重庆经济区划及分区发展问题研究

文章通过对重庆经济区划的分析评价,提出经济区划的原则及标准,对重庆经济区划体系提出了新观点,并对经济区发展问题提出了自己的看法。     

基于循环经济的企业发展与布局问题探讨

该文探讨循环经济对企业布局指向的影响,即原料指向削弱、集聚经济指向转为集聚循环经 济指向和布局指向不明企业增多的趋势减弱.认为实现规模循环经济效益是公司增长的重要 动因之一,横向一体化、闭环一体化和基于产业生态联系的多样化是基于循环经济的公司增 长战略与方法;重污染企业不仅可以进入生态工业园区,而且是目前中国生态工业园区产业 选择的重点之一.分析基于循环经济的公司空间结构,并探讨3种类型生态工业园在中国的 具体应用,认为近期应以逐步推广现有改造型生态工业园和虚拟型生态工业园为主,辅以全新型生态工业园,尤其要重视3种类型生态工业园的结合.     

Hydrochemical status of groundwater in district Ajmer (NW India) with reference to fluoride distribution

High fluoride in groundwater has been reported from many parts of India. However, a systematic study is required to understand the behaviour of fluoride in natural water in terms of local hydrogeological setting, climatic conditions and agricultural practices. Present study is an attempt to assess hydrogeochemistry of groundwater in Ajmer district in Rajasthan to understand the fluoride abundance in groundwater and to deduce the chemical parameters responsible for the dissolution activity of fluoride. Ajmer district falls in the semi-arid tract of central Rajasthan and is geologically occupied by Precambrian rocks (granites, pegmatites, gneisses, schists etc) where groundwater occurs under unconfined condition. A total of 153 well-water samples, representing an area of 8481 km² (further subdivided into eight blocks), were collected and chemically analyzed. The results of chemical analyses (pre-monsoon 2004) show fluoride abundance in the range of 0.12 to 16.9 mg/l with 66% of the samples in excess of permissible limit of 1.5 mg/l. Presence of fluoride bearing minerals in the host rock, the chemical properties like decomposition, dissociation and dissolution and their interaction with water is considered to be the main cause for fluoride in groundwater. Chemical weathering under arid to semi-arid conditions with relatively high alkalinity favours high concentration of fluoride in groundwater. Dental and skeletal fluorosis are prevalent in the study area which can be related to the usage of high fluoride groundwater for drinking. The suggested remedial measures to reduce fluoride pollution in groundwater include dilution by blending, artificial recharge, efficient irrigation practices and well construction.     

Late Cretaceous porphyry Cu and epithermal Cu–Au association in the Southern Panagyurishte District,Bulgaria: the paired Vlaykov Vruh and Elshitsa deposits

