机械力化学改性硅灰石表面行为TEM的研究

选用气流磨超音速气流作为机械力,对硅灰石、硬脂酸进行超细粉碎－表面改性。应用透射电子显微镜分析、观察硅石灰／硬脂酸复合粉体界面微观形貌及成分（Ｃａ、Ｓｉ、Ｃ）的变化规律。ＴＥＭ能谱分析结果表明：从硅灰石到硬脂酸,Ｃａ、Ｓｉ含量逐渐降低,Ｃ含量则逐渐升高。     

Multifractal detrended fluctuation analysis of streamflow series of the Yangtze River basin,China

Scaling and multifractal properties of the hydrological processes of the Yangtze River basin were explored by using a multifractal detrended fluctuation analysis (MF‐DFA) technique. Long daily mean streamflow series from Cuntan, Yichang, Hankou and Datong stations were analyzed. Using shuffled streamflow series, the types of multifractality of streamflow series was also studied. The results indicate that the discharge series of the Yangtze River basin are non‐stationary. Different correlation properties were identified within streamflow series of the upper, the middle and the lower Yangtze River basin. The discharge series of the upper Yangtze River basin are characterized by short memory or anti‐persistence; while the streamflow series of the lower Yangtze River basin is characterized by long memory or persistence. h(q) vs q curves indicate multifractality of the hydrological processes of the Yangtze River basin. h(q) curves of shuffled streamflow series suggest that the multifractality of the streamflow series is mainly due to the correlation properties within the hydrological series. This study may be of practical and scientific importance in regional flood frequency analysis and water resource management in different parts of the Yangtze River basin. Copyright © 2008 John Wiley & Sons, Ltd.     

强震前的“干热异常”与地温、降水波及应变弱停

对近30年出现在中国西部及邻区的14次MS≥6.9强震前1年多内的地温场和降水场进行了分析。发现有如下共同规律:①在震前1年左右东亚地区会出现干热异常(3.2 m地温升高,同时降水距平为负值),持续时间约为2~6个月,最大干热面积可达2~4×106km2;②在震前0.5~1年左右我国的月降水距平%图和3.2 m地温距平的月际变温图上,可看到波长小于1 000 km的地温波和降水波,可称为"超低频应力密度波(应变波)"[1],它是致使岩石破裂的力源;③在震前0~2个月应变波的波长会停止缩短,振幅变小,且波动方向可有一个近90°的旋转,是"应变弱停"[1]的表现。以上可视为孕震三步曲。依据上述统计事实本文提出了强震成因的假设:地外核中有一股热力极不稳定的Benard上升流体对其上的壳幔层形成顶托,造成地温升高,对流热传导系数变小,形成干热异常;岩石圈中脆性层的应力不断增大,致使出现不稳定波(应变波);出现"应变弱停"时意味着强震即将爆发。     

SMALL项目数字化地磁资料可靠性分析

在对中美合作 SMALL (中国低纬地磁台阵 )项目安装在北京地磁台 (白家疃 )和云南通海地磁台的磁通门磁力仪记录资料与磁变仪模拟记录资料进行了详细的对比分析后 ,得出的结果表明 ,两者的日变形态、日变幅有较好的一致性 ,所选特定事件的变化幅度非常一致 ,说明磁通门磁力仪记录到的变化磁场的资料是真实可靠的。尽管目前磁通门磁力仪的基线值存在温度影响和离散度较大的问题 ,但随温度变化有明显的规律性 ,若能采取改进观测条件和观测方法以及缩短观测时间等措施 ,并对基线值进温度校正 ,磁通门磁力仪完全可以提供长期连续可靠的资料。而其为地震预报 ,空间环境预报 ,为日地物理 ,空间物理和地磁学的研究提供的高精度、高分辨率、连续可靠的数字化变化磁场资料是磁变仪模拟记录无法比拟的。     

青海湖近600年的水位变化

根据王苏民＾「４」给出的青海湖深水区重力岩芯的密集采样结果,重建了青胡近６００年的水位变化,发现水位变化与降水关系密切,水位的长降时段与降水的丰枯时段相对应,６００年来青海湖区的环境变化有１８０年左右的周期。     

Distribution of petroleum hydrocarbons in soils and the underlying unsaturated subsurface at an abandoned petrochemical site,North China

