分析,对准噶尔盆地西北缘车拐地区三叠系储层的物性特征、孔隙类型、成岩作用及储层物性的主控因素进行了研究,认为发育于车拐地区三叠系扇三角洲前缘相带的储层经历了机械压实作用、胶结作用、交代作用、溶蚀作用等多种成岩作用,经过成岩作用和自生矿物特点可知车拐地区三叠系主要现今处于晚成岩阶段B期。压实作用为影响储层物性特征的主要因素,随着埋深的加大压实作用的增强物性随之变差,可使孔隙度减少20%以上;沸石和碳酸盐胶结物的溶蚀可使孔隙度增加达3%,研究区总的孔隙度分布范围主要在6%~18%之间,渗透率分布范围为0.08×10-3～40.0×10-3μm2。     

Celestite formation, bacterial sulphate reduction and carbonate cementation of Eocene reefs and basinal sediments (Igualada, NE Spain)

Petrographic and geochemical studies of an Upper Eocene reef and associated basinal sediments from the mixed carbonate–siliciclastic fill of the south‐eastern Pyrenean foreland basin near Igualada (NE Spain) provide new insights into the evolution of subsurface hydrology during the restriction of a marine basin. The reef deposits are located on delta‐lobe sandstones and prodelta marls, which are overlain by hypersaline carbonates and Upper Eocene evaporites. Authigenic celestite (SrSO₄) is an important component in the observed diagenetic sequences. Celestite is a significant palaeohydrological indicator because its low solubility constrains transportation of Sr²⁺ and SO₄^2? in the same diagenetic fluid. Stable isotopic analyses of carbonates in the reef indicate that meteoric recharge was responsible for aragonite stabilization and calcite cementation. Sulphur and oxygen isotope geochemistry of the celestite demonstrates that it formed from residual sulphate after bacterial sulphate reduction, but also requires that there was a prior episode of sulphate recycling. Meteoric water reaching the reef and basinal areas was most probably charged with SO₄^2? from the dissolution of younger Upper Eocene marine evaporites. This sulphate, combined with organic matter present in the sediments, fuelled bacterial sulphate reduction in the meteoric palaeoaquifer. Strontium for celestite precipitation was partly derived in situ from dissolution of aragonite corals in the reef and basinal counterparts. However, ⁸⁷Sr/⁸⁶Sr data also suggest that Sr²⁺ was partly derived from dissolution of overlying evaporites. Mixing of these two fluids promoted celestite formation. The carbonate stable isotopic data suggest that the local meteoric water was enriched in ¹⁸O compared with that responsible for stabilization of other reefs along the basin margin. Furthermore, meteoric recharge at Igualada post‐dated evaporite deposition in the basin, whereas other parts of the same reef complex were stabilized before evaporite formation. This discrepancy resulted from the spatial distribution of continental siliciclastic units that acted as groundwater conduits.     

障壁坝砂体储层特征与成岩孔隙定量演化模式 ——以鄂尔多斯盆地延长探区本溪组为例

为明确海陆变迁背景下障壁坝砂体成岩孔隙演化规律,运用岩石薄片、扫描电镜及配套能谱、阴极发光等资料,对延长探区石炭系本溪组障壁成因砂体储集特征与成岩作用进行综合分析,并结合砂岩初始孔隙度恢复模型与薄片孔隙定量分析技术,开展基于埋藏热演化历程的储层孔隙演化参数定量评价,建立该区本溪组障壁坝砂岩孔隙定量演化模式。结果表明:储层砂岩以石英砂岩、岩屑质石英砂岩及岩屑砂岩为主;孔隙度、渗透率平均值分别为4.72%和1.22×10^(-3 )μm^2;储集空间以溶蚀扩大孔、粒内孔、晶间孔为主;现今储层主体已达到晚成岩阶段;砂岩初始孔隙度平均值为38.1%,埋藏至今共经历了四个典型的成岩增/减孔阶段,即P_1～T_2(285～208 Ma)"低地温、快埋藏"的大幅减孔阶段(-30.7%)、T_2～J_3(208～153 Ma)"高地温、缓沉降"的溶蚀增孔阶段(+3.9%)、J_3～K_1(153～96 Ma)"高地温、稳埋深"的减孔定型阶段(-6.6%)、K_1至今(96 Ma～)"低地温、晚隆升"的弱改造阶段。     

