A modeling of the structure and favorable H-docking sites and defects for the high-pressure silica polymorph stishovite

Employing first-principles methods, the docking sites for H were determined and H, Al, and vacancy defects were modeled with an infinite periodic array of super unit cells each consisting of 27 contiguous symmetry nonequivalent unit cells of the crystal structure of stishovite. A geometry optimization of the super-cell structure reproduces the observed bulk structure within the experimental error when P1 translational symmetry was assumed and an array of infinite extent was generated. A mapping of the valence electrons for the structure displays mushroom-shaped isosurfaces on the O atom, one on each side of the plane of the OSi₃ triangle in the nonbonded region. An H atom, placed in a cell near the center of the super cell, was found to dock upon geometry optimization at a distance of 1.69 Å from the O atom with the OH vector oriented nearly perpendicular to the plane of the triangle such that the OH vector makes a angle of 91° with respect to [001]. However, an optimization of a super cell with an Al atom replacing Si and an H atom placed nearby in a centrally located cell resulted in an OH distance of 1.02 Å with the OH vector oriented perpendicular to [001] as observed in infrared studies. The geometry-optimized position of the H atom was found to be in close agreement with that (0.44, 0.12, 0.0) determined in an earlier study of the theoretical electron density distribution. The docking of the H atom at this site was found to be 330 kJ mol^–1 more stable than a docking of the atom just off the shared OO edge of the octahedra as determined for rutile. A geometry optimization of a super cell with a missing Si generated a vacant octahedra that is 20% larger than that of the SiO₆ octahedra. The valence electron density distribution displayed by the two-coordinate O atoms that coordinate the vacant octahedral site is very similar to those displayed by the bent SiOSi angles in coesite. The internal distortions induced by the defect were found to diminish rather rapidly with distance, with the structure annealing to that observed in the bulk crystal to within about three coordination spheres.     

黄骅坳陷北大港构造带沙河街组沉积体系定量研究

针对陆相湖盆沉积特征,以T A Cross高分辨率层序地层学理论为指导,在大量岩心、测井和地震资料研究的基础上,定量研究了黄骅坳陷北大港构造带沙河街组沉积体系和沉积物源特征,确定了沙河街组沉积时期总体发育近岸水下扇、滩坝、深水重力流水道、扇三角洲前缘和滑塌浊积扇等主要沉积相类型。中期基准面旋回A-D层序沉积时期发育近岸水下扇和扇三角洲前缘—前扇三角洲—滑塌浊积扇沉积体系;中期基准面旋回E-F层序沉积期间发育有利于油气储集的近岸水下扇和滩坝砂体;中期基准面旋回G层序沉积时期主要发育重力流主水道—重力流水道侧缘以及近岸水下扇沉积砂体;中期基准面旋回H层序沉积时期主要发育重力流主水道—重力流水道侧缘沉积体系。最后,预测了有利岩性圈闭发育的沉积相带和地区。     

氟离子对在河口区存在形态的理论研究

利用Davies离子强度校正方程,把在标准条件下获取的氟离子对的化学稳定数校正到35%的海水条件下,并应用逐步凑分法计算出F-离子对的几种存在形式:游离态F-占49.9%,MgF+占46.8%,其余为CaF+和NaF0.     

Advances and Practices on the Research,Prevention and Control of Land Subsidence in Coastal Cities

Land subsidence severely threatens most of the coastal plains around the world where high productive industrial and agricultural activities and urban centers are concentrated. Coastal subsidence damages infrastructures and exacerbates the effect of the sea-level rise at regional scale. Although it is a well-known process, there is still much more to be improved on the monitoring, mapping and modeling of ground movements, as well as the understanding of controlling mechanisms. The International Geoscience Programme recently approved an international project (IGCP 663) aiming to bring together worldwide researchers to share expertise on subsidence processes typically occurring in coastal areas and cities, including basic research, monitoring and observation, modelling and management. In this paper, we provide the research communities and potential stakeholders with the basic information to join the participating teams in developing this project. Specifically, major advances on coastal subsidence studies and information on well-known and new case studies of land subsidence in China, Italy, The Netherlands, Indonesia, Vietnam and Thailand are highlighted and summarized. Meanwhile, the networking, dissemination, annual meeting and field trip are briefly introduced.     

