Characterization of tar-like material and producible oil in Misoa C2 and C3 reservoir sands of the Area 2 South (Ceuta Field,Venezuela)

Here we characterized asphaltic oil occurrences in the Misoa C2 and C3 reservoirs within Area 2 South of the Ceuta Field (Lake Maracaibo Basin, NW Venezuela). To perform the geochemical and petrological characterization of the C2 and C3 sub-units, which cover an interval in which tar-like material was detected, we analyzed core (18) and cutting (123) samples using the Rock-Eval 6 technique in reservoir mode. Samples were studied under fluorescence light and scanning electron microscopy (SEM), showing the presence of two charges of oils and the relationships within silica cements and clay minerals. To evaluate vertical inter-reservoir communication and lateral intra-reservoir continuity, we also studied 12 oil samples from wells in Area 2 South. Biomarkers and isotopic signatures were examined using gas chromatography-mass spectrometry (GC-MS) and isotope ratio mass spectrometry (IRMS). The results suggest that oil and core extracts belongs to a single family derived from two pulses of hydrocarbon generation from the La Luna source rock, which was deposited in a marine reducing environment. The oil samples are a mixture of a paleobiodegraded oil charge and a later fresh, more mature oil recharge. The geochemical analyses also evidence that the formation of heavy oil tar zones can be related to biodegradation and in-reservoir oil mixing, though other formation mechanisms for the tar are also feasible. Finally, the GC fingerprints of the oils are indicative of lateral reservoir continuities across the F-1 and F-2 faults and vertical communication between the Misoa C2 and C3 sub-units in Area 2 South, suggesting that tar occurrences do not act as permeability barriers within the two reservoirs studied.     

Grain size composition and transport of sedimentary organic carbon in the Changjiang River (Yangtze River) Estuary and Hangzhou Bay and their adjacent waters

Surface sediments from the Changjiang River(Yangtze River) Estuary,Hangzhou Bay,and their adjacent waters were analyzed for their grain size distribution,organic carbon(OC) concentration,and stable carbon isotope composition(δ13C).Based on this analysis,about 36 surface sediment samples were selected from various environments and separated into sand(0.250 mm,0.125–0.250 mm,0.063–0.125 mm) and silt(0.025–0.063 mm)fractions by wet-sieving fractionation methods,and further into silt-(0.004–0.025 mm) and clay-sized(0.004mm) fractions by centrifugal fractionation.Sediments of six grain size categories were analyzed for their OC andδ13C contents to explore the grain size composition and transport paths of sedimentary OC in the study area.From fine to coarse fractions,the OC content was 1.18%,0.51%,0.46%,0.42%,0.99%,and 0.48%,respectively,while theδ13C was –21.64‰,–22.03‰,–22.52‰,–22.46‰,–22.36‰,and –22.28‰,respectively.In each size category,the OC contribution was 42.96%,26.06%,9.82%,5.75%,7.09%,and 8.33%,respectively.The OC content in clay and fine silt fractions(0.025 mm) was about 69.02%.High OC concentrations were mainly found in offshore modern sediments in the northeast of the Changjiang River Estuary,in modern sediments in the lower estuary of the Changjiang River and Hangzhou Bay,and in Cyclonic Eddy modern sediments to the southwest of the Cheju Island.Integrating the distribution of terrestrial OC content of each grain size category with the δ13C of the bulk sediment indicated that the terrestrial organic material in the Changjiang River Estuary was transported seaward and dispersed to the Cyclonic Eddy modern sediments to the southwest of the Cheju Island via two pathways:one was a result of the Changjiang River Diluted Water(CDW) northeastward extending branch driven by the North Jiangsu Coastal Current and the Yellow Sea Coastal Current,while the other one was the result of the CDW southward extending branch driven by the Taiwan Warm Current.     

植被对波浪作用下床面切应力影响的数值模拟分析

本文基于OpenFOAM建立三维波浪数值水槽,模拟计算植被水域波浪作用下的床面切应力,分析了入射波高、植被密度、植被淹没高度、水流对植被水域波浪作用下床面切应力的影响。结果表明：纯波时,由于植被的阻水作用,植被水域床面切应力沿程衰减,其衰减程度与入射波高、植被密度及植被淹没高度呈现正相关;与纯波时相比,在波浪和同向流共同作用下正向床面切应力幅值增大,负向床面切应力幅值减小;弱水流对植被水域床面切应力的大小及分布无明显影响;强水流时,床面切应力在植被水域先增大后逐渐减小并在植被水域后显著降低。     

河口区治江围涂对杭州湾水动力及海床影响分析

自二十世纪六十年代起，钱塘江河口进行了大规模治江围涂，人类活动对杭州湾水域的影响越来越为人们关注。基于实测资料的分析和潮汐水流数学模型计算，探讨了钱塘江河口区围涂对杭州湾水域潮汐水流和海床的影响。研究成果可为钱塘江河口和杭州湾的进一步开发治理和环境保护提供科学依据。     

