1850年以来呼伦湖沉积物无机碳埋藏时空变化

湖泊沉积物碳埋藏及其驱动机制是陆地生态系统碳循环及全球变化研究的热点问题之一,但以往湖泊碳循环的研究大多局限于有机碳,较少考虑无机碳的地位和作用.我国干旱-半干旱地区湖泊众多、无机碳储量丰富,在区域碳循环过程中的作用日益突出,因此探讨这些地区湖泊沉积物无机碳埋藏变化对深入理解区域碳循环具有重要意义.本研究通过对内蒙古高原呼伦湖15个沉积岩芯样品无机碳含量(TIC)的测定,结合沉积岩芯210Pb、137Cs年代标尺,分析了1850年以来呼伦湖无机碳埋藏速率时空变化,并揭示了影响呼伦湖无机碳埋藏的主要因素.结果表明,1980s之前,呼伦湖无机碳含量总体维持在相对稳定的低值,1980s之后开始快速增加,且近百年来呼伦湖平均无机碳含量在不同湖区差异不显著.1850年以来呼伦湖无机碳埋藏速率变化范围约为7.10～74.29 g/(m2·a),平均值约为36.15 g/(m2·a),且大体上可分为3个阶段,即1900s以前相对稳定的低值阶段、1900s-1950s期间的快速增加阶段以及1950s以来的波动增加阶段,各阶段无机碳埋藏速率平均值分别约为10.40、26.29和41.00 g/(m2·a).空间上,呼伦湖无机碳埋藏速率整体表现为中部高、南北两端低的分布格局,这可能与湖心水动力条件相对稳定,有利于碳酸盐沉积有关.此外,呼伦湖无机碳埋藏速率与湖区温度变化呈显著正相关,而与周边人类活动影响关系不明显,表明在未来全球变暖背景下,呼伦湖无机碳埋藏速率将进一步增加,湖泊在区域碳循环中的作用将更加显著.     

近百年来湖泊有机碳与无机碳埋藏响应流域开发的协同变化——以石林喀斯特地区为例

有机碳和无机碳的流域输出是湖泊碳埋藏的重要驱动因子,而喀斯特地区无机碳循环具有反应迅速且对人类活动影响敏感的特点.在流域开发持续增强的背景下,喀斯特地区湖泊有机碳和无机碳的来源、含量与埋藏通量可能会出现同步变化的协同模式.本文以云南省石林喀斯特地区流域土地利用类型不同的两个中型湖泊(长湖、月湖)开展对比分析,通过对沉积物钻孔的土壤侵蚀强度(磁化率)、流域外源输入(C:N比值)、水动力(粒度)、营养盐(总氮、总磷)、藻类生产力(叶绿素色素)等代用指标的分析,结合监测数据和历史资料重建了两个湖泊环境变化的近百年历史,并定量识别了有机碳和无机碳埋藏响应流域开发的变化特征与协同模式.沉积物磁化率和C:N比值结果揭示了流域地表侵蚀和外源输入的阶段性特征,同时总氮和总磷含量记录了长湖和月湖营养水平上升的长期模式.在流域森林覆被较高(33.43%)的长湖中,全岩和有机质C:N比值分别与磁化率信号呈显著正相关(r=0.95和0.89,P<0.001),且与无机碳和有机碳含量呈显著负相关(r=-0.94,P<0.001和r=-0.52,P=0.01),反映了森林植被退化时流域碳输出的减少对沉...     

东濮凹陷新生代的热历史

东濮凹陷是渤海湾盆地南缘极具油气开采潜力的凹陷,本文揭示该凹陷新生代埋藏史、热史及烃源岩演化史.利用凹陷各构造单元18口井的镜质体反射率数据,恢复其埋藏史、热史.结果显示,东濮凹陷经历“一升两降”的构造沉降,并具有“马鞍型”的热演化特征.自沙四段沉积开始至沙三段,地温梯度逐渐增加,在沙三段沉积末期达到最大,为45.2℃～48℃/km.自沙二段沉积开始至今,地温梯度总体逐渐降低,仅在东营组沉积时期出现微弱回升,现今地温梯度为30℃～ 34℃/km.以埋藏史和热史为基础,结合构造及有机地球化学资料,对东濮凹陷18口井烃源岩演化史进行模拟.结果表明,烃源岩热演化受东营组沉积时期的古地温控制,3套烃源岩成熟度均在27Ma(东营组沉积时期)达到最大.     

