广西河池五圩矿田箭猪坡矿区主要成矿元素富集规律

箭猪坡矿床位于羌塘-扬子克拉通滇黔桂被动陆缘南盘江—右江裂谷盆地南丹坳陷带的东南缘,属湘中—桂中北(坳陷)成矿带桂中北成矿亚带芒场-大厂成矿带.主要含矿地层为下泥盆统塘丁组灰黑色条带状及薄层状绢云母泥岩,矿区内NNW向的张扭性断裂,是矿床的主要控矿构造,矿脉的产状及形态,严格受其控制.在总结前人认识基础上,通过野外地质...     

中国中西部小型克拉通盆地群的叠合复合性质及其含油气系统

中国中西部盆地油气资源潜力巨大,是晚古生代一早中生代一新生代大型造山带环绕的小型克拉通盆地,盆地核心为构造相对稳定的小型克拉通,边缘环绕构造活跃的前陆冲断带。与北美、欧洲等大型含油气盆地相比,中国含油气盆地规模小、构造活动性强。盆地普遍经历：（1）寒武—志留纪,各自漂离于大洋中的小型克拉通盆地;（2）泥盆—二叠纪,亚欧板块南缘地体增生;（3）三叠—古近纪,特提斯洋关闭,陆相断（坳）陷盆地;（4）新近纪以来,再生前陆盆地等四个构造演化阶段。从下而上叠合了早古生代海相克拉通盆地、晚古生代海陆交互相克拉通盆地、早中生代陆相断（坳）陷盆地和新生代再生前陆盆地四个构造层序。古生界克拉通盆地构造相对稳定,古生代发育多期不整合界面和大型古隆起;中新生代前陆盆地叠置复合在其边缘,发育成排成带的构造。中国含油气盆地的叠合-复合性质决定了其叠合-复合含油气系统的特征：具有多油气系统、多源多阶段生烃、多期成藏、多层系含油气。中国中西部盆地的油气勘探主要包括古生界小型克拉通层序和中新生代前陆层序两大领域,其中早古生代克拉通层序以古隆起及其斜坡、晚古生代克拉通层序以大面积岩性储集体、中新生代前陆盆地以大型冲断带控制着油气的成藏与富集。     

Microthermometric measurement of fluid inclusions and its constraints on genesis of PGE-polymetallic deposits in Lower Cambrian black rock series, southern China

Systematic microthermometric measurements of fluid inclusions in the PGE-polymetallic deposits hosted in the Lower Cambrian black rock series in southern China were performed, and the results suggest: (1) there exist two types of fluid inclusions. TypeⅠis of NaCl-H2O system with low-medium salinity, and its homogenization temperatures (Th) and salinities are 106.9- 286.4℃ and ( 0.8- 21.8) wt%NaCl eq. respectively; TypeⅡ is of CaCl2-NaCl-H2O system with medium-high salinities, and its homogenization temperatures and salinities range from 120.1℃ to 269.6℃ and ( 11.4- 31.4) wt%NaCl eq., respectively. The typeⅡ fluid inclusions have been discovered for the first time in this kind of deposits; (2) two generations of ore-forming fluids were recognized. Characteristics of fluid inclusions in the PGE-polymetallic ores and carbonate-quartz stockworks in the underlying phosphorites are almost of no difference, they may represent ore-forming fluids at the main metallogenic stage. The peak value of homogenization temperature of those fluid inclusions is about 170℃, while their salinities possess a remarkable bimodal distribution pattern with two peak values of (27-31) wt%NaCl eq. and (4-6) wt%NaCl eq. On the contrary, fluid inclusions in the carbonate-quartz veins in the hanging wall may represent ore-forming fluids at the post-metallogenetic stage. The homogenization temperatures and the peak values of salinities are mostly 130-170℃ and (12-14) wt%NaCl eq., respectively; (3) nobel gas isotopic composition analyses in combination with the microthermometric measurements of fluid inclusions suggest that the ore-forming fluids at the main metallogenetic stage were probably derived from mixing of basinal hot brines with the CaCl2-NaCl-H2O system and seawater with the NaCl-H2O system; (4) in the Early Cambrian, the basinal hot brines were trapped in the Caledonian basins, which were distributed along the southern margin of the Yangtze Craton, and where giant thick sediments were accumulated, and expelled and migrated laterally along the strata because of the pressure caused by overlying sediments. The basinal hot brines absorbed Ni, Mo, V, PGE from the surrounding rocks and were transformed into ore-bearing hydrothermal fluids with the CaCl2-NaCl-H2O system and medium-high salinities, then ascended along faults and mixed with seawater of the NaCl-H2O system, and finally PGE-polymetallic deposits or occurrences were formed in the black rock series.     

