Isotopic Composition of Dissolved Carbonates Meromictic Soda Lake Doroninskoe(Eastern Transbaikalia,Russia)

正1 Introduction Meromictic soda Lake Doroninskoe localized in the intermountain area,filled with continental sediments of the Mesozoic,in the upper basin of the river Amur.Coordinates of its location are N51°14'42"E112°14'40",     

Primary carbonate/CO2 inclusions in sapphirine-bearing granulites from central Sri Lanka

High-density CO₂-rich fluid inclusions from a sapphirine-bearing granulite (Hakurutale, Sri Lanka) have been studied by microthermometry, Raman spectrometry and SEM analysis. Based on textural evidence, two groups of inclusions can be identified: primary, negative crystal shaped inclusions (group I) and pseudo-secondary inclusions, which experienced a local, limited post-trapping modification (group II). Both groups contain magnesite as a daughter mineral, occurring in a relatively constant fluid/solid inclusion volume ratio (vol_solid =0.15 total volume). CO₂ densities for group I and II differ only slightly. Both groups contain a fluid, which was initially trapped at peak metamorphic conditions as a homogeneous (CO₂+MgCO₃) mixture. Thermodynamic calculations suggest that such a fluid (CO₂+15 vol% MgCO₃) is stable under granulite facies conditions. After trapping, magnesite separated upon cooling, while the remaining CO₂ density suffered minor re-adjustments. A model isochore based on the integration of the magnesite molar volume in the CO₂ fluid passes about 1.5–2 kbar below peak metamorphic conditions. This remaining discrepancy can be explained by the possible role of a small quantity of additional water.     

Superposition of gold mineralisation on pre‐existing carbonate alteration: Structural evidence from the Mulgarrie gold deposit,Yilgarn Craton

Carbonate alteration at the Mulgarrie gold mine in the Eastern Goldfields of Western Australia, is represented by porphyroblasts, veins and pervasive, texturally destructive, carbonatisation. Two foliations, S_1M and S_2M, were produced by two separate deformation events at the mine‐scale, D_1M and D_2M. D_1M and D_2M both occurred in response to regional D₂ tectonism. Carbonate alteration was the product of two separate episodes of fluid ingress: the earlier produced magnesite and the latter Fe‐dolomite. Both periods of carbonate alteration occurred pre‐ to early syn‐D_2M, when mafic to ultramafic komatiitic rocks reacted with fluids that moved along regional faults and pre‐date the alteration associated with regional peak metamorphism. Gold at Mulgarrie overprints pre‐ and late syn‐D₂ quartz veins in zones of massive carbonate alteration, suggesting it has a late‐ to post‐D₂ timing. This late timing agrees with the generally accepted syn‐D₃ (and younger) age for gold mineralisation in the Eastern Goldfields. We suggest that carbonate alteration at Mulgarrie is not a product of the hydrothermal event responsible for the gold mineralisation. Rather, the different relative timing of magnesite, Fe‐dolomite and gold indicates there were two carbonate‐producing fluid systems and a fluid transporting the gold overprinted these. Similarly, early carbonate alteration may play a role in localising auriferous vein deposits throughout the Yilgarn and other Archaean cratons.     

Transfort of oxygen,nutrients and carbonates by the Kuroshio Current

Measured concentrations of dissolved oxygen, phosphate, silicate, total alkalinity and calculated total CO₂ in a section between 121° E and 125° E across the Kuroshio near 22° N off Taiwan and the geostrophic velocity were used to estimate the gross transport of oxygen, nutrients and carbonates. The flux of dissolved oxygen is 6.7×10⁶ mol/s northward and 0.9×10⁶ mol/s southward. The net flux equals 5.8×10⁶ mol/s down-stream. The northward flux of phosphate is 22.6×10³ mol/s; the southward flux is 1.4×10³ mol/s. The net phosphate flux is 21.2×10³ mol/s northward. The flux of silicate is 967×10³ northward and 59×10³ mol/s southward; the net transport is 908×10³ mol/s down-stream. The flux of alkalinity is 75.5×10⁶ mol/s northward, and 10.8×10⁶ mol/s southward, the net flux is 64.7×10⁶ mol/s northward. For total CO₂ the transport is 73.4×10⁶ mol/s northward and 10.8×10⁶ mol/s southward, or a net transport of 62.6×10⁶ mol/s horthward.     