塔巴庙地区上古生界砂岩成岩作用特征及其储集性分析

鄂尔多斯盆地北部塔巴庙地区上古生界发育一套低孔低渗致密砂岩储层，储集空间以溶蚀微孔、蜂窝状溶孔和高岭石晶间隙为主，孔喉以细——微细为主。成岩作用决定了砂岩内部储集空间特征和储集性能，主要表现在较强的压实作用和胶结作用使砂岩的原生孔隙很少得到保存；较弱的溶蚀作用和强的蚀变作用使砂岩储集空间以微孔、超微孔为主，具有孔径小喉道细的特征，这是砂岩储集物性特别是渗透率偏低的直接原因。     

陕川丁家林-太阳坪金矿带成矿机理

丁家林-太阳坪金矿带与丁家林-太阳坪脆-韧性剪切带同位分布、同能源作用、同步生成，是脆-韧性剪切变形形成的石英脉型金矿，总体走向NE，主要由丁家林和太阳坪2个金矿床组成，分石英单脉、单脉密集带、复脉带3个亚型。丁家林以含Au石英复脉为主，太阳坪以含Au石英单脉为主；成矿物质来源于富含Si质的志留系黄坪组，成矿流体主要是构造水；内生成矿作用分脆．韧性剪切变形-构造分异热液期和韧-脆性剪切变形-构造分异热液期，与2期脆-韧性剪切变形相对应，第2期为主成矿期。其成矿机理是脆-韧性剪切变形动力成岩成矿。     

热对流成岩作用的基本特征与研究意义

介绍了热对流产生的条件与地质背景,指出火成侵入体、盐丘和活跃断层周围等温线陡倾斜场所易发生热对流成岩作用。综述了岩浆成因热对流的岩石学记录,包括热变质作用、突然升温—逐渐降温的自生矿物组合和相对高温的自生矿物类型,分析了自生伊利石的K/Ar年龄在热对流成岩作用研究中的作用。阐述了热对流成岩作用对盆地动力学、砂岩储层和油气运移研究的意义。     

Interaction of glucose and cellulose with hydrogen sulphide and polysulphides

This paper describes simulation experiments in which glucose and cellulose were reacted with polysulphide and hydrogen sulphide at ambient temperatures in an aqueous environment. Organic sulphur containing compounds were formed that yield several thiophenes upon pyrolysis/evaporation. The experiments show that interaction of carbohydrates with hydrogen sulphide or polysulphides is a possible way for carbohydrates to react in very recent sediments. From the results of this study it can be concluded that carbohydrate carbon can be preserved in sediments in a form that is resistant to microbial attack and that will have a greater potential for survival during diagenesis than the carbohydrate precursor.     

陆相断陷湖盆层序对成岩演化控制作用探讨——以东营箕状断陷湖盆古近系沙河街组为例

以层序地层研究为基础,根据铸体薄片、扫描电镜、镜质体反射率、X衍射及地球化学等分析,对东营凹陷沙河街组层序与成岩的关系进行了系统研究。研究结果表明:不同层序部位具有不同的成岩响应,低位体系域主要发育微晶方解石胶结、硬石膏胶结、黄铁矿胶结等,湖盆扩张体系域主要发育有铁碳酸盐胶结、粘土矿物胶结等;高位体系域主要发育有白云石胶结、铁白云石胶结、溶蚀作用、粘土矿物胶结等;层序界面附近主要发育溶蚀现象和铁碳酸盐岩胶结现象。层序发育过程中,原始水介质条件及元素富集规律是引起早期成岩响应的主要因素,并对早期的成岩物质组分造成强烈影响;讨论了层序对成岩演化的控制作用,主要体现在3个方面:a.层序发育控制了原始成岩组分,进而控制后期成岩改造;b.早期成岩作用对层序发育过程具有一定的响应关系,后期成岩改造掩盖了部分成岩响应;c.层序界面通过河流作用、沉积间断减缓压实作用、后期成岩流体的侵入作用对成岩演化造成影响。