Anomalous Enrichment of Silver in Organic Matter of the Songxi Shale-hosted Ag-Sb Deposit in Northeastern Guangdong

The silver contents of organic matter in the host rocks of the Songxi shale-hosted Ag-Sb deposit of northeastern Guangdong, South China, have been directly determined using the electron microprobe technique. The silver contents in two types of organic matter, marine vitrinite and solid bitumen, vary in the range from 100×10-6to 350×10-6, which are from tens of times to thousands of times higher than those of the host rocks in the ore deposit. The average silver content of the organic matter is also several times higher than the pay grade of silver for commercial mining of the ore deposit. It is quite obvious that the organic matter of the host rocks in the ore district is characterized by an anomalous enrichment of silver. The results of this study indicate that the silver anomalies in the organic matter have been derived from both the host rocks and the silver-bearing fluids of the Songxi black shale ore source. In the course of sedimentation and later hydrothermal reworking, organic matter was able     

中条山西南段与变基性岩有关的铜矿地质特征及成因浅析

与变基性岩有关的铜矿 ,是在中条山西南段新发现的一种新的铜矿类型 ,其形成是在原始基性岩浆侵入或喷发作用形成的矿源岩或矿化体基础上 ,经过区域变质和印支 -燕山期构造 -岩浆热液的改造加富而成 ,其成因应属与变基性岩有关的变质 -热液改造型铜 (镍、铁 )矿床。     

渔塘坝硒矿床多元素富集与沉积环境

对采自湖北西部渔塘坝二叠系独立硒矿区的硅质岩和页岩样品进行了元素测试（微量元素、总铁、总有机碳、总硫）,分析了该区域的多元素富集及沉积环境。该区域V、Cu、As、Cd、Tl、Se、Mo、V、 Sb、 U、Ag、 Cr、Ni相对富集, Ba、Hf、Ta、W、Pb、Th相对贫化或亏损。全硫—全铁（TS—TFe）的关系表明页岩及部分硅质岩的S/Fe比值均大于1.15,说明有过量的硫存在,可能为有机硫或为其他亲硫元素沉淀提供条件。TOC—TS—TFe三角图及V/(V + Ni)表明该区域的岩石形成于缺氧或静海相环境。U/Th、Zr—Cr、P—Y等微量元素地球化学参数表明该区域有热水沉积的存在。通过对微量元素可能的来源研究分析,该区域的微量元素可能存在多种来源:热水来源、海水沉积、峨眉山玄武岩。     

氢氧化钠预处理对提高泡塑富集金能力的探讨

用氢氧化钠处理的泡塑对金的回收率高，富集能力强，并根据金的分布情况对影响泡塑富集能力的原因进行了探讨，为泡塑分离富集金的分析提供了一种新的泡塑予处理方法。     

Br2-H2O2-HCI溶解容量法测定矿石中的金

采用Br2-H2O2-HC1冷浸溶矿体系,泡塑吸附,氢醌容量法测定矿石中的金,结果满意.     

Evaluation of heavy metal contamination and implication of multiple sources from Hunchun basin, northeastern China

Present concentrations and distributions of heavy metals through profiles, surface soil, and stream sediment samples in the Hunchun area, north-eastern China, were investigated to determine the elemental background values. This study also aims to characterize potentially toxic materials such as pulverized fly ash (PFA) from power stations or ash and slag from coal used domestically in urban areas, agrochemicals applied inappropriately, and urban sewage sludges from Hunchun City, as well as to ascertain the possibility of natural enrichment through site characterization by mineralogical and geochemical investigation. The distribution of contaminants in the alluvial soils (fluvisol) of this area has been influenced by several interacting factors. The parent alluvial materials from weathered products of amphiboles have made coatings such as ferrihydrite, goethite, and hematite. This natural inheritance factor is supported by the fact that the concentrations of weak acid-extractable (plant-available) heavy metals are very low, except for Fe and Mn. However, in agricultural soils and adjacent stream sediments, an anthropogenic input of Cd, Pb, Ni and Cr by agrochemicals is strongly suggested. Also, F contamination by coal combustion and the dissolution of F-bearing minerals could cause some future problems. Wide distribution and significantly high concentrations of Cd, Fe, Mn, and F in soils throughout the combination of pollutants originating from lithogenic and the anthropogenic sources pose potential problems in utilizing water resources. Received: 14 June 1999 · Accepted: 27 December 1999     

Characterization of Geochemical Distributions Using Multifractal Models

The use of multifractals in the applied sciences has proven useful in the characterization and modeling of complex phenomena. Multifractal theory has also been recently applied to the study and characterization of geochemical distributions, and its relation to spatial statistics clearly stated. The present paper proposes a two-dimensional multifractal model based on a trinomial multiplicative cascade as a proxy to some geochemical distribution. The equations for the generalized dimensions, mass exponent, coarse Lipschitz–Hölder exponent, and multifractal spectrum are derived. This model was tested with an example data set used for geochemical exploration of gold deposits in Northwest Portugal. The element used was arsenic because a large number of sample assays were below detection limit for gold. Arsenic, however, has a positive correlation with gold, and the two generations of arsenopyrite identified in the gold quartz veins are consistent with different mineralizing events, which gave rise to different gold grades. Performing the multifractal analysis has shown problems arising in the subdivision of the area with boxes of constant side length and in the uncertainty the edge effects produce in the experimental estimation of the mass exponent. However, it was possible to closely fit a multifractal spectrum to the data with enrichment factors in the range 2.4–2.6 and constant K₁ = 1.3. Such parameters may give some information on the magnitude of the concentration efficiency and heterogeneity of the distribution of arsenic in the mineralized structures. In a simple test with estimated points using ordinary lognormal kriging, the fitted multifractal model showed the magnitude of smoothing in estimated data. Therefore, it is concluded that multifractal models may be useful in the stochastic simulation of geochemical distributions.