Rajkanella hottingerinaformis n. gen., n. sp., a new larger benthic foraminifer from the middle-upper Cenomanian of Kosovo

A new larger benthic porcelaneous foraminifer of soritid affinity is described as Rajkanella hottingerinaformis n. gen., n. sp. from the middle-upper Cenomanian of Kosovo. It occurs in foraminiferal packstones and grainstones, in association with cuneolinids, rhapidionids, chrysalidinids, and other benthic foraminifers. Due to its general morphology and superficial chamber subdivision by exoskeletal elements, Rajkanella n. gen. can be compared with the early Paleogene genus Hottingerina Drobne, 1975, from which it mainly differs in its apertural features, ornamented test, and coiled adult stage. Further differences to coeval Pseudorhapydionina De Castro, 1971, Pseudorhipidionina De Castro, 1971, and to other comparable genera, are discussed. The discovery of Rajkanella hottingerinaformis in the middle-upper Cenomanian is a further witness of the significant radiation and blooming of increasingly complex porcelaneous foraminifers in inner platform, shallow-water depositional settings during that period.     

Middle and Late Devonian microbial carbonates,reefs and mounds in Guilin,South China and their sequence stratigraphic,paleoenvironmental and paleoclimatic significance

The importance of calcimicrobes and microbialite in carbonate platform and reefal environments has been stressed in recent literature. Burne and Moore[1] introduced the term microbialite to describe the clotted, laminated and undifferentiated fabrics formed by mi-crobial communities. Microbialites are organosedi-mentary deposits that have accreted as a result of ben-thic (prokaryotic or eukaryotic) communities, trapping and binding detrital sediment[1]. Microbial organisms and microbialite are…     

NMR Measurements in Carbonate Rocks: Problems and an Approach to a Solution

Carbonate rocks are well known for their complex petrophysical behavior where, in contrast to siliciclastic rocks, different parameters, including porosity and permeability, usually are not directly related. This behavior is the result of thorough reorganization of porosity during diagenesis, and it turns prediction of reservoir quality of carbonate rocks into a challenge. The study presented here deals with the problem of utilizing NMR techniques in prediction of petrophysical properties in carbonates.We employ a visual porosity classification as a priori knowledge for better interpreting NMR data for prediction purposes. This allows for choice of suitable T₂ cutoff values to differentiate movable from bound fluids adapted for the specific carbonate rock, thus resulting in better interpretation of NMR data. The approach of using a genetic pore type classification for adapting the conventional method for T₂ cutoff determination, which originally was developed for siliciclastic rocks, is promising. Similarly, for permeability determination on the basis of NMR measurements, the classification of carbonate rocks based on porosity types also shows potential. The approach implemented here has the promise to provide a basis of standardized interpretation of NMR data from carbonate rocks.Acknowledgment We are grateful to Baker Hughes INTEQ, Celle, for permission to publish the results of this work. This study was part of I.S.s Masters Thesis at Hannover University that was carried out in collaboration with Baker Hughes INTEQ, Celle, Germany. We appreciate comments of an anonymous referee and PAGEOPH editor Brian J. Mitchell.     

The ichnology of carbonate drifts

Carbonate drifts have so far not been as intensely investigated as their siliciclastic equivalents, especially from an ichnological perspective. The aim of this work is therefore to provide an overview of the different bioturbation styles in carbonate drifts for ichnologists and sedimentologists working in such deposits. Different types of carbonate drifts from the Maldives were studied to address this objective. The cores recovered during International Ocean Discovery Program Expedition 359 were examined to provide the sedimentological and ichnological data for a detailed analysis of the ichnology of carbonate drifts. The ichnological characteristics of the Maldives drifts are compared to other carbonate drifts in order to discuss similarities and differences, and thus provide an overview of the general characteristics of carbonate drift ichnology. These drifts are located in the Santaren Channel which lines Great Bahama Bank, along the Marion Plateau in Australia, in the Limassol and Larnaca basins in Cyprus and in the Danish Basin in Denmark. The common characteristics of bioturbation in carbonate drifts are: (i) the complete bioturbation of the sediment with bioturbation indexes between four and six; (ii) the occurrence of distinctive trace fossils limited to facies contacts or condensed intervals; (iii) a typical ichnoassemblage consisting of Thalassinoides, Scolicia, Planolites, Zoophycos, Chondrites, Phycosiphon and Palaeophycus; (iv) the contiguous occurrence of ichnogenera from different tiers, with only Zoophycos and Chondrites as deep tiers; and (v) distinct infills of the traces including particulate organic matter, pyrite, silica and celestine. In addition, the main ichnofacies of carbonate drifts is the Zoophycos ichnofacies. Ichnofabrics grade from coarse‐grained and completely bioturbated to ichnofabrics with present to rare trace fossils and preserved sedimentary structures. The type and intensity of the bioturbation is controlled by the amount of organic matter and the oxygenation at the sea floor that is determined by the action of bottom currents and the sea‐level fluctuations affecting the carbonate factory in carbonate platforms bordering the basins where the carbonate drifts form. The study of the bioturbation in core and outcrop provides palaeoenvironmental information about carbonate‐drift deposits that complement the classical sedimentological data.     

