山东泰安朱家庄自然硫矿床地质概要

山东省泰安朱家庄自然硫矿床,赋存于鲁西断隆古近纪汶东陆相盆地。自然硫矿层在汶口组二段上亚段,泥质灰岩-含泥灰岩-含云灰岩-石膏岩韵律层中的白云岩-石膏岩层段发育。自然硫以胶态、晶态、土态3种形态产出,可划分为顺层型、准顺层型、斑杂型及不顺层型4大类10余种矿石类型。从矿区去膏化作用普遍、自然硫与石膏-硬石膏分别富集轻-重同位素的特征、油气显示明显及地下水主要径流方向自然硫矿化最强等各种证据,表明该矿属生物后生成因的矿床。     

Thorium and uranium isotopes in a manganese nodule from the Peru basin determined by alpha spectrometry and thermal ionization mass spectrometry (TIMS): Are manganese supply and growth related to climate?

Thorium- and uranium isotopes were measured in a diagenetic manganese nodule from the Peru basin applying alpha- and thermal ionization mass spectrometry (TIMS). Alpha-counting of 62 samples was carried out with a depth resolution of 0.4 mm to gain a high-resolution²³⁰Th_excess profile. In addition, 17 samples were measured with TIMS to obtain precise isotope concentrations and isotope ratios. We got values of 0.06–0.59 ppb (²³⁰Th), 0.43–1.40 ppm (²³²Th), 0.09–0.49 ppb (²³⁴U) and 1.66–8.24 ppm (²³⁸U). The uranium activity ratio in the uppermost samples (1–6 mm) and in two further sections in the nodule at 12.5±1.0 mm and 27.3–33.5 mm comes close to the present ocean water value of 1.144±0.004. In two other sections of the nodule, this ratio is significantly higher, probably reflecting incorporation of diagenetic uranium. The upper 25 mm section of the Mn nodule shows a relatively smooth exponential decrease in the²³⁰Th_excess concentration (TIMS). The slope of the best fit yields a growth rate of 110 mm/Ma up to 24.5 mm depth. The section from 25 to 30.3 mm depth shows constant²³⁰Th_excess concentrations probably due to growth rates even faster than those in the top section of the nodule. From 33 to 50 mm depth, the growth rate is approximately 60 mm/Ma. Two layers in the nodule with distinct laminations (11–15 and 28–33 mm depth) probably formed during the transition from isotopic stage 8 to 7 and in stage 5e, respectively. The Mn/Fe ratio shows higher values during interglacials 5 and 7, and lower ones during glacials 4 and 6. A comparison of our data with data from adjacent sediment cores suggests (a) a variable supply of hydrothermal Mn to sediments and Mn nodules of the Peru basin or (b) suboxic conditions at the water sediment interface during periods with lower Mn/Fe ratios.     

辽宁北部秀水盆地秀D1井孢粉组合及其地层意义

孢粉化石采自辽宁省北部秀水盆地的秀D1井,分析、鉴定和系统研究结果表明,来自秀D1井井深62.1~1089.7m的孢粉化石自下而上划分为3个孢粉组合,下部孢粉组合(井深703.85~1089.7m)以Osmundacidites-Klukisporites-Podocarpidites为代表,地质时代为晚侏罗世堤塘期(Tithonian),中部孢粉组合(井深381.5~699.3m)以Densoisporites-Cicatricosisporites-Piceaepollenites为代表,地质时代为早白垩世贝里阿斯期(Berriassian),上部孢粉组合(井深62.1~339m)以Cicatricosisporites-Impardecispora-Pinuspollenites为代表,地质时代为早白垩世凡兰吟期—欧特里夫期(Valanginian-Hauterivian)。秀D1井钻遇地层所含孢粉组合特征在区域上可以与冀北地区大北沟组,辽宁西部地区下白垩统义县组、九佛堂组,松辽盆地东南缘下白垩统火石岭组、沙河子组所产的孢粉组合对比。含孢粉组合地层时代的确定解决了井柱地层的划分,以及与区域地层的对比关系,同时为区域地层古生物研究提供了翔实的基础资料。     

Effects of Deep Fluids on Hydrocarbon Generation and Accumulation in Chinese Petroliferous Basins