Contamination characteristics of petroleum hydrocarbons in soils and the underlying unsaturated subsurface were analysed by investigating and sampling at different depth of five boreholes named SH1 through SH5 at a typical petrochemical site, North China. Topsoil volatile organic gas measurement revealed that SH‐3 was the center of one pollution plume. Soil samples analysis showed that aromatic hydrocarbons and chlorinated hydrocarbons were major pollutants. Their maximum concentration was found at 6.5 and 14.6 m of SH‐2, 13 m of SH‐5, and 18.5 m of SH‐3. These pollutants are mostly accumulated on the interface between two different lithological layers, especially between the sand and silt clay layers. Denitrifying and iron reducing were main biogeochemical processes in this site. Under the influence of groundwater level fluctuation, free NAPLs passed through the boundary and dissolved into the lower groundwater. Knowledge of these associations between contaminant distributions and affecting factors could have implications for soil and groundwater pollution prevention and control. Copyright © 2013 John Wiley & Sons, Ltd.     

Municipal water demand forecasting under peculiar fluctuations in population: a case study of Mashhad,a tourist city

ABSTRACT

Forecasting future water demands has always been of great complexity, especially in the case of tourist cities which are subject to population fluctuations. In addition to the usual uncertainties related to climate and weather variables, daily water consumption in Mashhad, a tourist city is affected by a significant different fluctuation. Mashhad is the second most populous city in Iran. The number of tourists visiting the city is subject to national and religious events, which are respectively based on the Iranian formal calendar (secular calendar) and the Arabic Hijri calendar (Islamic religious calendar). Since religious events move relative to the secular calendar, the coincidence of the two calendars results in peculiar wild fluctuations in population. Artificial neural networks (ANNs) are chosen to predict water demand under such conditions. Three types of ANNs, feedforward back-propagation, cascade-forward and radial basis functions, are developed. In order to track how population fluctuation propagates in the model and affects the outputs, two sets of inputs are considered. For the first set, based on evaluating several repetitions, a typical combination of variables is selected as inputs, whereas for the second set, new calendar-based variables are included to decrease the effect of population fluctuations; the results are then compared using some performance criteria. A large number of runs are also conducted to assess the impact of random initialization of the weights and biases of networks and also the effect of calendar-based inputs on improvement of network performance. It is shown that, from the points of view of performance measures and unchanging outputs through numerous runs, the radial basis network that is trained by patterns including calendar-based inputs can provide the best domestic water demand forecasting under population fluctuations.

Editor D. Koutsoyiannis Associate editor E. Rozos     

塔里木盆地奥陶系层序地球化学研究

对塔里木盆地奥陶系锶同位素分析表明,在早奥陶世海平面呈下降２,在中晚奥陶世海平面则持续上升并保持在高于奥陶纪平均海平面之上。氧,碳同位素及微量元素的分析结果均支持锶同位素的研究结论。研究表明,沉积层序中发育相应的沉积地球化学样式。     

Investigation of power-law correlations within daily total ozone time series and search for a stable node through phase portrait

In the study reported in this paper we have dealt with the intrinsic complexity of the daily total ozone time series over Mumbai, India (19°23′N, 72 15°00′E) by means of detrended fluctuation analysis and phase portrait analysis. From the detrended fluctuation analysis of first order it is revealed that the said time series is characterized by persistent power-law correlation which is stronger in shorter time scale than in the longer time scale. The phase portrait analysis is based on a non-linear autonomous system generated from regression equations; infinitely many stable nodes are found along the straight line x = 273.556 and from the behaviors of the contours, it has been revealed that the daily total ozone concentration is unlikely to go beyond 315 DU (approximately) and it is almost stable.     

Coastal currents caused by superposition of coastal-trapped waves and near-inertial oscillations observed near the Noto Peninsula, Japan

Current observations were made from 14 July 2006 to 31 March 2007, using an acoustic Doppler current profiler mounted on the seafloor near the eastern coast of the Noto Peninsula, Japan, to investigate strong coastal currents induced by large-amplitude coastal-trapped waves (CTWs) and near-inertial fluctuations (NIFs). The CTWs were generated by the winter monsoon and the passage of a typhoon during the observation period. Two types of strong currents with velocities higher than 50 cm s^-1 were observed. One type, the strong current in winter (SCW), had the coast on the left to its direction of flow. This current was observed after a strengthening of the winter monsoon in January 2007. The other type, the strong current in fall (SCF), had the coast on the right to its direction of flow and was observed after the passage of a typhoon in September 2006. The SCW was inferred to be formed mainly by low-mode CTWs without NIFs. Compared to the SCW, the SCF had a more complicated vertical structure and time variations. The SCF was inferred to be generated by low-mode CTWs strengthened by NIFs. The contributions of NIFs to the strong coastal currents became important when the wind stress direction was rotating clockwise.