Geochemical signal of seasonality in annually laminated organic- carbonate sediments in Shira lake(Khakasia)

正1 Introduction The most valuable for the task of climate reconstruction are the time series with an annual resolution,which allows to reveal natural periodicity and pass to the search for mechanisms of regional and global climatic changes.Bottom sediments of lakes are one of the best climate archives in addition to tree ring series,ice cores etc.     

Saddle dolomite and calcite cements as records of fluid flow during basin evolution: Paleogene carbonates,United Arab Emirates

Field observations indicate that tectonic compression, anticline formation and concomitant uplift events of marine Paleogene carbonates in eastern United Arab Emirates, which are related to the Zagros Orogeny, have induced brecciation, karstification, and carbonate cementation in vugs and along faults and fractures. Structural analysis, stable isotopes and fluid inclusion microthermometry are used to constrain the origin and geochemical evolution of the fluids. Fluid flow was related to two tectonic deformation phases. Initially, the flux of moderately ⁸⁷Sr-rich basinal NaCl–MgCl₂–H₂O brines along reactivated deep-seated strike-slip faults have resulted in the precipitation of saddle dolomite in fractures and vugs and in dolomitization of host Eocene limestones (δ¹⁸O_V-PDB −15.8‰ to −6.2‰; homogenization temperatures of 80–115 °C and salinity of 18–25 wt.% eq. NaCl). Subsequently, compression and uplift of the anticline was associated with incursion of meteoric waters and mixing with the basinal brines, which resulted in the precipitation of blocky calcite cement (δ¹⁸O_V-PDB −22‰ to −12‰; homogenization temperatures of 60–90 °C and salinity of 4.5–9 wt.% eq. NaCl). Saddle dolomite and surrounding blocky calcite have precipitated along the pre- and syn-folding E–W fracture system and its conjugate fracture sets. The stable isotopes coupled with fluid-inclusion micro-thermometry (homogenization temperatures of ≤50 °C and salinity of <1.5 wt.% eq. NaCl) of later prismatic/dogtooth and fibrous calcites, which occurred primarily along the post-folding NNE–SSW fracture system and its conjugate fracture sets, suggest cementation by descending moderately ⁸⁷Sr-rich, cool meteoric waters. This carbonate cementation history explains the presence of two correlation trends between the δ¹⁸O_V-PDB and δ¹³C_V-PDB values: (i) a negative temperature-dependent oxygen isotope fractionation trend related to burial diagenesis and to the flux of basinal brines, and (ii) positive brine-meteoric mixing trend. This integrated study approach allows better understanding of changes in fluid composition and circulation pattern during evolution of foreland basins.     

宇地系统场沉积响应范例：蓟县系雾迷山巨旋回层序及节律

燕辽拗拉谷盆地是一个具有全球性对比意义的典型碳酸盐岩盆地。文中提出建立雾迷山亚系和相应统的划分方案,并指出蓟县系雾迷山亚系（MPSSⅡ）时期,属于盆地巨旋回的造礁沉积平衡补偿形成阶段,沉降幅度和沉积厚度巨大,发育有代表不同沉积环境的多种类型叠层石,在层序上构成明显的沉积韵律,并显示出受米兰科维奇周期、小行星云周期和银道面周期控制形成的不同级次的宇地系统沉积旋回韵律。同时,由于山海关古陆的周期性隆升作用,导致由热水硅质形成的燧石层和由红色物源输入形成的不同级次沉积层序,更为宇地系统控制层序的周期性增添了色彩。总之,蓟县系雾迷山期巨旋回是受宇地系统场控制成因的沉积响应的典范。科学探索与实践证明只有建立宇宙观的地球科学领域,才能不断地开拓地球科学研究的新视野。     

Early Cretaceous atmospheric pCO2 levels recorded from pedogenic carbonates in China