BOOK REVIEWS

Book Reviewed in this article: Introduction to Climatology for the Tropics . J. O. Ayoade. Conservation and Management of Natural Resources in the United States . Charles F. Bennett. The Keeping of Animals: Adaptation and Social Relations in Livestock Producing Communities . Riva Berleant-Schiller and Eugenia Shanklin, ed. The Evolution of Geographic Thought in America: A Kentucky Root Wilford A. Bladen and Pradyumna P. Karan, eds. Latin America: Geographical Perspectives , 2nd ed. Harold Blakemore and Clifford T. Smith, ed. The Rural Real Estate Market. Department of Geography Publication Series, No. 18 . Chris Bryant. Urban Geomorphology in Drylands . R. U. Cooke, D. Brunsden, J. C. Doornkamp, and D. K. C. Jones with contributions by J. Griffiths, P. Knott, R. Potter, and R. Russell. Italian Geography, 1960–1980. Meeting of the Status of the Geographic Research in Italy, 1960–1980. Treated under the auspices of Consiglio Nazionale delle Ricerche and organized by Istituto di Geografia Umana della Facoltà di Lettere e Filosofia dell'Università degli Studi di Milano , Giacomo Corna Pellecrini and Carlo Brusa, eds. The Changing Fenland . H. C. Darby. The Future for the City Centre . R. L. Davies and A. G. Champion, eds. Saudi Arabia, Energy, Developmental Planning, and Industrialization . Ragaei El Mallakh, Dorothea H. El Mallakh, eds. For We Are Sold, I and My People: Women and Industry in Mexico's Frontier . Maria Patricia Fernández-Kelly. The Great Lakes Forest: An Environmental and Social History . Susan L. Flader, ed. Regional Transformation and Industrial Revolution: A Geography of the Yorkshire Woolen Industry . Derek Gregory Crime in City Politics . Anne Heinz, Herbert Jacob and Robert L. Lineberry, eds. Revitalizing Cities . H. Briavel Holcomb and Robert A. Beauregard. Cartographic Relief Presentation . Eduard Imhof. H. J. Steward, Trans. Soviet Union: A Geographical Survey . S. V. Kalesnik and V. F. Pavlenko, ed. Cognition and Environment . Stephen Kaplan and Rachel Kaplan. Environmental Protection: The International Dimension . David A. Kay and Harold K. Jacobsen, eds. Mathematical Programming Methods for Geographers and Planners , James Killen. Gentrification Amid Urban Decline: Strategies for America's Older Cities . Michael H. Lang. The North Atlantic Sulphur System . Risto Laulajainen. The Jerusalem Cathedra: Studies in the History, Archaeology, Geography and Ethnography of the Land of Israel, Vol. 2 . Lee I. Levine ed. Jerusalem and Detroit: Recreation Planning and Management . Stanely R. Lieber and Daniel R. Fesenmaier, eds. Heartland and Hinterland: A Geography of Canada . L. D. McCann, ed. Scarborough Where We Live: The Residential Districts of Minneapolis and St. Paul . Judith A. Martin and David A. Lanegran. California: The Geography of Diversity . Crane S. Miller and Richard S. Hyslop. Palo Alto The Dilemma of Amazonian Development . Emilio F. Moran, ed. Boulder Nuclear Waste: Socioeconomic Dimensions of Long-Term Storage . Steve H. Murdock, F. Larry Leistritz, and Rita R. Hamm, eds. Boulder Communism and the Politics of Inequalities . Daniel N. Nelson, ed. The Los Angeles Metropolis . Howard J. Nelson. Dubuque An Historical Geography of Urban System Development: Tidewater Virginia in the 18th Century . James O'Mara. Procedures and Standards for a Multipurpose Cadastre . East Asia: Geographical and Historical Approaches to Foreign Area Studies . Clifton W. Pannell, ed. Dubuque Mackinder: Geography as an Aid to Statecraft . W. H. Parker. Beyond the Urban Fringe: Land Use Issues of Nonmetropolitan America . Rutherford H. Platt and George Macinko, eds. Recreation Geography of the USSR . V. S. Preobrazhensky and V. M. Krivosheyev, eds. Missouri: A Geography . Milton D. Rafferty The Invisible Farmers: Women in Agricultural Production . Carolyn E. Sachs. Cayman Islands Seashore Vegetation: A Study in Comparative Biogeography . Jonathan D. Sauer. Hillslope Materials and Processes . Michael J. Selby. Housing in Britain: The Post-War Experience . John R. Short The Study of Population: Elements, Patterns and Processes . George A. Schnell and Mark Stephen Monmonier. Columbus The Soviet Union: A Systematic Geography . Leslie Symons, ed. The Ottoman Slave Trade and Its Suppression . Ehud R. Toledano. The Impact of Recession on Industry, Employment and the Regions, 1976–1981 . Alan R. Townsend. Landslides and Their Control , 2nd ed. Quido Záruba and Vojtech Mencl. Translated from the Czech by H. Zárubová and V. Mencl.     