Patterns and rates of fluid flow during burial diagenesis of the Middle Jurassic Lincolnshire Limestone, eastern England

A phase of ferroan burial calcite from the Middle Jurassic Lincolnshire Limestone exhibits a systematic spatial arrangement of oxygen isotopic characteristics. Mean δ¹⁸O values of the ferroan calcites from each of 15 core and outcrop localities over a study area 25 × 25 km were obtained. These values show a marked depletion from west to east across the study area of approximately 3‰, such that the oxygen isotopic composition of the ferroan calcites can be contoured. The systematic change in oxygen isotopic composition across the study area is believed to have recorded the thermal gradient in the limestone during ferroan calcite precipitation. This thermal gradient can be partially attributed to approximately 200 m of differential burial of the Lincolnshire Limestone across the study area during the Chalk deposition, with a maximum burial of 550 m to the east of the area at this time. A component of up-dip fluid flow (from east to west) through the formation is required to generate the temperature enhancements above those predicted for conduction alone by simple differential burial. Using a finite-difference step computer program, rates of fluid flow during ferroan calcite precipitation are calculated to be approximately 25 m/year. This rate of fluid flow is considerably greater than rates usually predicted for buried sedimentary basins. The causes of such rapid, probably relatively short-lived flow-rates may be the sudden dewatering of adjacent shales, the release of overpressure within the formation of interest, seismic pumping, or fluid circulation round a supracrustal convective loop.     

Wave pressures and uplift forces on and scour around submarine pipeline in clayey soil

Experimental investigations are carried out on wave-induced pressures and uplift forces on a submarine pipeline (exposed, half buried and fully buried) in clayey soil of different consistency index both in regular and random waves. A study on scour under the pipeline resting on the clay bed is also carried out. It is found that the uplift force can be reduced by about 70%, if the pipeline is just buried in clay soil. The equilibrium scour depth below the pipeline is estimated as 42% of the pipe diameter for consistency index of 0.17 and is 34% of the pipe diameter for consistency index of 0.23. The results of the present investigations are compared with the results on sandy soil by Cheng and Liu (Appl. Ocean Res., 8(1986) 22) to acknowledge the benefit of cohesive soil in reducing the high pore pressure on buried pipeline compared to cohesionless soil.     

Numerical prediction on the scour burial of cylinder object freely resting on the sandy seabed in the East China Sea using the DRAMBUIE model1

After experiencing 8-day combined tidal current, circulation and wave actions, scour depth surrounding cylinder object freely resting on sandy seabed in the East China Sea (ECS) in January is numerical...     

Burial fluxes and sources of organic carbon in sediments of the central Yellow Sea mud area over the past 200 years

Long-term changes of composition,sources and burial fluxes of TOC(total organic carbon) in sediments of the central Yellow Sea mud area and their possible affecting factors are discussed in this paper.Firstly,similarity analysis is employed to confirm that the carbon burial features resulted from two collected cores are typical in the central Yellow Sea mud area where YSWC(Yellow Sea Warm Current) is prevalent.On this basis,the burial flux of TOC here was considered to be 235.5–488.4 μmol/(cm2?a) since the first industrial revolution,accounting for about 70%–90% among burial fluxes of TC(total carbon) in the sediments.Compared TOC/TC ratio in the two cores with that in other marine sediments worldwide,we suggest that the growth of calcareous/non-calcareous organisms and dissolution of IC(inorganic carbon) are important factors controlling the TOC/TC ratio in sediment.Results of two-end mixed model based on δ13C data indicate that marine-derived organic carbon(OCa)is the main part among total burial organic carbon which accounts for a ratio over 85%.Due to the high TOC/TC ratio in the two cores,TC in the sediments also mainly exists as OCa,and the proportion of OCa is about 60%–80%.Away from the shore and relatively high primary production in upper waters are the main reasons that OCa is predominant among all burial OC in sediments of the central Yellow Sea mud area.Burial of OC in this mud area is probably mainly influenced by the human activities.Although the economic development during the late 19 th century caused by the first industrial revolution in China did not obviously increase the TOC burial fluxes in the sediments,the rise of industry and agriculture after the founding of new China has clearly increased the TOC burial flux since 1950 s.Otherwise,we also realize that among TC burial fluxes,TIC account for about 10%–30% in sediments of the central Yellow Sea mud area,so its burial could not be simply ignored here.Distinct from TOC burial,long-term TIC burial fluxes variations relate with climate changes more closely:the East Asian summer monsoon may influence the strength of the Huanghe River(Yellow River) flood,which could further affect the transport of terrestrial IC from land to the central Yellow Sea as well as the burial of these IC in the sediments.     