Propagation of water waves over permeable rippled beds

Unsteady two-dimensional Navier-Stokes equations and Navier-Stokes type model equations for porous flow were solved numerically to simulate the propagation of water waves over a permeable rippled bed. A boundary-fitted coordinate system was adopted to make the computational meshes consistent with the rippled bed. The accuracy of the numerical scheme was confirmed by comparing the numerical results concerning the spatial distribution of wave amplitudes over impermeable and permeable rippled beds with the analytical solutions. For periodic incident waves, the flow field over the wavy wall is discussed in terms of the steady Eulerian streaming velocity. The trajectories of the fluid particles that are initially located close to the ripples were also determined. One of the main results herein is that under the action of periodic water waves, fluid particles on an impermeable rippled bed initially moved back and forth around the ripple crest, with increasing vertical distance from the rippled wall. After one or two wave periods, they are then lifted towards the next ripple crest. All of the marked particles on a permeable rippled bed were shifted onshore with a much larger displacement than those on an impermeable bed. Finally, the flow fields and the particle motions close to impermeable and permeable beds induced by a solitary wave are elucidated.     

Multi-bioindicator study of a small estuary in Vendée (France)

Surficial sediment (about 5 mm) was scraped off in 15 stations selected in the Vie Estuary, a small estuary on the French Atlantic coast. The samples, prepared using the suitable methods, were used for comparing the behaviour of periphytic algae, sporopollinic and other palynologic material, ostracoda and foraminifera for proposing a synthetic evaluation of the information provided by each of them. Dinoflagellate cysts, which are found in an almost monospecific assemblage in low-salinity water, are dispersed by tidal currents, but the location of tintinnids in only the lower reaches shows a limited inward transport. Sporopollinic material is clearly related to the adjacent vegetation, indicating a local origin, and then little influence of transport on the microbenthos, even if fragments of freshwater crustaceans and of Pediastrum alga are found down to the mouth in the sporopollinic deposits. This limited transport of microbenthos allows the use of periphytic algae, benthic ostracoda and benthic foraminifera as indicators of local environmental conditions. It was then possible to determine the extent of marine influence in the estuary, to discriminate between the main channel and adjacent basins, and between different stages of evolution of the basins, from a recently dug basin to a eutrophicated one.     

甘孜—理塘蛇绿混杂岩带中段理塘地区混杂岩物质组成及其洋盆演化史

理塘混杂岩位于甘孜-理塘蛇绿混杂岩带中段新龙县-理塘县一带,其内部保存有完整的混杂岩系,包括蛇绿岩残片、洋岛残块、洋内弧残块、复理石建造、裂谷残片、高压变质岩等,是恢复和反演甘孜-理塘洋盆演化的理想地区。在总结前人研究的基础上,结合笔者近年来的研究成果,详细阐述了理塘混杂岩的物质组成、构造环境及形成时代,进一步约束了甘孜-理塘洋盆的时空、性质以及演化历程。LA-ICP-MS锆石U-Pb测年结果表明,甘孜-理塘混杂岩带内蛇绿岩年龄为（346±17）Ma、（286.2±5.1）Ma、（219.5±2.2）Ma、（216.1±2.3）Ma,洋岛年龄为（271±10）Ma、（245.1±1.5）Ma、（211.8±1.8）Ma,在侏罗纪瑞环山组粉砂岩夹层中测得碎屑锆石最新年龄为（196±3）Ma,结合大量的古生物化石鉴定结果,分析认为理塘混杂岩最早的年龄记录可追溯至中泥盆世,最晚可延至早白垩世,是甘孜-理塘洋盆中泥盆世-早白垩世连续演化的记录。综合以上研究成果,笔者还大致建立了甘孜-理塘洋盆晚古生代-中生代的演化过程模式。     

疏浚物中镉释放的影响条件

本文模拟研究了疏浚沉积物中Ｃd的释放行为和影响条件。结果表明介质的盐度、pＨ、氧化还原状态等环境条件和疏浚沉积物的污染程度、粒度大小、有机质含量等理化特征对Ｃd的 释放有明显的影响。Ｃd从疏浚物中释放,其释放速率较快,释放率在４０％～９６％之间。疏物的海上倾弃可能引起Ｃd的污染和对部分生态环境的危害。同时还讨论了Ｃd的释放所遵循的动力学规律。     

Corrected Formula of Bed Resistance Coefficient for Plane Numerical Simulation of Tidal Current

By means of a logarithm law for the velocity profile,a corrected formula of bed resistancecoefficient,which involves many factors such as gradient of still water depth,variation of surfaceelevation,flow direction,and so on,is derived from the 3D governing equations of tidal current by aver-aging over the whole water depth.Theoretical analysis and application have shown that the 2D plane tidalcurrent numerical model would be more reasonable and could be applied to steep bottom topographywhen the corrected bed resistance coefficient is used,therefore the results of reproduction simulation andengineering calculation would be more scientific and reasonable.     

抛石防波堤人工护面块体强度模拟研究

本文主要研究了混凝土人工护面块体在模型试验中的强度模拟问题，根据不同比尺要求的强度指标，确定新型材料组成成份及其配比，并针对已有防波堤护面块体的破坏情况，进行了水槽模型验证试验。