Multicomponent ionic diffusion in porewaters: Coulombic effects revisited

The diffusion of an ion in porewaters cannot occur independently of the other ions in solution as a result of Coulombic coupling, as well as from other effects not considered here. Unfortunately, a longstanding disagreement exists about the correct form and meaning of the equations that describe Coulombic coupling in porewaters, i.e., Ben-Yaakov [Am. J. Sci. 281 (1981) 974] vs. Lasaga [Am. J. Sci. 281 (1981) 981]. This paper re-examines this controversy by reformulating the problem starting from fundamental concepts of mass and charge conservation. We show that these antagonistic formulations are both valid and, in fact, equivalent, when the different interpretations of charge balance are resolved. Most of the disagreements between Ben-Yaakov and Lasaga are then shown to result from differing methods of solution, not fundamental disparities in their models. We note, however, that the explanation for the concept of “stationary” gradients of nonreacting ions as given Ben-Yaakov is inaccurate, and such gradients do lead to diffusive fluxes that are counterbalanced by electrochemical migrational fluxes to produce no net flux (excluding advective flux). We further find that the bicarbonate diffusive flux will not balance the diffusional charge flux of sulfate during its reduction if advection is present. This latter imbalance generates compensating fluxes in the other nonreacting ions. We have applied our theory to a simplified case of sulfate reduction in a marine sediment. The results show that nonreacting ions do diffuse and that with normally expected values of porewater advection, the ratio of the bicarbonate to the sulfate flux can be far different than the ideal value of −2.     

非均质土坝稳定性的渗流场和应力场耦合分析

綦于多孔介质的渗流特性和土的非线性本构关系，研究了渗流场与应力场的耦合效应，并针对一实际十坝建立了非线性耦合分析模型，探讨了位于软基之上的非均质土坝的渗流与应力耦合规律。分析结果表明，在渗流作用下，坝休和坝基中渗流与应力的相互作用是不应忽视的，其作用结果将会使土坝、特别足防渗心端附近应力水平和渗透坡降均有不同程度的提高，表明考虑渗流场和应力场耦合作用的计算结果对土坝稳定安全性不利。     

重金属迁移转化模型研究

大量重金属污染物迁移转化的现象和研究成果都表明重金属以泥沙颗粒为载体迁移转化,描述重金属在天然水体中的迁移转化必须紧紧抓住泥沙颗粒运动及重金属与泥沙之间的转化关系进行.为此在对现有的重金属迁移转化数学模型进行概括分类的基础上,根据水沙运动与污染物相互作用关系,分析了泥沙颗粒运动及重金属吸附解吸不平衡过程,并结合水沙数学模型,建立了重金属迁移转化的耦合模型.同时在模型合理性分析的基础上,对模型进行了计算分析,分析表明模型能够合理地反映重金属污染物在水体中的迁移转化过程.     

某滑坡软弱夹层抗剪强度取值方法的研究

文章主要针对软弱夹层抗剪强度取值所存在的争议，通过对贵州新街子滑坡的软弱夹层分别选择比例极限、屈服极限及峰值作为剪应力值，采用最小二乘法获得比例抗剪强度、屈服抗剪强度和峰值抗剪强度。以参数选取中应用较为成熟的反分析方法推求力学性质参数c、φ值作为判据对以上3种参数进行比较。计算结果表明：本滑坡软弱夹层中由于含泥量较大，而且粘塑性较强，屈服抗剪强度和反分析得到的抗剪强度偏差最小，比例抗剪强度偏差最大，峰值抗剪强度居中。并以此3种抗剪强度进行天然状态下滑坡稳定性验算，结果表明选用比例极限抗剪强度与当前滑坡的地质现象不符，选用峰值极限抗剪强度安全储备较低，而选取屈服极限抗剪强度最为合理。用此参数进行设计，滑坡已经得到了良好的治理。在取值研究中认为采用试验与反分析相结合的方法确定滑坡稳定性计算参数是比较合理的。以上结论为滑坡中软弱夹层抗剪强度取值的选择提供了重要的依据。     

Plastic flow strength of jadeite and diopside investigated by microindentation hardness tests

Microindentation hardness tests were performed on jadeite and diopside, being end members of the omphacite solid solution series. At temperatures between 300 and 750 °C, the hardness of jadeite ranges from 7.4 to 8.5 GPa, that of diopside from 4.9 to 6.1 GPa. Jadeite is significantly stronger than diopside in the low-temperature plasticity regime. Normalization of the hardness-derived yield stress with respect to the shear modulus considerably reduces the strength contrast. The normalized Peierls stress is identical for jadeite and diopside. This indicates that jadeite and diopside belong to the same isomechanical group. The hardness-derived yield stress for jadeite as well as for diopside is used to estimate flow law parameters for the low-temperature plasticity regime.     

谈县级地震部门依法管理建设工程抗震设防要求

以山西省祁县依法管理工程抗震设防要求为例，论述了强制性审核、确定一般工业、民用建设工程抗震设防要求的重要性及其深远意义。结合工作实际．总结了部分依法行政、规范管理和落实抗震设防要求的经验。     

Knickpoint recession rate and catchment area: the case of uplifted rivers in Eastern Scotland

Knickpoint behaviour is a key to understanding both the landscape responses to a base‐level fall and the corresponding sediment fluxes from rejuvenated catchments, and must be accommodated in numerical models of large‐scale landscape evolution. Knickpoint recession in streams draining to glacio‐isostatically uplifted shorelines in eastern Scotland is used to assess whether knickpoint recession is a function of discharge (here represented by its surrogate, catchment area). Knickpoints are identified using DS plots (log slope versus log downstream distance). A statistically significant power relationship is found between distance of headward recession and catchment area. Such knickpoint recession data may be used to determine the values of m and n in the stream power law, E = KA^mSⁿ. The data have too many uncertainties, however, to judge definitively whether they are consistent with m = n = 1 (bedrock erosion is proportional to stream power and KPs should be maintained and propagate headwards) or m = 0·3, n = 0·7 (bedrock incision is proportional to shear stress and KPs do not propagate but degrade in place by rotation or replacement). Nonetheless, the E Scotland m and n values point to the dominance of catchment area (discharge) in determining knickpoint retreat rates and are therefore more consistent with the stream power law formulation in which bedrock erosion is proportional to stream power. Copyright © 2005 John Wiley & Sons, Ltd.