BOOK REVIEWS

Books Reviewed in this article: Lob Trees in the Wilderness . Clifford and Isabel Ahlgren . Satellite Microwave Remote Sensing . T. D. Allan , ed. Sunbelt Cities: Politics and Growth Since World War II . Richard M. Bernard and Bradley R. Rice , eds. Legacy of Minneapolis: Preservation Amid Change . John R. Borchert , David Gebhard , David Lanegran , and Judith A. Martin . Bloomington, MN: Preparing a Historic Preservation Ordinance. Richard J. Roddewig . The Mountains of Northeastern Tasmania, A Study of Alpine Geomorphology . Nel Caine . Introductory Cartography . John Campbell . Englewood Cliffs, NJ: Changing Climate . Manual of Remote Sensing, Second Edition . 2 Vols. Robert N. Colwell , ed.-in-chief; David S. Simonett and John E. Estes , vol. eds. Remote Sensing in Meteorology, Oceanography and Hydrology . A. P. Cracknell , ed. Multidimensional Scaling . Mark L. Davison . Environmental Karst . Percy H. Dougherty , ed. The Urban Environment . Ian Douglas . Geomorphology of Europe . Clifford Embleton , ed. An Introduction to South Asia . B. H. Farmer . Great Geological Controversies . A. Hallam . Hazardous Waste Management: In Whose Backyard? Michalann Harthill , ed. Energy for Subsistence . Margaret Haswell . Perspective on Ratzel's Political Geography . James M. Hunter . Economic Deposits and their Tectonic Setting . Charles S. Hutchison . Energy Risk Assessment . Herbert Inhaber . Discovering the Vernacular Landscape . John Brinckerhoff Jackson . Climate and Energy Systems: A Review of Their Interactions . Jill Jäger . Dilemmas in Regional Policy . Antoni Kuklinski and J. G. Lambooy , eds. California Farmland: A History of Large Agricultural Landholdings . Ellen Liebman . The Spatial Organization of New Land Settlement in Latin America . Jacob O. Maos . Dark Continent: Africa as Seen by Americans . Michael McCarthy . Westport, CT: Climatology: An Introduction . John E. Oliver and John J. Hidore . Columbus, OH: The Geography of Warfare . Patrick O'Sullivan and Jesse W. Miller . The Expanding City. Essays in Honour of Professor Jean Gottmann . John Patten , ed. Scotland's Environment During the Last 30,000 Years . Robert J. Price . Integrated Urban Models . S. H. Putman . Development and the Environmental Crisis: Red or Green Alternatives? Michael Redclift .     

BOOK REVIEWS

Books reviewed in this article: The Mexican Colonial Copper Industry. Elinore M. Barrett . The Control Revolution: Technological and Economic Origins of the Information Society . James R. Beniger . Land Degradation and Society . Piers M. Blaikie And Harold C. Brookfield , Eds . La carte, mode d'emploi. Roger Brunet . France: les dynamiques du territoire . Roger Brunet AND Jacques Sallois , EDS. At the Crossroads—The Mineral Problems of the United States . Eugene N. Cameron . A Census of One Billion People , Papers for International Seminar on China's 1982 Population Census. Li Chengrui , ED. Les Milieux “Naturels” du Globe . Jean Demangeot . The Geophysiology of Amazonia: Vegetation and Climate Interactions : Robert E. Dickinson , ED. Tenn-Tom Country . James F. Doster And David C. Weaver . Family Farming in Europe and America . Boguslaw Galeski And Eugene Wilkening , EDS. The Geography of Urban Transportation . Susan Hanson , Ed. Combating Desertification in Developing Countries . J. K. Jain , ED. Cartography in France—1660–1848. Science, Engineering and Statecraft . Josef W. Konvitz . Distribution of Distances in Pregeographical Space . Hans Kuiper . Physical Geography Lab Manual: A New Experimental Approach . Neal G. Lineback And John M. Harlin . Physical Geography: A Landscape Appreciation , 2nd ed. Tom L. Mc Knight . The Desert Is No Lady: Southwestern Landscapes in Women's Writing and Art . Vera Norwood And Janice Monk , EDS. France: A Geographical, Social, and Economic Survey . Philippe Pinchemel , translated, by D. Elkins and T. H. Elkins. Gene Banks and the World's Food . Donald L. Plucknett , Nigel J. H. Smith , J. T. Williams , And N. Murthi Anishetty . Latin American Development: Geographical Perspectives . David Preston , Ed. Making Sense of Development: An Introduction to Classical and Contemporary Theories of Development and Their Application to Southeast Asia . P. W. Preston . The History of the Countryside. Oliver Rackham . The Third World in Perspective . H. A. Reitsma AND J. M. G. Kleinpenning . The Industrial Geography of Australia . David C. Rich . The Recruiting Game , 2nd Ed., revised. John F. Rooney , JR. A Cultural Geography of North American Indians . Thomas E. Ross AND Tyrel G. Moore , EDS. Eastern Europe . Dean S. Rugg . Human Territoriality: Its Theory and History . Cambridge Studies in Historical Geography: 7. Robert David Sack . Experimental Fluvial Geomorphology . Stanley A. Schumm , M. Paul Mosley , AND William E. Weaver . The New Urban Landscape . David Schuyler . Atlas of American Women . Barbara Gimla Shortridge . Impacts of Hazardous Technology: The Psycho-Social Effects of Restarting TMI-1 . John Sorensen , Jon Soderstrom , Emily Copenhaver , Sam Carnes AND Robert Bolin . Modern Physical Geography , 3rd Ed., (Third Edition). Arthur N. Strahler AND Alan H. Strahler . India: Economic Resource Base and Contemporary Political Patterns . B. L. Sukhwal .     

