Wavelet analysis of inter‐annual variability in the runoff regimes of glacial and nival stream catchments,Bow Lake,Alberta

Continuous wavelet analyses of hourly time series of air temperature, stream discharge, and precipitation are used to compare the seasonal and inter‐annual variability in hydrological regimes of the two principal streams feeding Bow Lake, Banff National Park, Alberta: the glacial stream draining the Wapta Icefields, and the snowmelt‐fed Bow River. The goal is to understand how water sources and flow routing differ between the two catchments. Wavelet spectra and cross‐wavelet spectra were determined for air temperature and discharge from the two streams for summers (June–September) 1997–2000, and for rainfall and discharge for the summers of 1999 and 2000. The diurnal signal of the glacial runoff was orders of magnitude higher in 1998 than in other years, indicating that significant ice exposure and the development of channelized glacial drainage occurred as a result of the 1997–98 El Niño conditions. Early retreat of the snowpack in 1997 and 1998 led to a significant summer‐long input of melt runoff from a small area of ice cover in the Bow River catchment; but such inputs were not apparent in 1999 and 2000, when snow cover was more extensive. Rainfall had a stronger influence on runoff and followed quicker flow paths in the Bow River catchment than in the glacial catchment. Snowpack thickness and catchment size were the primary controls on the phase relationship between temperature and discharge at diurnal time scales. Wavelet analysis is a fast and effective means to characterize runoff, temperature, and precipitation regimes and their interrelationships and inter‐annual variability. The technique is effective at identifying inter‐annual and seasonal changes in the relative contributions of different water sources to runoff, and changes in the time required for routing of diurnal meltwater pulses through a catchment. However, it is less effective at identifying changes/differences in the type of the flow routing (e.g. overland flow versus through flow) between or within catchments. Copyright © 2003 John Wiley & Sons, Ltd.     

Sea‐surface temperature and salinity changes in the northwest Pacific since the Last Glacial Maximum

The oxygen isotope records of both benthic and planktonic Foraminifera in five piston cores, collected from the region between the Oyashio and Kuroshio Currents near Japan, clearly show the marked latitudinal shifts of these two currents during the past 25 kyr. Under the present hydrographic condition, a clear relationship between the sea‐surface temperature (SST) and oxygen isotope differences from benthic to planktonic Foraminifera is observed in this region. Using this relationship, we find decreased SSTs of 12–13°C (maximum 15°C) in the southernmost core site at the Last Glacial Maximum (LGM), indicating the Oyashio Current shifted southward. The SSTs at the southern two core sites abruptly increased more than 10°C at 10–11 ka, suggesting the Kuroshio Current shifted northward over these sites at 10–11 ka. In contrast, the northern two core sites have remained under the influence of the cold Oyashio Current for the past 25 kyr. With the reasonable estimate of bottom‐water temperature decrease of 2.5°C at the LGM, the SSTs estimated by this new method give exactly the same SST values calculated from Mg/Ca ratio of planktonic Foraminifera, allowing palaeosea‐surface salinities to be reconstructed. The result suggests that the ice volume effect was 1.0 ± 0.1‰ at the LGM. Copyright © 2004 John Wiley & Sons, Ltd.     

中国石油生产的展顾

本文分析了中国石油生产近20年变化的原因,对一些学者认为80年代中国会成为超级产油大国,后又悲观断定80年代中国可能变成石油净进口国作了评述。同时对90年代中国石油生产前景作了初步展望。     

Subtidal sea level and current variations in the northern reach of San Francisco Bay

Analyses of sea level and current-meter data using digital filters and a variety of statistical methods show a variety of phenomena related to non-local coastal forcing and local tidal forcing in the northern reach of San Francisco Bay, a partially mixed estuary. Low-frequency variations in sea level are dominated by non-local variations in coastal sea level and also show a smaller influence from tidally induced fortnightly sea level variations. Low-frequency currents demonstrate a gravitational circulation which is modified by changes in tidal-current speed over the spring-neap tidal cycle. Transients in gravitational circulation induce internal oscillations with periods of two to four days.     

Implications of low-pass filtering on power spectra and autocorrelation functions of turbulent velocity signals

Filtering either through the electronics of an instrument or through digital procedure is performed routinely on geophysical data. When velocity fluctuations are measured in turbulent flows using electromagnetic current meters (ECMs), a builtin lowpass Butterworth filter of order n usually attenuates fluctuations at high frequencies. However, the effects of this filter may not be acknowledged in turbulence studies, thus impeding comparisons between data collected with different ECMs. This paper explores the implications of the filters on the characteristics of velocity signals, mainly on variance, power spectra, and correlation analyses. Variance losses resulting from filtering can be important but will vary with the order n of the Butterworth filter, decreasing as n increases. Knowing the filter response, it is possible to reconstruct the original signal spectrum to evaluate the effect of filtering on variance and to allow comparisons between data collected with different instruments. The autocorrelation function also is affected by filtering which increases the value of the coefficients in the first lags, resulting in an overestimation of the integral length scale of coherent structures. These important effects add to those related to size and shape differences in ECM sensors and must be taken into account in comparative studies.     