Pedogenic carbonates were collected from Early Cretaceous strata in Sichuan and Liaoning, China. These paleosol carbonates and calcareous paleosols were evaluated in order to reconstruct atmospheric CO₂ concentrations during the Early Cretaceous using a paleosol barometer. Using the isotopic ratios of pedogenic carbonates from Early Cretaceous (early-middle Berriasian, early Valanginian) strata in Sichuan Basin, averaged atmospheric pCO₂ is estimated to have been 360 ppmv in the early-middle Berriasian and a mean value of 241 ppmv in the early Valanginian. In the late Barremian in western Liaoning, however the average was 530 ppmv, with a range of 365 ppmv and 644 ppmv, lower than previous estimates of pCO₂ for these time periods, consistent with the suggestion of overall climate cooling and paleotemperature fluctuation during the Early Cretaceous. This indicates that not all of the Cretaceous was a high or continuous CO₂ greenhouse, especially during Early Cretaceous.     

Methane gas Seeps Along the Oxic/Anoxic Gradient in the Black Sea: Manifestations, Biogenic Sediment Compounds and Preliminary Results on Benthic Ecology

Abstract. Sediment parameters (grain size, organic content, chloroplastic pigments, Adenylates, Potential hydrolytic activity and electron transport system activity) and benthic biota were studied in methane seep area south-west of the Crimean Peninsula in the Black Sea over a depth range from 60 to 260m. A control transect with similar depths was performed in an adjacent nonseep area. Methane seepage in this region occurs from 35 to ˜ 85m depth, passing the oxic anoxic interface zone at 130 to 180m. The methane seep areas were characterized by abundant carbonate precipitates which occurred in various shapes from small, flat structures to tall chimneys with increasing anoxia. The carbonates were associated with distinct bacterial mats. Most of the measured biochemical parameters in the sediment were quite similar in the seep and nonseep areas. The content of organic matter was higher and grain size was more uniform in the nonseep areas. However, the seep areas were charaterized by highter proportions of the larger fauna (size classes 0.5–1 mm and ≥ 1mm) as well as increased total numbers of benthic fauna in the suboxic and upper anoxic zone. The animals did not show any seep-specific adaptations. In addition to methane seepage, highly variable hydrochemical and sedimentary conditions on the lower shelf and upper slope may also play an important role in structuring the composition and distribution of the benthic fauna.     

Magnetic susceptibility variations of the Ediacaran cap carbonates in the Yangtze platform and their implications for paleoclimate

Magnetic susceptibility (MS) data were obtained from 11 sections of the Doushantuo (Ediacaran) cap carbonate that directly overlies the Nantuo glacial diamictite in the southeastern margin of the Yangtze platform. The MS data revealed two regionally correlatable peaks at the bottom and top of the cap carbonate, separated by an interval of low values. The lower MS peak coincides with high percentage of insoluble siliciclastic residues that are compositionally identical to the matrix of the underlying diamictite, suggesting its origin controlled mainly by detrital components during the first phase of cap carbonate deposition at the end of the glaciation. The upper MS peak is associated with high clay content and iron sulfides, and can be interpreted as either derived from enhanced greenhouse weathering that could have brought more terrigenous components into the ocean, or the result of ocean anoxia at the late stage of cap carbonate deposition that could led to formation of abundant iron sulfides. The regionally consistent MS curves from the cap carbonates provided the first geophysical record for the rapid climate change from icehouse to greenhouse conditions in the aftermath of the Neoproterozoic “snowball Earth” event.     

B同位素分馏系数α4—3的研究进展

B同位素分馏系数α4-3,是海洋生物碳酸盐B同位素恢复古海水pH理论公式中的关键因素之一,近年来,此领域的研究取得了许多重要的成果,但由于所涉及的理论尚不完善,随着研究的不断深入,提出的问题也逐渐增多。对近年来国内外理论和实验的研究成果进行了综述,并对其今后的研究前景进行了展望。     

Late Pleistocene and Holocene cool‐water carbonates of the Western Mediterranean Sea

