硫化物固—液界面电化学效应实验探讨

硫化物作为一类重要的常见矿物，目前国内外对其表面矿物学特征研究有限。具体到硫化物固－液界面处的行为机理，前人的研究程度就更低了。笔者自行设计了一个Fe1-xS-Cr^6 原电池，通过实测电动势（E），t-E关系曲线，溶液可见光吸收谱及其λ－A关系曲线，阐明硫化物与Cr^6＋溶液间的界面行为机理。认为其界面行为过程为；硫化物溶解→离子反应（氧化还原）→吸附Cr^3 。该原电池与一般原电池结构不同，其主要差别在于将反应电极和测量电极分开，从而解决电极反应过程中的浓度极化问题，提高了电化学实验的精度。该研究成果有助于揭示矿物－液体相互作用机理，完善和丰富表面矿物学研究内容，深化化界面成矿理论，并对环境治理，矿物材料应用等开发领域具有重要的参考价值。     

硅酸盐固溶体矿物中组分的韵律型空间分布及形成过程中的时-空自组织

本文根据熔体聚合模型和正规溶液模型,建立了非平衡条件下,在二组分硅酸盐熔体固结过程中的非平衡非理想界面反应的非线性动力学模型:对上式进行数值模拟表明,当W/RT<-2时,有三重态,并通过建立界面状态(组成)的质量守恒方程,合理地说明了硅酸盐固溶体矿物韵律结构形成的可能机理之一,寻找界面反应三重态是研究固溶体矿物韵律结构的一条相当普遍的途径。     

华南二叠-三叠系的成因地层序列及古特提斯海重建

总结各类沉积盆地的沉积和地层格架，厘定出６类等时性地层界面和５个级别的成因地层单位，在分析地层界面性质和各类成因地层单位沉积构成的基础上，将华南二叠－三叠系划分为７个沉积幕、３个构造沉积幕和２个沉积盆地域、恢复了华南板块二叠－三叠纪的演化过程，论述了板块构造运动，海平面升降和源区侵蚀作用对各级成因地层单位的控制意义，证明了华南的古特提斯海经历了陆表海和伸展裂谷海两个演化阶段。     

基于钻孔数据任意边域地层分界面B-Rep建模研究

对相邻钻孔数据的类型进行了分析,对不同连续性和规则性的地层分界面进行了建模.考虑地层分界面的光滑性和整体控制性,运用边界表示法(B-Rep)和B样条曲面重构地层分界面,为地层建模提供了一种新的方法.建模研究表明:在钻孔数据前处理算法的基础上,B-Rep能够建立连续型、非连续型、空洞型等任意边域的地层分界面.     

地下点坝砂体内部构型分析--以孤岛油田为例

用Miall层次界面分析法对孤岛油田52井组馆陶组Ng4^4砂层点坝砂体内部3,4级界面进行详细研究,并与Miall的6级层次界面相对应,定义4级界面为单一河道的顶底界面,构型要素为单一的点坝砂体;3级界面为点坝内部侧积体分界面,实际上是点坝砂体的侧积面,其限定的构型要素为点坝侧积体。还对单井进行了泥质界面划分及成因砂体分析,建立了点坝成因砂体单井模型,根据研究区开发动态特征,推论点坝砂体内部存在倾斜的泥质侧积层,并借助储层地质学基本理论,对侧积体规模、倾角进行了限定。在上述研究基础上建立了点坝侧积体的三维地质模型,数值模拟结果研究表明,点坝侧积层对剩余油分布具明显控制作用。     

铀成矿流体地球化学界面

在简要介绍流体成矿地球化学界面的概念、组成、分类、地球化学标志及研究意义的基础上,讨论了流体地球化学界面与铀成矿的关系,提出了铀成矿流体地球化学界面研究的基本思路和方法,指出了今后应重视开展研究的某些重大地质问题。     

多孔介质中天然气水合物稳定性的实验研究进展

勘探表明天然气水合物多产出于细碎屑沉积物中,其分布和赋存形式受温度、压力、水化学条件等多种物理化学因素的影响。前人的实验研究表明不同孔径尺度中的甲烷水合物稳定性有别于块状、层状水合物,同时孔隙表面的润湿性也是影响因素之一。在综合分析前人研究成果的基础上,系统阐述了孔隙的孔径、孔隙内表面润湿性对所含天然气水合物稳定性的影响规律,总结了可能的内在机理;并指出了当前应当尽快建立包括空间效应、温度、压力和组分等因素的综合天然气水合物相图,查明含天然气水合物沉积物的孔隙结构和表界面特征,建立天然气水合物的稳定性模型,将有助于精确预测天然气水合物的分布和规模,对于水合物开发和甲烷存储技术的研发也有着重要的意义。     

Disturbed state model for sand–geosynthetic interfaces and application to pull-out tests

Successful numerical simulation of geosynthetic-reinforced earth structures depends on selecting proper constitutive models for soils, geosynthetics and soil–geosynthetic interfaces. Many constitutive models are available for modelling soils and geosynthetics. However, constitutive models for soil–geosynthetic interfaces which can capture most of the important characteristics of interface response are not readily available. In this paper, an elasto-plastic constitutive model based on the disturbed state concept (DSC) for geosynthetic–soil interfaces has been presented. The proposed model is capable of capturing most of the important characteristics of interface response, such as dilation, hardening and softening. The behaviour of interfaces under the direct shear test has been predicted by the model. The present model has been implemented in the finite element procedure in association with the thin-layer element. Five pull-out tests with two different geogrids have been simulated numerically using FEM. For the calibration of the constitutive models used in FEM, the standard laboratory tests used are: (1) triaxial tests for the sand, (2) direct shear tests for the interfaces and (3) axial tension tests for the geogrids. The results of the finite element simulations of pull-out tests agree well with the test data. The proposed model can be used for the stress-deformation study of geosynthetic-reinforced embankments through numerical simulation. Copyright © 1999 John Wiley & Sons, Ltd.     

Numerical modeling of three‐phase dissolution of underground cavities using a diffuse interface model

Natural evaporite dissolution in the subsurface can lead to cavities having critical dimensions in the sense of mechanical stability. Geomechanical effects may be significant for people and infrastructures because the underground dissolution may lead to subsidence or collapse (sinkholes). The knowledge of the cavity evolution in space and time is thus crucial in many cases. In this paper, we describe the use of a local nonequilibrium diffuse interface model for solving dissolution problems involving multimoving interfaces within three phases, that is, solid–liquid–gas as found in superficial aquifers and karsts. This paper generalizes developments achieved in the fluid–solid case, that is, the saturated case [1]. On one hand, a local nonequilibrium dissolution porous medium theory allows to describe the solid–liquid interface as a diffuse layer characterized by the evolution of a phase indicator (e.g., porosity). On the other hand, the liquid–gas interface evolution is computed using a classical porous medium two‐phase flow model involving a phase saturation, that is, generalized Darcy's laws. Such a diffuse interface model formulation is suitable for the implementation of a finite element or finite volume numerical model on a fixed grid without an explicit treatment of the interface movement. A numerical model has been implemented using a finite volume formulation with adaptive meshing (e.g., adaptive mesh refinement), which improves significantly the computational efficiency and accuracy because fine gridding may be attached to the dissolution front. Finally, some examples of three‐phase dissolution problems including density effects are also provided to illustrate the interest of the proposed theoretical and numerical framework. Copyright © 2014 John Wiley & Sons, Ltd.