闽浙沿岸海域沉积物中汞和甲基汞的含量分布及其影响因素

在2012年6月实施的国家自然科学基金春季航次中,采集了闽浙沿岸海域表层和岩心沉积物样品。对沉积物样品进行了汞和甲基汞的分析测试,并结合沉积物中常量元素含量、粒度组分、有机质含量和孔隙水中硫酸根离子浓度等系统地分析了汞和甲基汞含量的分布及其影响因素。研究结果表明:(1)闽浙沿岸海域沉积物中汞和甲基汞含量分布大致表现为近岸含量高(杭州湾以南浙江沿岸),远岸含量低的特点。泥质区岩心沉积物中汞的甲基化作用主要发生在近表层较小的深度范围内(泥质区北部和南部,其深度范围分别为0~15和0~13 cm)。(2)在闽浙近岸泥质区,汞的原位甲基化是甲基汞的主要来源,在成岩过程中,埋深或其他环境条件的变化可以导致甲基汞的转移或再分配。(3)影响沉积物中汞和甲基汞含量分布及甲基化作用强弱的因素主要包括人为污染、海流体系、粒级组成、有机质含量和硫酸盐还原菌活性。人为污染是沉积物中汞含量的主控因素;海流体系控制着汞含量的分布格局;粒级组成影响着甲基汞的富集程度;有机质对表层沉积物中汞的甲基化作用影响不明显,在岩心沉积物中,既可以促进汞的甲基化,也可以抑制汞的甲基化,主要取决于沉积物中有机质的类型;硫酸盐还原菌的活化能力是汞甲基化作用的主控因素之一。     

织锦巴非蛤斧足颜色与总类胡萝卜素含量相关分析

斧足是织锦巴非蛤重要的食用部位。本研究检测了94个织锦巴非蛤斧足的总类胡萝卜素含量(TCC)和3个颜色指标L*(明暗度)、a*(红绿值)、b*(黄蓝值),发现织锦巴非蛤斧足总类胡萝卜素含量和颜色指标在不同个体之间存在较大差异。相关性分析表明,织锦巴非蛤斧足的总类胡萝卜素含量与颜色指标L*、a*、b*之间相关极显著(P0.01),相关系数分别为:–0.546、0.569、0.449。本研究表明,斧足颜色越深,其类胡萝卜素含量也越高可能是一个普遍规律,这对我们接下来选育高类胡萝卜素含量贝类提供了一种直观的参考指标。     

Effects of Mudstone Particle Content on Shear Strength of a Crushed Sandstone–Mudstone Particle Mixture

The present study focuses on the shear strength, deformation, and particle crushing of sand which is mixed by crushed sandstone and mudstone particles. Two triaxial tests—one for unsaturated specimens and the other for saturated specimens—were performed, along with sieve analysis tests. Results obtained from the triaxial tests indicate that, with the increment of the mudstone particle content by weight, the angle of internal friction decreases, the cohesion increases and then decreases, and both the initial angle of shearing resistance at the atmospheric pressure and decremental angle increase and then decrease. Compared to the unsaturated specimens, the deviator stress or normalized deviator stress of the saturated specimens at the same axial stress may decrease due to the wetting action. Thus, the shear strength of the tested materials may be reduced by the wetting action. Results of sieve analysis tests indicate that the mixing of some mudstone particles into the sandstone particle mixture may reduce the amount of particle crushing, but the wetting action may increase the amount. The amount of the crushed particle may arrive at a minimum of 40% of mudstone particle content by weight.     

Laboratory Study for Influence of Clay Content (CC) on Wave-Induced Liquefaction in Marine Sediments

In this artice, the influence of clay content on the wave-induced liquefaction in marine sediments was reported. The one-dimensional (1-D) equipment was setup with a vertical cylinder and 1.8–m–thick clayey sandy deposit and 0.2–m–thick water above the deposit. Unlike the previous experimental study for a single soil layer, this study used sand-kaolin mixtures, sand-illite mixtures, and sand-bentonite mixtures as the experimental samples. A series of experiments with 3,000 wave cycles in each test were conducted under numerous wave and soil conditions, which allowed us to examine the influence of clay content (CC) on wave-induced liquefaction in marine sediments. The experimental results showed that the clayey sandy deposit will become prone to liquefaction with the increase of CC when CC is less than a critical value, which depends on the type of clay. However, when CC is greater than the critical value, liquefaction depth will decrease as CC increases. Furthermore, when the CC value reaches a certain level, liquefaction will not occur. For example, no liquefaction occurs when CC ≥ 33% for both kaolin-sand and illite-sand mixtures and CC ≥ 16.36% for bentonite-sand mixtures.     

