论湖南柿竹园多金属矿床成岩成矿的化学模式─—与毛景文先生等商榷

从湖南柿竹园多金属矿床成岩成矿的事实出发，用化学基本定律对其矽卡岩的形成，蚀变及成岩成矿的化学反应方程式进行研讨，建立了比较符合矿床实际与地球化学理论的化学模式。认为地球科学与化学是在相互交叉，相互渗透，相互促进中共同发展的。     

氟离子对在河口区存在形态的理论研究

利用Davies离子强度校正方程,把在标准条件下获取的氟离子对的化学稳定数校正到35%的海水条件下,并应用逐步凑分法计算出F-离子对的几种存在形式:游离态F-占49.9%,MgF+占46.8%,其余为CaF+和NaF0.     

干酪根化学降解产物的碳同位素组成研究

采用一系列温和的化学降解法对松辽盆地南部嫩江组烃源岩的干酪根进行连续的选择性化学降解，并对不同降解产物进行色谱—同位素比值质谱分析。研究表明碱性水解和脱硫产物以一元脂肪酸和正构烷烃为主，其中正构烷烃碳同位素分布曲线呈现一定的“负倾”（即随碳数增加呈现逐渐贫13C）趋势；一元脂肪酸以C16和C18为主，具有明显的偶碳优势，与同碳数的正构烷烃具有相似的碳同位素组成。氧化产物则以一元脂肪酸和α,ω 二元脂肪酸为主，一元脂肪酸低碳数部分呈现“负倾”趋势，高碳数部分则呈现“正倾”的趋势；α,ω 二元脂肪酸与低碳数的一元脂肪酸具有相似的分布，表明它们可能具有相同的母源。对比研究表明JL 30抽提物中正构烷烃可能存在混源的影响，其碳同位素组成是多源混合的结果。     

入湖河道生态修复工程对水流流速的影响研究

在河流中开辟生化反应区、直接布设仿生填料净化河流微污染水体可以达到改善入湖水质、减少投资、降低能源消耗的目的。但在河道内直接布设填料势必会对河流的水动力条件及其河流原有的使用功能造成一定的影响。从填料给水流带来的阻力、流速及糙率变化等方面进行河道内直接布设生物填料对河流水动力条件的影响试验分析。结果表明,由于河道流速不大(属于缓流水体),9根/m2的填料布设密度对水流的扰动作用程度不高,填料段的糙率仅为无填料段糙率的1.08倍,不会对河道的泄水能力造成影响。     

复方化学消毒剂中苯扎氯铵的高效液相色谱测定

建立了一种测定复方化学消毒剂中苯扎氯铵成分十二烷基二甲基苄基氯化铵、十四烷基二甲基苄基氯化铵和十六烷基二甲基苄基氯化铵的反相离子对高效液相色谱法。色谱柱为Platisil ODS(5μm,250 mm×4.6mm),流动相为甲醇-0.2 mol/L己烷磺酸钠(含1%三乙胺,V/V,用高氯酸调节至pH=6.0,体积比85∶15),紫外220 nm检测。用己烷磺酸钠作为离子对试剂,增强了苯扎氯铵成分的保留,三乙胺作为扫尾剂,通过抑制固定相表面残存的硅羟基对苯扎氯铵成分的吸附,减少了色谱峰拖尾。3种苯扎氯铵成分分离良好,标准曲线的线性范围分别为0.002～5 mg/mL、0.005～10 mg/mL和0.005～10 mg/mL,检测限分别为0.0005 mg/mL、0.001mg/mL和0.001 mg/mL。方法具有良好的准确度和精密度,在测定低浓度样品时优势明显。实际用于测定苯扎氯铵消毒液和医用消毒纸巾中3种苯扎氯铵成分的含量,回收率为99.3%～104.1%,日内和日间测定相对标准偏差(RSD)均小于2.0%。     

黑龙江绥芬河市北寒葱河河谷地下水水质保护及开发利用建议

为掌握绥芬河市北寒葱河河谷地下水的水质状况,向地方提供合理的水资源开发建议,本研究以地质、水文地质调查、水样采集等手段为基础,利用模糊综合评价法和层级阶梯法分别进行了研究区地下水水质和污染状况评价,应用物探测试、抽水试验等原位测试技术论证了区域地下水的富水性。以上工作基本查明了研究区地下水的水量和水质现状.认为研究区裂隙承压水一般为Ⅰ~Ⅲ类水质,污染等级为未污染水,水质状况较好,污染程度较低,宜于饮用;中生代构造破碎带涌水量可达350m3·d-1以上,建议地方政府应重点围绕构造破碎带开展物探找水,并开展地下水源地分区保护规划.     