Geometry of scour hole around, and the influence of the angle of attack on the burial of finite cylinders under combined flows

Experiments were conducted to investigate the geometry of the scour hole and flow structure around short cylinders under the action of waves alone (WA) and combined flows (CF). The study is aimed at better understanding the dynamics of isolated objects on a sandy floor under oscillatory flows as occurs in shallow water regions in coastal areas. Flow velocities within the fluid core were recorded and 3D mapping of the bottom was performed with sub-aquatic acoustic sensors. Experiments were conducted for cylinder Reynolds wave number and Keulegan-Carpenter number within the ranges 10⁴R_e1.7×10⁵ and 2KC71, respectively. The present experimental evidence shows that the geometric characteristics of the scour hole (length and width) depend primarily on the Keulegan-Carpenter number (KC) and the cylinder aspect ratio (a_r=L_c/D). The effect of variation in the angle of attack of the flow with respect to the cylinder main axis was also investigated. Initial orientations of zero and ninety degrees were found to be stable while cylinders with intermediate initial orientations tended to orientate their main axes perpendicular to the flow direction. The final angle of orientation was found to be primarily a function of the Shields parameter, θ, and the initial angle of attack, α_i.     

Efficient trapping of organic carbon in sediments on the continental margin with high fluvial sediment input off southwestern Taiwan

Accumulation rates of marine and terrigenous organic carbon in the continental margin sediments off southwestern Taiwan were estimated from the measured concentrations and isotopic compositions of total organic carbon (TOC) and previously reported sedimentation rates. Surficial sediments were collected from the study area spanning from the narrow shelf near the Kaoping River mouth to the deep slope with depths reaching almost 3000 m. The average sediment loading of Kaoping River is 17 Mt/yr, which yields high sediment accumulation rates ranging from 0.08 to 1.44 g cm⁻² yr⁻¹ in the continental margin. About half of the discharged sediments were deposited on the margin within 120 km of the river mouth. Carbon isotopic compositions of terrestrial and marine end-members of organic matter were determined, respectively, based on suspended particulate matter (SPM) collected from three major rivers in the southwestern Taiwan and from an offshore station. All samples were analyzed for the TOC content and its isotopic composition (δ¹³C_org). The SPM samples were also analyzed for the total nitrogen (TN) content. TOC content in marine sediments ranges from 0.45% to 1.35% with the highest values on the upper slope near the Kaoping River mouth. The TOC/TN ratio of the SPM samples from the offshore station is 6.8±0.6, almost identical to the Redfield ratio, indicating their predominantly marine origin; their δ¹³C_org values are also typically marine with a mean of −21.5±0.3‰. The riverine SPM samples exhibit typical terrestrial δ¹³C_org values around −25‰. The δ¹³C_org values of surficial sediments range from −24.8‰ to −21.2‰, showing a distribution pattern influenced by inputs from the Kaoping River. The relative contributions from marine and terrestrial sources to sedimentary organic carbon were determined by the isotope mixing model with end-member compositions derived from the riverine and marine SPM. High fluvial sediment inputs lead to efficient trapping of organic carbon over a wide range of water depth in this continental margin. The marine organic accumulation rate ranges from 1.6 to 70 g C m⁻² yr⁻¹ with an area weighted mean of 4.2 g C m⁻² yr⁻¹, which is on a par with the mean terrestrial contribution and accounts for 2.3% of mean primary production. The depth-dependent accumulation rate of marine organic carbon can be simulated with a function involving primary productivity and mineral accumulation rate, which may be applicable to other continental margins with high sedimentation rates. Away from the nearshore area, the content of terrigenous organic carbon in surficial sediments decreases with distance from the river mouth, indicating its degradation in marine environments.     

Burial and thermal history of the West Bashkirian sedimentary basins

The GALO system is applied to the numerical reconstruction of burial and thermal histories of the West Bashkirian lithosphere from the Riphean to the present. An analysis of the variation in tectonic subsidence of the basin during its development is utilized to estimate approximately the mantle heat flow variations. Our variant of basin evolution suggests that after cooling in the Early Riphean, the rather weak thermal reactivations have not led to considerable heating of the lithosphere in the study region. Surface heat flow decreased from relatively high values in the Early Riphean (60–70 mW/m² in the eastern area and 40–50 mW/m² in the western part) to present-day values of 32–40 mW/m². In spite of the relatively low temperature regime of the basin as a whole, a syn-rifting deposition of more than 10 km of limestone, shale and sandstone in the Riphean resulted in rather high temperatures (180–190 °C) at the base of present-day sedimentary blanket in the eastern area. In agreement with the observed data, computed present-day heat flow through the sediment surface increases slightly from 32 to 34 mW/m² near the west boundary of the region to 42 mW/m² near the boundary of the Ural Foldbelt, whereas the heat flow through the basement surface decreases slightly from 28–32 to 24–26 mW/m² in the same direction. The mantle heat flow is only 11.3–12.7 mW/m², which is considerable lower than mean heat flow of the Russian Platform (16–18 mW/m²) and comparable with the low heat flow of Precambrian shields.