Deep fluids in a petroliferous basin generally come from the deep crust or mantle beneath the basin basement, and they transport deep substances(gases and aqueous solutions) as well as heat to sedimentary strata through deep faults. These deep fluids not only lead to large-scale accumulations of CO_2, CH_4, H_2, He and other gases, but also significantly impact hydrocarbon generation and accumulation through organic-inorganic interactions. With the development of deep faults and magmatic-volcanic activities in different periods, most Chinese petroliferous basins have experienced strong impacts associated with deep fluid activity. In the Songliao, Bohai Bay, Northern Jiangsu, Sanshui, Yinggehai and Pearl Mouth Basins in China, a series of CO_2 reservoirs have been discovered. The CO_2 content is up to 99%, with δ~(13)C_(CO2) values ranging from-4.1‰ to-0.37‰ and ~3He/~4He ratios of up to 5.5 Ra. The abiogenic hydrocarbon gas reservoirs with commercial reserves, such as the Changde, Wanjinta, Zhaozhou, and Chaoyanggou reservoirs, are mainly distributed in the Xujiaweizi faulted depression of the Songliao Basin. The δ~(13)CCH4 values of the abiogenic alkane gases are generally -30‰ and exhibit an inverse carbon isotope sequence of δ~(13)C_(CH4)δ~(13)C_(C2H6)δ~(13)C_(C3H8)δ~(13)C_(C4H10). According to laboratory experiments, introducing external H_2 can improve the rate of hydrocarbon generation by up to 147% through the kerogen hydrogenation process. During the migration from deep to shallow depth, CO_2 can significantly alter reservoir rocks. In clastic reservoirs, feldspar is easily altered by CO_2-rich fluids, leading to the formation of dawsonite, a typical mineral in high CO_2 partial pressure environments, as well as the creation of secondary porosity. In carbonate reservoirs, CO_2-rich fluids predominately cause dissolution or precipitation of carbonate minerals. The minerals, e.g., calcite and dolomite, show some typical features, such as higher homogenization temperatures than the burial temperature, relatively high concentrations of Fe and Mn, positive Eu anomalies, depletion of 18 O and enrichment of radiogenic ~(87)Sr. Due to CO_2-rich fluids, the development of high-quality carbonate reservoirs is extended to deep strata. For example, the Well TS1 in the northern Tarim Basin revealed a high-quality Cambrian dolomite reservoir with a porosity of 9.1% at 8408 m, and the Well ZS1 C in the central Tarim Basin revealed a large petroleum reserve in a Cambrian dolomite reservoir at ~6900 m. During the upward migration from deep to shallow basin strata, large volumes of supercritical CO_2 may extract petroleum components from hydrocarbon source rocks or deep reservoirs and facilitate their migration to shallow reservoirs, where the petroleum accumulates with the CO_2. Many reservoirs containing both supercritical CO_2 and petroleum have been discovered in the Songliao, Bohaiwan, Northern Jiangsu, Pearl River Mouth and Yinggehai Basins. The components of the petroleum trapped with CO_2 are dominated by low molecular weight saturated hydrocarbons.     

塔里木河流域适应气候变化和人类活动的应对措施

自2001年开始实施塔里木河流域近期综合治理工程,提出了以强化流域水资源统一管理和调度为核心,以源流区节水改造和干流河道治理为重点进行综合治理,积极稳妥地进行经济结构调整,实施退耕封育保护,有效保护好现有天然林草植被.通过向塔里木河下游生态输水,干涸近30a的台特玛湖于2001年11月16日开始有水,使塔里木河下游绿色走廊得到初步复苏等,流域生态环境得到极大的恢复.然而,自2007年以来,塔里木河向下游输水已大为减少,仅能输水到中游,特别是2009年水文干旱,塔里木河干流断流达1 100km多,使下游绿色走廊再度陷入生态危机.为此,需要重新审视塔里木河流域的综合治理,从加强源流治理开始,来巩固干流治理成果.认真总结10a来治理经验与教训,针对人类活动和气候变化对源流与干流造成的影响程度,积极采取应对措施.     

内蒙古巴彦塔拉盆地砂岩型铀矿化的蚀变特征

巴彦塔拉盆地砂岩型铀矿床产于下白垩统赛汉塔拉组下段辫状河流相砂岩中。本文通过对含矿主岩沉积特征、矿化和矿床蚀变特征的分析研究 ,认为早期为潜水氧化蚀变成矿 ;晚期为层间氧化 油气还原蚀变成矿 ,即来自蚀源区和天窗补给的含铀、含氧地下水遇沿断裂 (F2 1)上升的含H2 S的油气还原叠加改造成矿     

Sensitivity assessment of strontium isotope as indicator of polluted groundwater for hydraulic fracturing flowback fluids produced in the Dameigou Shale of Qaidam Basin