基于网络药理学探究补阳还五汤治疗颈椎病的作用机制

目的：基于网络药理学与分子对接技术分析补阳还五汤治疗颈椎病的作用机制。方法：使用TCMSP、化学专业数据库获取补阳还五汤的活性成分,并对潜在靶点进行预测及规范。分别从PharmGKB、DisGeNET、OMIM、GeneCards数据库中得到颈椎病疾病靶点,利用韦恩图获取补阳还五汤与颈椎病的交集靶点。通过CytoScape软件构建中药-活性成分-疾病靶点和蛋白质-蛋白质相互作用（PPI）网络,获得核心有效成分与关键靶点,利用David数据库对潜在靶点进行富集分析。最后运用AutoDock Vina软件对补阳还五汤核心有效成分与关键靶点进行分子对接验证。结果：共获得补阳还五汤治疗颈椎病的有效活性成分97个,包括槲皮素、山柰酚、黄芩素、木犀草素等;交集靶点64个,关键靶点有白细胞介素-6（IL-6）、肿瘤坏死因子（TNF）、丝氨酸/苏氨酸蛋白激酶1（AKT1）、白细胞介素-1B（IL-1B）等;主要涉及肿瘤坏死因子（TNF）、白细胞介素-17（IL-17）、磷脂酰肌醇3-激酶（PI3K）/蛋白激酶B（Akt）等信号通路,分子对接结果显示核心有效成分与关键靶点之间结合紧密,为补阳还五汤治疗颈椎病提供相应条件。结论：该研究在总体上预测了补阳还五汤治疗颈椎病的活性成分、靶点和信号通路,作用途径广泛,为下一步的临床应用提供参考及思路。     

White-light promoted degradation of leucopterin and related pteridines dissolved in seawater, with evidence for involvement of complexation from major divalent cations of seawater

The photochemical instability of several related pteridines in seawater was investigated by aseptic incubation of solutions at 20–22°C under illumination from cool-white light of intensity 6 kerg cm⁻² sec⁻¹, and the chemical changes were spectrophotometrically monitored. All the pteridines showed markedly accelerated degradation from this illumination relative to their behaviour in total darkness.Pterin and lumazine were degraded very slowly with zero-order reaction kinetics, while the other pteridines photolysed rapidly (according to first-order kinetics) with decomposition rates increasing in the order dioxylumazine (2,4,6,7-tetrahydroxypteridine) < leucopterin < isoxanthopterin < xanthopterin < oxylumazine (2,4,6-trihydroxypteridine). Excepting leucopterin and dioxylumazine, the photolysis rates were attributable to the pH of seawater and not its salt content; this was also the case with oxylumazine which required the salt content of seawater for decomposition in darkness. Leucopterin and dioxylumazine (both 6,7-dihydroxylated pteridines) gave evidence of complexation with the major divalent cations (Ca²⁺, Mg²⁺) of seawater, by virtue of which their photolytic degradation rates were enhanced to magnitudes obtained in pH-10 buffer without seawater. It is proposed that such complexation produces structural forms of these pteridines analogous to their normal ionic forms at pH 10–12.The photolysis of the 6-hydroxylated pteridines (xanthopterin, oxylumazine) proceeded via intermediate formation of their corresponding 7-hydroxylated derivatives (leucopterin, dioxylumazine).     

Freshening of the Intermediate Waters in the Northern South China Sea over the PastSix Decades

The properties of salinity in the South China Sea (SCS), a significant marginal sea connecting the Pacific andIndian Oceans, are greatly influenced by the transport of fresh water flux between the two oceans. However, the long-termchanges in the intermediate water in the SCS have not been thoroughly studied due to limited data, particularly in relationto its thermodynamic variations. This study utilized reanalysis data products to identify a 60-year trend of freshening in theintermediate waters of the northern South China Sea (NSCS), accompanied by an expansion of low-salinity water. Thestudy also constructed salinity budget terms, including advection and entrainment processes, and conducted an analysis ofthe salinity budget to understand the impacts of external and internal dynamic processes on the freshening trend of theintermediate water in the NSCS. The analysis revealed that the freshening in the northwest Pacific Ocean and theintensification of intrusion through the Luzon Strait at intermediate levels are the primary drivers of the salinity changes inthe NSCS. Additionally, a weakened trend in the intensity of vertical entrainment also contributes to the freshening in theNSCS. This study offers new insights into the understanding of regional deep sea changes in response to variations in boththermodynamics and oceanic dynamic processes.     

山西能源重化工基地建设研究

山西能源重化工基地建设关系到全国四个现代化的实现,被列为国家重点建设工程,制定了《山西能源重化工基地综合规划》。本文分析了80年代山西省经济建设的成就与问题。提出了“整体创新,综合开发”,把山西能源重化工基地建设成内陆经济开放区的战略大思路,为此,90年代应完成11项大型经济战略工程,同时展望了经济发展改革前景。