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11.
A review of the occurrence, form and origin of C-bearing species in the Khibiny Alkaline Igneous Complex, Kola Peninsula, NW Russia 总被引:4,自引:0,他引:4
The Khibiny Complex hosts a wide variety of carbon-bearing species that include both oxidized and reduced varieties. Oxidised varieties include carbonate minerals, especially in the carbonatite complex at the eastern end of the pluton, and Na-carbonate phases. Reduced varieties include abiogenic hydrocarbon gases, particularly methane and ethane, dispersed bitumens, solid organic substances and graphite. The majority of the carbon in the Khibiny Complex is hosted in either the carbonatite complex or within the so-called “Central Arch”. The Central Arch is a ring-shaped structure which separates khibinites (coarse-grained eudialite-bearing nepheline-syenites) in the outer part of the complex from lyavochorrites (medium-grained nepheline-syenites) and foyaites in the inner part. The Central Arch is petrologically diverse and hosts the major REE-enriched apatite–nepheline deposits for which the complex is best known. It also hosts zones with elevated hydrocarbon (dominantly methane) gas content and zones of hydrothermally deposited Na-carbonate mineralisation. The hydrocarbon gases are most likely the product of a series of post-magmatic abiogenic reactions. It is likely that the concentration of apatite-nepheline deposits, hydrocarbon gases and Na-carbonate mineralisation, is a function of long lived fluid percolation through the Central Arch. Fluid migration was facilitated by stress release during cooling and uplift of the Khibiny Complex. As a result, carbon with a mantle signature was concentrated into a narrow ring-shaped zone. 相似文献
12.
以浓硫酸为催化剂,研究了对羟基苯甲酸和异丙醇合成对羟基苯甲酸异丙酯的工艺条件。对影响产率的因素进行了探讨:实验表明,在以7%的浓硫酸为催化剂,反应温度为120℃,醇酸摩尔比为4:1,反应时间为5h的最佳条件下,合成了羟基苯甲酸异丙脂,通过多次重结晶的方法纯化产品,产率可达85.5%,并通过熔点仪、红外光谱等手段对产品加以表征,验证了产品具有较高的纯度。该法简单、快速、产率高、纯度好,具有较高的实用价值。 相似文献
13.
研究了N甲基对二甲胺基苯乙烯吡啶碘盐系列化合物的合成、分离方法,通过可见吸收、MS谱、HNMR 谱及氮素测定分析产物,证实了其结构和理论预期的一致性 相似文献
14.
文章概述了漓江流域水环境现状,分析了存在的主要问题,阐明了流域水灾频繁、水环境污染的成因,指出了流域森林结构欠合理,调蓄能力不足,导致了流域洪涝、干旱频繁,枯水期长,水资源短缺;流域生活与生产排污,造成枯水期水污染。因而需进行深入的科学研究、绿化、兴修水利工程、实施节水技术、严格管理、科学调配水资源等综合举措,实现流域的可持续发展。 相似文献
15.
用固相反应法和sol-gel法合成了不同类型的磷灰石(AP),并采用TEM、XRD、IR、BET比表面积法及静、动态吸附等方法研究了不同AP的比表面积、结晶度、晶胞参数、结晶尺寸、晶格缺陷度、Ca/P摩尔比和煅烧温度等与吸氟能力的关系,结果表明:结晶度高、晶粒大的AP有较小的吸氟量,属表面单分子层化学络合吸附机理;酸活化的AP有较大的吸氟量,属溶解-沉淀与沉淀物表面纳米尺寸效应吸附的复合去氟机理;具纳米尺寸的HAP在常温、常压、无二次污染、小于11mg/L的低含氟浓度废水中且不酸化情况下有较大吸氟量,属纳米尺寸效应吸附机理。 相似文献
16.
水热条件下利用微波加热从粉煤灰合成沸石研究 总被引:14,自引:0,他引:14
着重选用NaOH水溶液为反应前驱物, 通过改变反应温度、NaOH浓度与合成时间等参数, 在水热条件下利用微波加热直接对粉煤灰进行晶化, 合成得到了浊沸石、菱沸石、NaP1沸石3种沸石.粉煤灰转化为沸石率约15%~40%.研究表明: (1) 反应体系在15min左右即有合成沸石产生, 30min左右合成沸石转化率达到最佳; (2) 为保证沸石晶核生成和晶体的生长, 反应体系的溶液/粉煤灰比不应低于2.5; (3) 在溶液/粉煤灰比为2.5时, 应控制加热时间在30min左右. 相似文献
17.