Post‐glacial, neritic cool‐water carbonates of the Western Mediterranean Sea were examined by means of hydroacoustic data, sediment surface sampling and vibrocoring to unravel geometries and to reconstruct sedimentary evolution in response to the last sea‐level rise. The analysed areas, located on the Alboran Ridge, in the Bay of Oran, and at the southern shelf of the island of Mallorca, are microtidal and bathed by oligotrophic to weakly mesotrophic waters. Seasonal water temperature varies between 13 °C and 27 °C. Echosounder profiles show that the Bay of Oran and the southern shelf of Mallorca are distally steepened ramps, while the Alboran Ridge forms a steep‐flanked rugged plateau around the Alboran Island. In the three areas, an up to 10 m thick post‐glacial sediment cover overlies an unconformity. In Oran and Mallorca, stacked lowstand wedges occur in water depths of 120 to 130 m. On the Alboran Ridge and in the Bay of Oran, highstand wedges occur at 35 to 40 m. Up to 5 m long cores of upper Pleistocene to Holocene successions were recovered in water depths between 40 and 81 m. Deposits contain more than 80% carbonate, with mixed carbonate‐volcaniclastics in the lower part of some cores in Alboran. The carbonates consist of up to 53% of aragonite and up to 83% of high magnesium calcite. Radiocarbon dating of bivalve shells, coralline algae and serpulid tubes indicates that deposits are as old as 12 400 cal yr bp . The carbonate factories in the three areas are dominated mostly by red algae, but some intervals in the cores are richer in bivalves. A facies rich in the gastropod Turritella, reflecting elevated surface productivity, is restricted to the Mallorca Shelf. Rhodoliths occur at the sediment surface in most areas at water depths shallower than 70 m; they form a 10 to 20 cm thick veneer overlying rhodolith‐poor bioclastic sediments which, nonetheless, contain abundant red algal debris. This rhodolith layer has been developing for the past 800 to 1000 years. Similar layers at different positions in the cores are interpreted as reflecting in situ growth of rhodoliths at times of reduced net sedimentation. Sedimentary successions in the cores record the post‐glacial sea‐level rise and the degree of sediment exposure to bottom currents. Deepening‐upward trends in the successions are either reflected by shallow to deep facies transitions or by a corresponding change of depth‐indicative red algae. There are only weak downcore variations of carbonate mineralogy, which indicate that no dissolution or high magnesium to low magnesium calcite neomorphism occurs in the shallow subsurface. These new data support the approach of using the Recent facies distribution for interpretation of past cool‐water, low‐energy, microtidal carbonate depositional systems. Hydroacoustic data show that previous Pleistocene transgressive and highstand inner ramp deposits and wedges were removed during sea‐level lowstands and accumulated downslope as stacked lowstand wedges; this suggests that, under conditions of high‐amplitude sea‐level fluctuations, the stratigraphic record of similar cool‐water carbonates may be biased.     

High‐Precision Barium Isotope Measurements of Carbonates by MC‐ICP‐MS

This study presents a high‐precision method to measure barium (Ba) isotope compositions of international carbonate reference materials and natural carbonates. Barium was purified using chromatographic columns filled with cation exchange resin (AG50W‐X12, 200–400 mesh). Barium isotopes were measured by MC‐ICP‐MS, using a ¹³⁵Ba–¹³⁶Ba double‐spike to correct mass‐dependent fractionation during purification and instrumental measurement. The precision and accuracy were monitored by measuring Ba isotope compositions of the reference material JCp‐1 (coral) and a synthetic solution obtained by mixing NIST SRM 3104a with other matrix elements. The mean δ^137/134Ba values of JCp‐1 and the synthetic solution relative to NIST SRM 3104a were 0.21 ± 0.03‰ (2s, n = 16) and 0.02 ± 0.03‰ (2s, n = 6), respectively. Replicate measurements of NIST SRM 915b, COQ‐1, natural coral and stalagmite samples gave average δ^137/134Ba values of 0.10 ± 0.04‰ (2s, n = 18), 0.08 ± 0.04‰ (2s, n = 20), 0.27 ± 0.04‰ (2s, n = 16) and 0.04 ± 0.03‰ (2s, n = 20), respectively. Barium mass fractions and Ba isotopes of subsamples drilled from one stalagmite profile were also measured. Although Ba mass fractions varied significantly along the profile, Ba isotope signatures were homogeneous, indicating that Ba isotope compositions of stalagmites could be a potential tool (in addition to Ba mass fractions) to constrain the source of Ba in carbonate rocks and minerals.