地理环境因子对肌酸激酶同工酶参考值的影响

研究目的旨在探讨三种常用的变量筛选回归方法对中国健康成年人肌酸激酶同工酶（CK-MB）参考值在地理空间上的分布规律特征,应用于制定不同地区CK-MB参考值标准,为临床医学研究做出贡献。方法通过阅读大量文献搜集全国137个市县级单位共8697例健康成年人CK-MB参考值,并选择了地理位置、气候、土壤三大类共24项地理因子。使用相关分析方法检验CK-MB参考值和地理因子之间的显著性,提取到9项相关性地理因子。基于R语言评估模型多重共线性的严重程度,建立CK-MB参考值岭回归（Ridge）模型、拉索回归（Lasso）模型、主成分分析模型。对比得到最优预测模型,拟合全国2322个市县级单位健康成年人CK-MB预测参考值,再结合地统计分析,运用析取克里金法进行趋势分析,得到CK-MB预测参考值地理分布规律特征。结果表明全国2322个市县级单位的健康成年人CK-MB参考值具有空间自相关性,模型测试表明,主成分分析法具有更好的模拟和预测能力。研究表明健康成年人CK-MB参考值分别与纬度、年日照时数、年平均相对湿度、年降水量、气温年较差、年平均气温、表土石砾含量、表土（粘土）阳离子交换量、表土（粉土）阳离子交换量具有显著的相关性。由地理空间分布图显示,整体上呈北高南低,从东南沿海向西北内陆逐渐升高的趋势。通过搜集到的任一地区地理因子,结合主成分分析预测模型或已得的地理分布图可确定该地区健康人CK-MB参考值范围,为在临床诊断中考虑地域差异提供参考。     

Experimental study on weathering of seafloor volcanic glass by bacteria (Pseudomonas fluorescens) – Implications for the contribution of bacteria to the water–rock reaction at the Mid-Oceanic Ridge setting

The biologically mediated weathering of the ocean crust has received increasing attention in recent decades, but the rates and the possible mechanism of elemental release during microbe–basalt interactions occurring below the seafloor have not been studied in detail. In this study, we established an experimental weathering study of seafloor natural basaltic glass comparing the effect of microbial activity (Pseudomonas fluorescens) in P-rich and P-poor media with parallel controls containing either nonviable cells or organic acid. The changes in the chemical parameters, including pH, bacterial densities, and ion concentrations (Ca, Mg, Si, Mn, Al, Fe, and P) in the solution, were examined during the different batch experiments. The results showed that the pH decreased from 7.0 to 3.5 and the bacterial density increased from 10⁵ to 10⁸ cells/ml during the first 120 h, and the cell numbers remained constant at 10⁸ cells/ml and the pH increased from 3.5 to 6 between 120 h and 864 h in the P-bearing reactors containing bacteria. In contrast, during all the experimental time, the pH remained close to neutral condition in the abiotic control systems and the dissolution rates increased markedly with a decrease in pH and became minimal at near-neutral pH in P-bearing reactors containing bacteria, where Ca, Si, and Mg release rates were 2- to 4-fold higher than those obtained in chemical systems and biotic P-limited systems. Furthermore, the surfaces of the natural volcanic glass from the biotic systems were colonized by bacteria. Simultaneously, the etch pits were observed by Scanning Electron Microscope, which further indicate that the bacteria may promote the mineral dissolution for energy gain. Some elements (e.g., Fe, Mn, and Al) releasing from natural volcanic glass are likely an important source of the elemental budget in the ocean, and thus the element release and its possible mechanism conducted in this experimental study have potential implications on the biogeochemical cycling process in the Mid-Oceanic Ridge setting.     

Geophysical signatures over and around the northern segment of the 85°E Ridge,Mahanadi offshore,Eastern Continental Margin of India: Tectonic implications

The nature and origin of the subsurface 85°E Ridge in the Bay of Bengal has remained enigmatic till date despite several theories proposed by earlier researchers. We reinterpreted the recently acquired high quality multichannel seismic reflection data over the northern segment of the ridge that traverses through the Mahanadi offshore, Eastern Continental Margin of India and mapped the ridge boundary and its northward continuity. The ridge is characterized by complex topography, multilayer composition, intrusive bodies and discrete nature of underlying crust. The ridge is associated with large amplitude negative magnetic and gravity anomalies. The negative gravity response across the ridge is probably due to emplacement of relatively low density material as well as ∼2–3 km flexure of the Moho. The observed broad shelf margin basin gravity anomaly in the northern Mahanadi offshore is due to the amalgamation of the 85°E Ridge material with that of continental and oceanic crust. The negative magnetic anomaly signature over the ridge indicates its evolution in the southern hemisphere when the Earth’s magnetic field was normally polarized. The presence of ∼5 s TWT thick sediments over the acoustic basement west of the ridge indicates that the underlying crust is relatively old, Early Cretaceous age.The present study indicates that the probable palaeo-location of Elan Bank is not between the Krishna–Godavari and Mahanadi offshores, but north of Mahanadi. Further, the study suggests that the northern segment of the 85°E Ridge may have emplaced along a pseudo fault during the Mid Cretaceous due to Kerguelen mantle plume activity. The shallow basement east of the ridge may have formed due to the later movement of the microcontinents Elan Bank and Southern Kerguelen Plateau along with the Antarctica plate.     