利用钾长石粉水热合成13X沸石分子筛的实验研究 总被引:11,自引:0,他引:11
对综合利用钾长石提钾工艺中的重要高附加值副产品13X沸石分子筛的合成进行了实验研究。对福建沙县的钾长石粉加入配料NaCO3进行焙烧实验,确定培烧的最佳工艺参数为:钾长石粉:NaCO3=1:1.30(摩尔比),焙烧温度为845℃,焙烧时间为150min;优化的水热合成条件为M2O/SiO2(mo1)=1.50,H2O/M2O(mo1)=40.0,合成时间为8h,晶种加入量为9.0%。对合成样品化学成分分析、X射线物相分析、红外光谱分析、扫描电镜分析表明,合成13X沸石分子筛结晶完好,性能优良.水热反应经由溶解水合反应和聚合浓缩反应两大阶段。 相似文献
18.
全极化SAR数据在地表覆盖/利用监测中的应用 总被引:2,自引:0,他引:2
SIR-C/X-SAR是运行在地球轨道上的第一个多波段(L、C、X)全极化(HH、VV、VH和HV)成像雷达系统,该系统具有极化测量和干涉测量功能。全极化雷达测量每一个像元的全散射矩阵,所获取的信息非常丰富。但是,由于这些极化合成图像具有较高的相关性,导致了图像信息提取精度的降低。本文基于新疆和田地区的SIR-CL波段全极化雷达数据,利用全散射矩阵的特点合成了HH-VV极化相关图像、极化度图像、目标增强图像和相位差图像。这些图像相关性小,地表覆盖信息丰富,提高了全极化SAR数据在实验区信息提取的准确度。 相似文献
19.
INFLUENCE OF THE SURFACE AIR TEMPERATURE OVER ASIAN-PACIFIC REGION ON THE SUMMERTIME NORTHEASTERN ASIAN BLOCKING HIGH*
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Synthesis analysis and singular value decomposition (SVD) methods were used to study the impact of surface air temperature (SAT) over Asian-Pacific region on the summertime northeastern Asian blocking high (NABH) with NCEP/NCAR Reanalysis Data.The results showed that 500 hPa geopotential height and SAT fields over Asian-Pacific region shared the similar pattern of East Asian Pacific (EAP) wave train;there was steady remote response relationship between the EAP wave train in summer and the "+-+" pattern of tropical SAT in zonal direction from former winter to summer;there were two relative negative(positive) Walker circulations over the tropical Indian Ocean and Pacific when being more(less) summertime NABH. The influence of sea surface temperature anomaly (SSTA) on the summertime NABH was possibly as follows.The special distribution of SSTA in tropical zonal direction continuously forced the tropical convection and zonal circulation from former winter to summer,and led them to act anomaly.Finally the abnormal conditions were transported to middle-high latitudes through EAP wave train and yielded the advantageous or disadvantageous atmospheric circulation background for the summertime NABH. 相似文献
20.
In this work, the possible exploitation of fiber-reinforced composites in the context of maritime transportation of compressed natural gas (CNG) is investigated. In addition to a more conventional steel configuration, two different fiber materials, carbon and glass, are considered as construction materials for pressure vessels (PVs) to be stored on board ships, with thickness optimized by FEM analysis.The considered scenario is represented by the transportation of CNG from an offshore well to a terminal on shore. Fleets of ships carrying CNG in pressure vessels manufactured with the investigated materials are generated by means of a ship synthesis model (SSM) software and compared on the basis of technical and economical indicators.The choice of the construction material influences considerably the weight of the PVs, which represent a major item of total ship weight and reflects directly on the general transport performances in terms of resistance, seakeeping and reliability in the service. On the other hand, capital as well as operating expenditures are considerably affected by the choice. When exploring the design space, the ship synthesis model is able, at a preliminary stage of the design, to account for the various technical and economical aspects, their implications and relationships. Results are presented of computations carried out in a specific case, identified by the annual gas production and other characteristics of the well terminal and a cruising route for the ships. The comparison is carried out on the basis of the cost per transported unit of gas and of the percentage of success in the transportation process. The computations show that the choice of the PV material has a key influence on the results in terms of optimal number, dimensions and speed of the ships. 相似文献