Fuzzy process capability indices for quality control of irrigation water

Water covers over 70% of the Earth surface and is a very important resource to people and the environment. Water pollution affects drinking water, rivers, lakes and oceans all over the world. This consequently harms human health and the natural environment. Water pollution can also affect the crops. So, water pollution is an important issue for humanity. Therefore, the control of irrigation water is a necessity. In this paper, a methodology based on process capability indices (PCIs) has been presented to control the levels of pH, dissolved oxygen (DO) and temperature (T) in dam’s water for irrigation. Fuzzy PCIs have been proposed for this aim. The fuzzy estimates of $ \hat C_p Water covers over 70% of the Earth surface and is a very important resource to people and the environment. Water pollution affects drinking water, rivers, lakes and oceans all over the world. This consequently harms human health and the natural environment. Water pollution can also affect the crops. So, water pollution is an important issue for humanity. Therefore, the control of irrigation water is a necessity. In this paper, a methodology based on process capability indices (PCIs) has been presented to control the levels of pH, dissolved oxygen (DO) and temperature (T) in dam’s water for irrigation. Fuzzy PCIs have been proposed for this aim. The fuzzy estimates of and are obtained for pH, DO, and T based on Buckley’s interval estimation approach and based on fuzzy specification limits. An application has been made for Kesikk?prü Dam in Ankara, Turkey. In this paper, Buckley’s approach is re-arranged to obtain a triangular fuzzy membership function because it cannot be obtained from Buckley’s approach in some situation.     

环境矿物材料治理镉（Cd^2＋）污染研究进展

近年来,环境矿物材料以其经济、有效、无二次污染等特点,在重金属废水处理和土壤修复方面显示出了众多优势,可替代传统的镉污染处理方法。本文综述了国内外环境矿物材料在处理镉污染方面的研究进展,并对今后应用环境矿物材料治理镉污染提出了一些建议。     

河北滦南滨海湿地土壤重金属污染特征及评价

滨海湿地作为一种具有多种功能和蕴含丰富资源的生态系统，是人类重要的生存环境之一。湿地土壤重金属污染问题是当前湿地科学领域内的热点话题。为研究河北省滦南滨海湿地重金属污染特征，本文利用单因子指数法、内梅罗综合污染指数法和地累积指数法对重金属污染状况进行评价。结果表明：铜（Cu）、锌（Zn）、铬（Cr）、铅（Pb）、镉（Cd） 的单因子质量指数均小于1.0，说明研究区重金属含量小于土壤背景值，土壤未受到污染。内梅罗综合指数法Cu、Zn、Cr、Pb、Cd 指数均小于0.7，表明滦南湿地土壤重金属污染水平处于未污染。湿地各区域重金属地累积指数为无污染或较轻污染，其中Pb 污染为较轻污染，监测点主要与人类活动有关。利用地累积指数分析认为Pb 在湿地北区为轻度污染水平，经调查发现该区域主要为居民点，人类活动频繁，其他重金属均无污染。河北滦南滨河湿地土壤未受到重金属污染，湿地土壤环境较好。     

Heavy metal release by peat erosion in the Peak District,southern Pennines,UK

Upper North Grain (UNG) is a heavily eroding blanket peat catchment in the Peak District, southern Pennines, UK. Concentrations of lead in the near‐surface peat layer at UNG are in excess of 1000 mg kg⁻¹. For peatland environments, these lead concentrations are some of the highest globally. High concentrations of industrially derived, atmospherically transported magnetic spherules are also stored in the near‐surface peat layer. Samples of suspended sediment taken during a storm event that occurred on 1 November 2002 at UNG, and of the potential catchment sources for suspended sediments, were analysed for lead content and the environmental magnetic properties of anhysteretic remanent magnetization (ARM) and saturation isothermal remanent magnetization (SIRM). At the beginning of the storm event, there is a peak in both suspended sediment and associated lead concentration. SIRM/ARM values for suspended sediment samples throughout the storm reveal that the initial ‘lead flush’ is associated with a specific sediment source, namely that of organic sediment eroded from the upper peat layer. Using the magnetic ‘fingerprinting’ approach to discrimination of sediment sources, this study reveals that erosion of the upper peat layer at UNG is releasing high concentrations of industrially derived lead (and, by inference, other toxic heavy metals associated with industrial particulates) into the fluvial systems of the southern Pennines. Climate‐change scenarios for the UK, involving higher summer temperatures and stormier winters, may result in an increased flux both of sediment‐associated and dissolved heavy metals from eroding peatland catchments in the southern Pennines, adversely affecting the quality of sediment and water entering reservoirs of the region. Copyright © 2005 John Wiley & Sons, Ltd.