自贡西山公园山脊场地地形和土层效应数值模拟

利用自贡地形影响强震动观测台阵在汶川地震中获得的强震动记录,以位于山脚下基岩上的台站为参考点,采用传统谱比法对场地放大效应进行了初步分析;同时用显式有限元-有限差分方法模拟了自贡西山公园山脊场地地形和土层的地震动效应,并进行了数值模拟结果与强震动观测结果的对比分析.结果表明:上覆土层对地震动的放大作用相对于地形变化的放大作用更为明显;地形对地震动水平分量的放大效应要明显于对竖直分量的放大效应;采用二维模型对上覆土层的模拟与观测结果较吻合,对于基岩介质部分的模拟在低频范围内也能反映山脊地形对地震动的影响.     

Formation of Fe-Mn-Si oxide and nontronite deposits in hydrothermal fields on the Valu Fa Ridge, Lau Basin

Hydrothermal Fe-Mn-Si oxides and nontronite are pervasive in the Hine Hina, Vai Lili and Mariner hydrothermal fields along the central Valu Fa Ridge, Lau Basin. Morphometric and mineralogical analyses reveal that the iron-rich filaments are the most important constituents of these Fe-Mn-Si oxide deposits. Both the morphologies and chemical composition of the filaments indicate that neutrophilic Fe-oxidizing bacteria have played a key role in the formation of these deposits. A key process of the formation of these deposits is the creation of a complicated filamentous network in which a series of metabolic activities and passive sorption and nucleation processes occur. The precipitation of dissolved Si in unsaturated and saturated states leads to a “two-generation” growth model in the hydrothermal vents. The precipitation of amorphous opal occurs in a relatively narrow temperature range (41.1-42.9 °C) based on oxygen isotope analyses, indicating a fast precipitation rate of opal-A when conductive cooling of the hydrothermal fluid occurrs. Patchy nontronite in the Mariner fields is a product of the direct precipitation from hydrothermal fluids at a temperature of ∼87.9 °C, whereas the scattered nontronite at the Hine Hina field is the product of the replacement of hydrothermal Fe-Si oxides at a temperature of ∼46.2 °C.     

Geochemistry of basaltic lavas from the southern Lau Basin: input of compositionally variable subduction components

We present new major element, trace element, and Sr–Nd–Pb isotope data for 18 basaltic lavas and six glasses collected in situ from the Eastern Lau Spreading Centre (ELSC) and the Valu Fa Ridge (VFR). All lava samples are aphanitic and contain rare plagioclase and clinopyroxene microlites and microphenocrysts. The rocks are sub-alkaline and range from basalt and basaltic andesite to more differentiated andesite. In terms of trace element compositions, the samples are transitional between typical normal mid-ocean ridge basalt (MORB) and island arc basalt. Samples from the VFR have higher large ion lithophile element/high field strength element ratios (e.g. Ba/Nb) than the ELSC samples. VFR and ELSC Sr–Nd isotopic compositions plot between Indian MORB and Tonga arc lavas, but VFR samples have higher ⁸⁷Sr/⁸⁶Sr for a given ¹⁴³Nd/¹⁴⁴Nd ratio than ELSC analogues. The Pb isotopic composition of ELSC lavas is more Indian MORB-like, whereas that of VFR lavas is more Pacific MORB-like. Our new data, combined with literature data for the Central Lau Spreading Centre, indicate that the mantle beneath the ELSC and VFR spreading centres was originally of Pacific type in composition, but was displaced by Indian-type mantle as rifting propagated to the south. The mantle beneath the spreading centres also was variably affected by subduction-induced metasomatism, mainly by fluids released from the altered, subducting oceanic crust; the influence of these components is best seen in VFR lavas. To a first approximation, the effects of underflow on the composition and degree of partial melting of the mantle source of Lau spreading centre lavas inversely correlate with distance of the spreading centres from the Tonga arc. Superimposed on this general process, however, are the effects of the local geographic contrasts in the composition of subduction components. The latter have been transferred mainly by dehydration-generated fluids into the mantle beneath the Tonga supra-subduction zone.     