缝洞型碳酸盐岩气藏多类型储集层孔隙结构特征及储渗能力——以四川盆地高石梯-磨溪地区灯四段为例

为全面表征缝洞型碳酸盐岩气藏多类型储集层的孔隙结构特征及储渗能力,借助多种测试技术对四川盆地高石梯-磨溪地区灯四段储集层样品进行分析与研究。首先利用铸体薄片和扫描电镜技术定性刻画了储集层的岩性、物性、储集空间和喉道特征,然后根据高压压汞得到的毛管压力曲线对储集层进行分类,最后基于多尺度CT扫描定量表征了3类样品的二维、三维孔隙结构特征。结果表明：研究区储集空间既有受组构控制的粒间溶孔、粒内溶孔和晶间溶孔等,又有不受组构控制的溶洞、溶缝和构造缝;喉道以缩颈、片状和管束状为主;根据毛管压力曲线特征,储集层可划分为缝洞型、孔洞型和孔隙型;缝洞型大孔隙与溶洞发育,分布均匀且连通性好,喉道粗大且数量较多,微裂缝与溶洞串接呈串珠状分布,沟通了孤立的储集空间,具有最好的储渗能力;孔洞型多尺度孔隙与溶洞发育,储集能力强,喉道粗大但数量较少,连通性较差,各储集空间无法有效沟通,渗流能力受限;孔隙型细小孔隙发育且分布不均,大部分区域被岩石骨架占据,喉道数量少且连通性极差,储渗能力弱。     

Crystallization pathways in the Great Artesian Basin (Australia) spring mound carbonates: Implications for life signatures on Earth and beyond

Recent studies of continental carbonates revealed that carbonates with similar fabrics can be formed either by biotic, biologically-induced, biologically-influenced or purely abiotic processes, or a combination of all. The aim of this research is to advance knowledge on the formation of carbonates precipitated (or diagenetically altered) in extreme, continental environments by studying biotic versus abiotic mechanisms of crystallization, and to contribute to the astrobiology debate around terrestrial analogues of Martian extreme environments. Both fossil (upper Pleistocene to Holocene) and active carbonate spring mounds from the Great Artesian Basin (South Australia) have been investigated. These carbonates consist of low-Mg to high-Mg calcite tufa. Four facies have been described: (i) carbonate mudstone/wackestone; (ii) phytohermal framestone/boundstone; (iii) micrite boundstone; and (iv) coarsely crystalline boundstone. The presence of filaments encrusted by micrite, rich in organic compounds, including ultraviolet-protectants, in phytohermal framestone/boundstone and micrite boundstone is clear evidence of the existence of microbial mats at the time of deposition. In contrast, peloidal micrite, despite commonly being considered a microbial precipitate, is not directly associated with filaments in the Great Artesian Basin mounds. It has probably formed from nanocrystal aggregation on colloid particulate. Thus, where biofilms have been documented, it is likely that bacteria catalyzed the development of fabrics. It is less certain that microbes induced calcium carbonate precipitation elsewhere. Trace elements, including rare earth element distribution from laminated facies, highlight strongly evaporative settings (for example, high Li contents). Carbon dioxide degassing and evaporation are two of the main drivers for an increase in fluid alkalinity, resulting in precipitation of carbonates. Hence, although the growth of certain fabrics is fostered by the presence of microbial mats, the formation of carbonate crystals might be independent from it and mainly driven by extrinsic factors. More generally, biological processes may be responsible for fabric and facies development in micritic boundstone whilst micrite nucleation and growth are driven by abiotic factors. Non-classical crystallization pathways (aggregation and fusion of nanoparticles from nucleation clusters) may be more common than previously thought in spring carbonate and this should be carefully considered to avoid misinterpretation of certain fabrics as by-products of life. It is proposed here that the term ‘organic-compound catalyzed mineralization’ should be used for crystal growth in the presence of organic compounds when dealing with astrobiological problems. This term would account for the possibility of multiple crystallization pathways (including non-classical crystallization) that occurred directly from an aqueous solution without the direct influence of microbial mats.