Effects of Column Diameter on Setting Behavior of Dredged Slurry in Sedimentation Experiments

This article investigates the influence of dimensions of a settling column on the settling mode and the settling rate. End conditions of the settling stage in the hindered settling were also analyzed. It was found that the settling mode in a column with a smaller diameter tends to be consolidation settling. The effect of a settling column wall decreases with increasing column diameter, and it can be ignored provided the column diameter is larger than 14.5 centimeters. For the difference in initial water content, the settling behavior of the slurry develops a different sensitivity to the diameter effect. The influence of column diameter reduces as the initial water content of the slurry becomes higher. It is suggested that the internal diameter of the column used in a sedimentation experiment should be 14.5 centimeters.     

用实测海水透明度数据和NOAA卫星数据计算黄海悬浮体含量

用国家海洋局1975—1982年间在黄东海调查的海水透明度数据换算为悬浮体含量,用NOAA卫星高分辨率辐射计数据计算悬浮体含量,以绘制悬浮体含量分布图。分布图显示,研究区有三个悬浮体含量高值区,位于苏北浅滩、长江口、成山角沿岸水域。研究表明,风浪是影响悬浮体含量的海洋外部的主要因素。层化参量是影响悬浮体含量海洋内部的主要因素。     

南海上层海洋热含量的年际和年代际变化

分析了1959—1988年南海表面至100m垂直平均温度（TAV）资料，结果表明：南海上层海洋热含量存在明显的准两年、4—5年和年代际振动。在E1Nino年，南海上层热含量显著增加。50年代末至70年代初，南海TAV为负距平，此后转为正距平。南海TAV的变化与ENSO事件、东亚冬季风和热带大气环流的变异密切相关。     

热带西太平洋海洋上层热含量的分布特征及其年际变化的分析

选用海面至20℃等温线所处深度水层的平均温度来表征研究海域海洋上层热含量。利用这一特征值，分析1986—1990年期间热带西太平洋边缘海域海洋上层热含量在秋季的分布特征和年际变化。结果表明：（1）热含量呈南高北低分布，在7．5－22．1°N范围内。以130°E断面为代表，热含量的平均递减率为0．179（℃／纬度）；（2）热含量的分布主要取决于环流系统，其等值线因受黑潮和棉兰老海流的影响而由纬向分布转向经向分布。某些区域因受暖涡及冷涡的影响而呈封闭状分布；（3）热含量的年际变化与E1Nino事件存在着很好的相关性，在E1Nino事件发生期间，热含量变得很低，高热含量（大于26．5℃）海区的分布范围明显缩小。     

热带西太平洋海域上层海洋热含量的CSEOF分析

基于月平均Argo温、盐度剖面、纬向风和Ni o3.4指数等资料,利用循环平稳经验正交函数(CSEOF)分解法、最大熵谱分析和相关分析等方法,研究了热带西太平洋海域上层(0—700m)海洋热含量的时空变化特征,并探讨了其年际变化的可能原因。结果表明,热带西太平洋海域上层海洋热含量距平场具有显著的东-西向反位相振荡,且这种振荡除了具有较明显的季节变化外,还存在着较强的准2a振荡。此外,热含量距平场还存在着负-正-负的三极式经向模态,该模态除了具有明显的季节变化外,还存在着显著的准4a振荡。进一步分析表明,热含量的准2a振荡与ENSO事件的发生有着非常密切的联系,并对赤道西太平洋纬向风异常有1—2月的滞后响应。     

黄、东海海域水团发育对底质沉积物分布的影响

通过对黄、东海海域底质沉积物中的细粒级粘土矿物组合特征和全粒级碳酸盐含量分析、对比上覆水团和悬浮体资料，探讨研究区水团发育消长对底质沉积物分布的影响作用。结果表明研究区可以划分为长江冲淡水影响的长江型物质沉积区；黄海水影响的黄河型物质沉积区和黑潮水以及东海次表层水影响的残留型物质沉积区。而水团发育消长可直接影响下伏底质的分布特征。黄河型物质沉积区与残留型物质沉积区的分界相应于黄海冷水向东南扩展与黑潮次中层混合水向陆架爬升互为消长的长期综合平衡位置，而黄海冷水向东南的扩展范围代表着黄河物质在陆架向东南扩展沉积的最大范围．