U–Pb detrital zircon evidence of transcontinental sediment dispersal: provenance of Late Mississippian Wedington Sandstone member,NW Arkansas

ABSTRACT

U–Pb ages of detrital zircons from the Wedington Sandstone member in northwest Arkansas provide evidence for Late Mississippian westward transcontinental sediment transport from the Appalachian foreland. The Late Mississippian Wedington Sandstone member of the Fayetteville Shale is a fine- to medium-grained quartzarenite. It separates the Fayetteville Shale into informal lower and upper intervals, and was deposited as a small constructive delta complex that prograded towards the south and southeast during the Late Mississippian. As a major influx of clastic sediments, the Wedington Sandstone member records the sediment source and dispersal in the mid-continent during the Late Mississippian. A total of 559 detrital zircon grains from six Wedington samples were recovered for U–Pb detrital zircon geochronological analysis. Results show that age distributions can be subdivided into six groups: ~350–500, ~900–1350, ~1360–1500, ~1600–1800, ~1800–2300, and > ~2500 Ma, and are characterized by a prominent peak for the age group of ~900–1350 Ma, a major peak at ~1600–1800 Ma, and a few other minor age clusters. Regional correlation and geological evidence from surrounding areas suggest that the transcontinental sediment dispersal started as early as the Late Mississippian. U–Pb detrital zircon age distribution suggests that the Wedington Sandstone member was likely derived from the Appalachian foreland with contributions from the Nemaha Ridge to the west where the Yavapai–Mazatzal sources were exposed during the Late Mississippian. Sediment was likely transported westward through or around the Illinois Basin, merged with mid-continent sediment, and then entered into its current location in northwest Arkansas. Transportation of this sediment from mixed sources continued along its course to the south, forming a delta on the Northern Arkansas Structural Platform.     

Fault systems and paleostresses in the Vestfirdir Peninsula. Relationships with the Tertiary paleo-rifts of Skagi and Snaefells (Northwest Iceland)

Abstract

The Vestfirdir Peninsula of northwestern Iceland mainly consists of tholeiitic lava flows, 8–14 Ma old, gently dipping to the southeast. A detailed study of strike-slip and normal faulting allowed identification of two main paleostress regimes. Two sets of normal faults were recognized. The largest set trends ENE-WSW to NNE-SSW; the minor set trends NW-SE to WNW-ESE. Concerning the major extension, the reconstruction of paleostress trajectories shows a gradual change in trend from ESE-WNW, in the northern half of the peninsula, to NNW-SSE to the south. The minor extension also shows a gradual change from NNE-SSW to ENE-WSW trends, from north to south. The nearly constant perpendicularity between the major and minor trends of extension is accounted for by permutation of stress axes within the general pattern of extension related to oceanic rifting. The progressive azimuthal change of the major extension trend, from northeast to southwest across the peninsula, is interpreted as the expression of a change in trend of the extinct Skagi-Snaefells rift, a structure that cannot be reconstructed directly through geological mapping. The average trends of extension in the southern Vestfirdir Peninsula, N150°E, suggest a N60°E trend for the ancient Snaefells rift segment. Likewise, the N100–110°E trends of extension in northern Vestfirdir suggest a N10–20°E trend for the Skagi paleo-rift., © Elsevier, Paris     

The occurrence of gold in hydrothermal sulfide at Southwest Indian Ridge 49.6°E

Massive sulfide precipitates found in the Southwest Indian Ridge(SWIR) 49.6°E hydrothermal field are enriched in gold.Here,the mineralogy and mineral chemistry of these massive sulfides to constrain the process of gold precipitation were studied.Sulfide samples in this field include lowertemperature Zn-rich sulfides and relative higher-temperature Fe-rich sulfides.Zn-rich sulfides are dominated by sphalerite-pyrite-chalcopyrite assemblages,with concentrations of gold ranging from 9.08 to 17.0 μg/g.Fe-rich sulfides consist mainly of pyrite-marcasite-isocubanite assemblages,with gold concentrations from 2.17 to 3.79 μg/g.The significant enrichment in gold within the lowertemperature Zn-rich sulfides and the effective separation of Zn and Fe in hydrothermal precipitates at the surface of this field are here interpreted to reflect the strong temperature dependence of gold transportation and deposition within the sulfides.In Zn-rich samples,large amounts of isolated native gold grains were identified.They were found mainly as inclusions up to 8 μm in diameter,occupying porous cavities in sphalerite or in the elevated iron content rim of sphalerite.The fineness of the gold ranged from 810 to 830.Unlike previously published results on other hydrothermal fields,these data show a low gold fineness values in SWIR 49.6°E.The FeS content of sphalerite associated with gold grains ranged from 3.2 mole % to 18.9 mole %.This was higher than in other fields,indicating that the sulfur activity is relatively low during the gold precipitation process and that sulfur activity may be one of the main factors affecting gold fineness in the SWIR 49.6°E hydrothermal field.Evidence regarding gold fineness and sulfur activity suggests that gold was quite likely transported as AuHS0 rather than as a Au(HS)-2 complex.