基于壳聚糖席夫碱类衍生物修饰电极测定食品中的亚硝酸根离子

利用水杨醛对壳聚糖进行改性,合成壳聚糖席夫碱类衍生物(S-CTS),将其滴涂在玻碳电极表面成膜。用循环伏安法研究了该修饰电极对NO2-的电催化作用。以0.1mol/LpH4.5的B-R缓冲溶液为底液,还原峰电流与NO2-浓度在0.20～81mg/kg范围内呈良好的线性关系,相关系数为0.9899,检测限达到2.8×10-7mol/L。用于样品测定,结果较为满意。     

利用重力异常研究虎林盆地的构造分区和基底形态

首先应用MATLAB语言,编制了多边形法计算基底界面深度的程序,计算了一条基底界面深度。以区域地质资料和物性资料为依据,对黑龙江省虎林市幅1∶20万重磁场进行了综合分析。根据虎林盆地布格异常和区域场特征,结合重力异常和航磁异常等综合资料,按结晶基底起伏状态,将虎林盆地划分为3个隆起区,2个凹陷区。应用Sufer软件以及3D成图技术恢复出盆地基底起伏界面全貌。     

大比例尺土地利用数据库建设有关技术问题的探讨

地籍调查、村集体土地所有权调查和土地利用调查对调查底图的要求不同,在土地利用数据库建设的过程中应综合考虑;GPS、GIS和RS技术的应用,改变了土地利用调查的技术流程,提高了调查效率;土地利用数据库质量控制包括质量检查方法、质量标准和质量责任体系。     

预植入金刚石微粉的WC-Co合金表面金刚石薄膜沉积特征

通过提高金刚石薄膜与硬质合金基底间的粘结力,可提高涂层工具的使用寿命。实验结果表明,在预植入金刚石微粉的硬质合金表面沉积金刚石薄膜,金刚石既在预植入金刚石表面同质外延生长,又在硬质合金上结晶生长,两者交互生长,且相容性较好,最终生长为致密均匀的金刚石薄膜。     

Resource-based development in the Russian Far East: Problems and prospects

The paper examines the prospects for resource-based development in the Russian Far East. It adopts a critical perspective on the potential for resource-based development by examining problems with Far East resource industries, specifically by looking at the experience of the other resource economies more generally. In particular, it highlights the new geo-economic context for resource development in the Far East of Russia as the world economy approaches the much touted, and now questioned, ‘Pacific Century’.     

能源基地地下水污染及防治措施

能源基地地下水已受到不同程度的污染,随着基地大规模开发建设,地下水污染将更加严重。对基地一些地区地下水的污染特征、污染途径和污染源进行了分析研究,并在此基础上提出了相应的防治措施和建议。     

Geothermal resource assessment of the United States

Geothermal resource assessment is the broadly based appraisal of the quantities of heat that might be extracted from the earth and used economically at some reasonable future time. In the United States, the Geological Survey is responsible for preparing geothermal assessments based on the best available data and interpretations. Updates are required every few years owing to increasing knowledge, enlarging data base, improving technology, and changing economics. Because geothermal understanding is incomplete and rapidly evolving, the USGS complements its assessments with a broad program of geothermal research that includes (1) study of geothermal processes on crustal and local scales, (2) regional evaluations, (3) intensive study of type systems before and during exploitation (4) improvement of exploration techniques, and (5) investigation of geoenvironmental constraints.     

Efficiency verification of a horizontal flow barrier via flowmeter tests and multilevel sampling

The remediation strategy for an industrial site located in a coastal area involves a pump and treat system and a horizontal flow barrier (HFB) penetrating the main aquifer. To validate the groundwater flow conceptual model and to verify the efficiency of the remediation systems, we carried out piezometric measurements, slug tests, pumping tests, flowmeter tests and multilevel sampling. Flowmeter tests are used to infer vertical groundwater flow directions, and base exchange index is used to infer horizontal flow directions at a metric scale. The selected wells are located both upstream and downstream of the HFB. The installation of the HFB produced constraints to the groundwater flow. A stagnant zone of contaminated freshwater floating over the salt wedge in the upper portion of the aquifer is detected downstream of the HFB. This study confirms that the adopted remediation system is efficiently working in the area upstream of the HFB and even downstream in the bottom part of the aquifer. At the same time, it has also confirmed that hot spots are still present in stagnant zones located downstream of the HFB in the upper part of the aquifer, requiring a different approach to accomplish remediation targets. The integrated approach for flow quantification used in this study allows to discriminate the direction and the magnitude of groundwater fluxes near an HFB in a coastal aquifer. Copyright © 2012 John Wiley & Sons, Ltd.     

Salinograph trends as indicators of the recession characteristics of stream components

Compared to hydrograph recession analysis, which is widely applied in engineering hydrology, the quantitative assessment of stream salinity with time (i.e. the salinograph) has received significantly less attention. In particular, while in many previous hydrological studies an inverse relationship between hydrograph and salinograph responses is apparent, the concept of salinity accession (the inversely related salinity counterpart to hydrograph recession) has not been introduced nor quantitatively evaluated in previous literature. In this study, we conduct a mathematical analysis of salinograph accession, and determine new quantitative relationships between salinity accession and hydrograph recession parameters. An equation is formulated that reproduces the general trend in salinity accession. A salinity accession parameter k_c is then introduced and is shown to be the ratio of direct runoff to total stream flow recession parameters: k_r/k. The groundwater recession parameter k_g was estimated using a simple and rapid method that uses both salinograph and hydrograph data. Salinity accession type‐curves illustrate that under certain conditions, the relative steepness of individual salinographs is dependent upon the ratio of groundwater salinity to direct runoff salinity: C_g/C_r. The salinity accession algorithms are applied to two contrasting field settings: Scott Creek, South Australia and Sandy Creek, northern Queensland, Australia. It was found that k_g > k during periods of obvious stream flow recession, for the events analysed. Salinograph accession behaviour was fairly similar for both sites, despite contrasting environments. Using assumed end‐member salinities for groundwater and direct runoff based upon field observations, the behaviour of k_c from the Scott Creek site was approximately reproduced by varying the initial groundwater to runoff flow ratio: Q_g0/Q_r0, within reasonable parameter ranges. The use of salinograph information when used in addition to standard hydrograph analyses provided useful information on recession characteristics of stream components. Copyright © 2008 John Wiley & Sons, Ltd.     

Synthesis, Characterization and Antibacterial Activity of New Ln（Ⅲ ） Complexes with an Unsymmetrical Schiff Base Ligand

1Introduction SomeSchiffbasecomplexesderivedfromaminoacidsareparticularlyactiveinbiologycatalysisandmaterial.Thestudyofthemisfocusofthestudyof coordinationchemistry.Recently,studiesofsuchmetalcomplexesofmono Schiffbaseshavebeenre ported(Fanetal.,2003a,b;L…