岩石化探样中微量铀 钍的XRFA法测定

本文提出以粉末样品直接压饼法测定岩石化探样品中的微量U,Th,其方法简便、快速,适用于各类地质样品,尤其是岩石化探样品测量。     

Geotechnical properties of a chemically stabilized soil from Malaysia with rice husk ash as an additive

Summary The stabilization of Malaysian soil by mixing with rice husk ash, a locally available waste material, to improve its engineering properties is described. Stabilizing agents, i.e. cement and lime, were added to produce the reaction products which are responsible for the enhancement of the engineering properties. Based on the strength development, it seems that lime is the more effective stabilizing agent. However, the cheap waste material can be used as partial replacement for the more expensive cement in the cement-treatment of the soil. A durability study was carried out to evaluate the effectiveness of this stabilization method.     

累托石的结晶度研究

本文用峰形分析法分析累托石的001X射线衍射峰特征;用001峰的半峰宽(W)测定累托石的结晶度(G),并令G=K/W=1为最大结晶度。文中测定了5个矿区10件累托石样品的结晶度,详细描述了不同结晶度累托石的X射线衍射、红外谱及差热曲线特征,讨论了研磨、热处理和改型对结晶度的影响,并阐明累托石的结晶度与造浆率之间呈正相关性。     

拜城县黑英山霞石正长岩矿物学特征研究

霞石正长岩是重要的炼铝资源和陶瓷、玻璃原料。文中利用扫描电镜、X衍射、红外线、电子探针等,综合分析方法对黑英山霞石正长岩的矿物学特征作了详细研究。着重描述了岩石的矿物组合、矿物生成及变化特征。对主要矿物进行了化学成分及X衍射分析,测得霞石成分:SiO_243.66％,Al_2O_330.97％,K_2O4.23％,Na_2O18.46％(Na_2O高于其它地区的霞石)。根据霞石单矿物实测成分计算出其晶体化学分子式为:(K_(0.525)Na_(3.528)Ca_(0.012))_(4.065)[Cr_(0.010)Al-(3.559)Mg_(0.009)Fe_(0.054)Mn_(0.012)Ti_(0.008)Si_(4.258)O_(16)];测得霞石的主要X衍射d值为:0.302～0.303,0.386～0.389,0.1388～0.1391(nm)。测得微斜长石的成分:SiO_264.82％,Al_2O_319.68％,K_2O11.77％,Na_2O2.30％,求得其三斜度△=0.83～1.00,属低微斜长石。通过霞石正长岩中钾长石与霞石矿物中对K原子分配值计算和作图,解得矿物生成温度为400～500℃。测得岩石中的钠长石主要为低钠长石,属后期交代矿物。     

用路径积分法求解电子的衍射态

本文用费曼的路径积分方法求解出自由电子经狭缝衍射后的量子态及在观察屏处的几率分布，所得结果与光子的夫琅和费衍射相同。     

High-temperature X-ray investigation of natural columbites

Structural investigations at high temperature were carried out on natural columbite samples across the join Fe(Nb_0.95Ta_0.05)₂O₆–Mn(Nb_0.95Ta_0.05)₂O₆. The samples were preliminarily annealed to attain the complete cation-ordered state and avoid the superimposition of the effects of cation ordering during high-temperature studies. Unit-cell parameters of three columbites with different X_Fe content were measured at regular intervals in the temperature range 25–900 °C using single-crystal X-ray diffraction techniques. The crystal structures of completely ordered ferrocolumbite and manganocolumbite were also refined from intensity data collected at room temperature, 300 and 600 °C. Structural thermal expansion coefficients show positive, linear expansion of a, b, c lattice constants and cell volume. In general, slightly higher expansion occurs along a and c directions. However, anisotropy decreases sharply with decreasing Fe content. Reversibility of thermal expansion in the investigated temperature range was checked by high-temperature diffraction studies under heating-up and cooling-down conditions. Impurities do not play an important role in thermal expansion of columbites; expansion coefficients measured on two crystals of the same sample characterized by different Ti content are in fact almost identical. Structural changes with temperature essentially affect bond lengths: volumes of both A and B octahedral sites increase linearly with temperature, whereas interpolyhedral geometrical parameters do not vary significantly.     

X射线荧光光谱分析检出限问题的探讨与建议

对有关X射线荧光光谱分析低含量元素的检出限问题进行了多方面的探讨。从检出限的定义及其定义下的相对标准偏差到各种不同测量、校准与校正方法的检出限及其相对应的相对标准偏差进行计算。提出了以定义检出限的相对标准偏差为基准,对各种测量方法计算出的检出限进行重新界定,从而确认一个具有可比性的、精度一致的检出限。同时还讨论了仪器与X光管固有杂质元素谱线对该元素检出限的影响;测量仪器、测量条件与测量时间对检出限的影响;不同岩性试样对检出限的影响;检出限与测定限等问题。     

X-Ray Interferometry

For the astronomer, X-ray interferometry is the theory and practice of building dilute aperture telescopes for studying celestial X-ray sources. The short wavelengths and high surface brightness of X-ray sources will make the eventual scientific payoff very high, with direct imaging of the event horizons of black holes as the centerpiece. In this article, we review the history of X-ray interferometry and discuss the recent technical developments toward astronomical applications. We present several mission concepts and show they are achievable with todays technology.