BOOK REVIEWS

Book Reviewed in this article: Unfairly Structured Cities . Blair Badcock Religion and Rural Revolt . Janos M. Bak and Gerhard Benecke The Industrial Geography of Canada . Anthony Blackbourn and Robert G. Putnam The Cuban-American Experience, Culture, Images, and Perspectives. Thomas D. Boswell and James R. Curtis Quaternary Paleoclimatology . R. S. Bradley Development and Crisis in Brazil, 1930–1983 . Luiz Bresser Pereiras Centres of Origin in Biogeography . John C. Briggs Analytical Urban Geography . Martin Cadwallader Geomorphology . Richard J. Chorley , Stanley A. Schumm, and David E. Sugden South Africa: The Impact of Past Geographies . A. J. Christopher The Geography of Underdevelopment. A Critical Survey . D. K. Forbes Health Care in Developing Countries . Wilbert M. Gesler Place to Grow Old: The Meaning of Environment in Old Age . Stephen M. Golant The Emerging Marine Economy of the Pacific . Chennat Gopalakrishnan An Introduction to Agricultural Geography . David B. Grigg The Soviet Union: A Geographical Study . G. Melvyn Howe Geographical Aspects of Health: Essays in Honour of Andrew Learmonth . N. D. Mc Glashan and J. R. Blunden Physical Geography: A Landscape Appreciation . Tom L. Mc Knight Mountain Experience. The Psychology and Sociology of Adventure. Richard G. Mitchell Jr . Systematic and Regional Biogeography. Stanley A. Morain The Economic Transformation of American Cities. T. J. Noyelle and T. M. Stanback , Jr . Normal Accidents: Living With High-Risk Technologies. Charles Perrow Vanishing Farmland: A Legal Solution for the States. Sarah E. Redfield Applied Methods of Regional Analysis: The Spatial Dimensions of Development Policy. Dennis A. Rondinelli Urbanization in Romania. A Geography of Social and Economic Change Since Independence. Per Ronnas Statistical Techniques in Geographical Analysis. Gareth Shaw and Dennis Wheeler The Granite Garden: Urban Nature and Human Design. Anne Whiston Spirn Political Geography: Recent Advances and Future Directions. Peter Taylor and John House Geographia y Medio Ambiente. Manuel Valenzuela -Rubío Nãgara and Commandery: Origins of the Southeast Asian Urban Traditions. Paul Wheatley The Common Fisheries Policy of the European Community. Mark Wise Geography and Gender. Women and Geography Study Group of the IBG Technological Hazards. D. J. Zeigler , J. H. Johnson , S. D. Brunn     

Kinetics of the reactions of hydroxyl radicals with aliphatic ethers studied under simulated atmospheric conditions: Temperature dependences of the rate coefficients

Rate coefficients have been measured for the reactions of hydroxyl radicals with five aliphatic ethers over the temperature range 242–328 K. Competitive studies were carried out in an atmospheric flow reactor in which the hydroxyl radicals were generated by the photolysis of methyl nitrite in the presence of air containing nitric oxide. The reaction of OH with 2,3-dimethyl-butane was used as the reference reaction and the following Arrhenius parameters have been obtained for the reactions: OH+RORproducts:

城市自然地理学的理论、实践和发展

在全球快速城市化背景下,城市成为经济高速发展、人类活动高度集中、人地相互作用最强烈的区域,人工环境下“第二自然格局”的形成以及剧烈的城市土地利用/覆被变化效应使得城市自然地理学在城市复杂系统的研究中具有重要的理论和应用价值。本文通过对城市自然地理学的缘起、学科发展的综合分析,从学科理论体系、研究内容以及前沿发展领域等方面进行了论述,以期丰富和深化城市自然地理学研究内容,并进一步推动城市自然地理学的研究和发展。未来,城市自然地理学的研究应从以下方面开展：①关注基础理论研究,深化学科理论体系;②发展多学科的交叉视角,深化城市地表系统多要素变化研究;③聚焦城市自然—人文复杂系统,揭示自然和人文多要素间耦合机理及驱动机制;④拓宽城市服务应用领域的研究,提供城市可持续发展的多目标决策。