Hydrogeochemical processes that would occur in polluted groundwater and aquifer system, may reduce the sensitivity of Sr isotope being the indicator of hydraulic fracturing flowback fluids(HFFF) in groundwater. In this paper, the Dameigou shale gas field in the northern Qaidam Basin was taken as the study area, where the hydrogeochemical processes affecting Sr isotope was analysed. Then, the model for Sr isotope in HFFF-polluted groundwater was constructed to assess the sensitivity of Sr isotope as HFFF indicator. The results show that the dissolution can release little Sr to polluted groundwater and cannot affect the εSr(the deviation of the 87 Sr/86 Sr ratio) of polluted groundwater. In the meantime, cation exchange can considerably affect Sr composition in the polluted groundwater. The Sr with low εSr is constantly released to groundwater from the solid phase of aquifer media by cation exchange with pollution of Quaternary groundwater by the HFFF and it accounts for 4.6% and 11.0% of Sr in polluted groundwater when the HFFF flux reaches 10% and 30% of the polluted groundwater, respectively. However, the Sr from cation exchange has limited impact on Sr isotope in polluted groundwater. Addition of Sr from cation exchange would only cause a 0.2% and 1.2% decrease in εSr of the polluted groundwater when the HFFF flux reaches 10% and 30% of the polluted groundwater, respectively. These results demonstrate that hydrogeochemical processes have little effect on the sensitivity of Sr isotope being the HFFF indicator in groundwater of the study area. For the scenario of groundwater pollution by HFFF, when the HFFF accounts for 5%(in volume percentage) of the polluted groundwater, the HFFF can result in detectable shifts of εSr(ΔεSr=0.86) in natural groundwater. Therefore, after consideration of hydrogeochemical processes occurred in aquifer with input of the HFFF, Sr isotope is still a sensitive indicator of the Quaternary groundwater pollution by the HFFF produced in the Dameigou shale of Qaidam Basin.     

山西大同-阳高地震活动背景

通过对大同盆地历史地震活动及大同盆地历史地震活动与华北地震区、山西地震带强震活动的关系的研究，得出山西大同-阳高1989年6．1级地震活动是这一地区历史地震的延续，是华北北部中强地震活动的重要组成部分，具有广义前震的重要意义，其后对应发生的河北张北6．2级地震。标志着华北地震区的地震活动期已进入尾声。     

A constitutive model for mechanical and chemo‐mechanical compaction in sedimentary basins and finite element analysis

Compaction and associated fluid flow are fundamental processes in sedimentary basin deformation. Purely mechanical compaction originates mainly from pore fluid expulsion and rearrangement of solid particles during burial, while chemo‐mechanical compaction results from Intergranular Pressure‐Solution (IPS) and represents a major mechanism of deformation in sedimentary basins during diagenesis. The aim of the present contribution is to provide a comprehensive 3D framework for constitutive and numerical modeling of purely mechanical and chemo‐mechanical compaction in sedimentary basins. Extending the concepts that have been previously proposed for the modeling of purely mechanical compaction in finite poroplasticity, deformation by IPS is addressed herein by means of additional viscoplastic terms in the state equations of the porous material. The finite element model integrates the poroplastic and poroviscoplastic components of deformation at large strains. The corresponding implementation allows for numerical simulation of sediments accretion/erosion periods by progressive activation/deactivation of the gravity forces within a fictitious closed material system. Validation of the numerical approach is assessed by means of comparison with closed‐form solutions derived in the context of a simplified compaction model. The last part of the paper presents the results of numerical basin simulation performed in one dimensional setting, demonstrating the ability of the modeling to capture the main features in elastoplastic and viscoplastic compaction. Copyright © 2016 John Wiley & Sons, Ltd.     

中国西北内陆盆地水分垂直循环及其生态学意义

中国西北内陆盆地中的地下水系统,对维系其浅表水分、热量、盐分均衡以及地表的生态平衡、土壤的资源属性和局部地域气候相对稳定性具有不可或缺的调节作用,这种调节作用是通过饱和带水、包气带水(土壤水)、近地表大汽水和植物体内水("四水")之间的垂直循环来实现的.目前的相关研究主要侧重于地下水与地表植被类型间对应关系的统计分析,较少涉及水分运移的机制;而以水分垂直循环的动力学机制为研究对象的SPAC系统(土壤-植物-大气连续体),则对地下水的重视程度不够,且存在着尺度转换的困难,更为完整的应该是GSPAC系统(地下水-土壤-植物-大气连续体).干旱区内陆盆地地下水生态效应的研究需要开展以下的工作:"四水"垂直循环的动力学过程与机制研究,尤其是饱水带-包气带界面水、汽、热转化过程的研究;人类活动影响下地下水系统演化特征的研究,它不仅是实现水分垂直循环研究的最终目的——水资源合理开发利用的中间环节,更是将"四水"垂直循环这一微观水文循环过程与区域水文循环过程相结合,实现尺度转化的关键所在.