Vlaykov Vruh–Elshitsa represents the best example of paired porphyry Cu and epithermal Cu–Au deposits within the Late Cretaceous Apuseni–Banat–Timok–Srednogorie magmatic and metallogenic belt of Eastern Europe. The two deposits are part of the NW trending Panagyurishte magmato-tectonic corridor of central Bulgaria. The deposits were formed along the SW flank of the Elshitsa volcano-intrusive complex and are spatially associated with N110-120-trending hypabyssal and subvolcanic bodies of granodioritic composition. At Elshitsa, more than ten lenticular to columnar massive ore bodies are discordant with respect to the host rock and are structurally controlled. A particular feature of the mineralization is the overprinting of an early stage high-sulfidation mineral assemblage (pyrite ± enargite ± covellite ± goldfieldite) by an intermediate-sulfidation paragenesis with a characteristic Cu–Bi–Te–Pb–Zn signature forming the main economic parts of the ore bodies. The two stages of mineralization produced two compositionally different types of ores—massive pyrite and copper–pyrite bodies. Vlaykov Vruh shares features with typical porphyry Cu systems. Their common geological and structural setting, ore-forming processes, and paragenesis, as well as the observed alteration and geochemical lateral and vertical zonation, allow us to interpret the Elshitsa and Vlaykov Vruh deposits as the deep part of a high-sulfidation epithermal system and its spatially and genetically related porphyry Cu counterpart, respectively. The magmatic–hydrothermal system at Vlaykov Vruh–Elshitsa produced much smaller deposits than similar complexes in the northern part of the Panagyurishte district (Chelopech, Elatsite, Assarel). Magma chemistry and isotopic signature are some of the main differences between the northern and southern parts of the district. Major and trace element geochemistry of the Elshitsa magmatic complex are indicative for the medium- to high-K calc-alkaline character of the magmas. ⁸⁷Sr/⁸⁶Sr_(i) ratios of igneous rocks in the range of 0.70464 to 0.70612 and ¹⁴³Nd/¹⁴⁴Nd_(i) ratios in the range of 0.51241 to 0.51255 indicate mixed crustal–mantle components of the magmas dominated by mantellic signatures. The epsilon Hf composition of magmatic zircons (+6.2 to +9.6) also suggests mixed mantellic–crustal sources of the magmas. However, Pb isotopic signatures of whole rocks (²⁰⁶Pb/²⁰⁴Pb = 18.13–18.64, ²⁰⁷Pb/²⁰⁴Pb = 15.58–15.64, and ²⁰⁸Pb/²⁰⁴Pb = 37.69–38.56) along with common inheritance component detected in magmatic zircons also imply assimilation processes of pre-Variscan and Variscan basement at various scales. U–Pb zircon and rutile dating allowed determination of the timing of porphyry ore formation at Vlaykov Vruh (85.6 ± 0.9 Ma), which immediately followed the crystallization of the subvolcanic dacitic bodies at Elshitsa (86.11 ± 0.23 Ma) and the Elshitsa granite (86.62 ± 0.02 Ma). Strontium isotope analyses of hydrothermal sulfates and carbonates (⁸⁷Sr/⁸⁶Sr = 0.70581–0.70729) suggest large-scale interaction between mineralizing fluids and basement lithologies at Elshitsa–Vlaykov Vruh. Lead isotope compositions of hydrothermal sulfides (²⁰⁶Pb/²⁰⁴Pb = 18.432–18.534, ²⁰⁷Pb/²⁰⁴Pb = 15.608–15.647, and ²⁰⁸Pb/²⁰⁴Pb = 37.497–38.630) allow attribution of ore-formation in the porphyry and epithermal deposits in the Southern Panagyurishte district to a single metallogenic event with a common source of metals.     

长江中下游成矿带铜陵矿集区铜多金属矿床模型

通过对长江中下游成矿带的系统考察和对前人资料的阅读和研究,聚焦铜陵矿集区,初步提出了一个可以涵盖不同类型矿床的矿床模型.该模型表达为:在早白垩世高钾钙碱性花岗岩侵位过程中,通过岩浆的分馏演化,在岩体隆起部位及其内外接触带形成斑岩-矽卡岩型矿床,由于广泛发育石炭纪至三叠纪碳酸盐岩.钙质和镁质矽卡岩型矿床是最主要的矿床类型.作为斑岩-矽卡岩型矿床系统的一部分,在斑岩-矽卡岩铜金钼矿床外围分布有矽卡岩铜金矿床、脉状金矿床以及脉状铅锌银矿床.长江中下游地区在三叠纪曾作为大别-苏鲁造山带的前陆盆地,在后碰撞时期出现了大量滑覆构造和扩容空间,它们在不整合界面处十分发育.因此,在成矿过程中不仅形成了像新桥那样的厚大矿体,而且在位于不整合界面附近的矽卡岩往往退化蚀变成为具有典型层纹状和曲卷状构造的退化蚀变岩和矿石,甚至沿一些层位交代形成了层控矽卡岩型或Manto型矿体.此外,还提出了运用该模型开展勘查评价的建议.     

都龙锡锌多金属矿田万龙山矿区矽卡岩矿物特征及成因意义

万龙山锌锡矿床是都龙锡矿田的一个重要矿区。通过矽卡岩岩石化学研究,认为矿区矽卡岩属于钙矽卡岩,在w(SiO_2)—w(CaO)图解中,矿区矽卡岩与花岗岩、大理岩投点区呈线性展布,表明三者之间具有成因联系。对矿区主要的矽卡岩矿物石榴子石、辉石、角闪石、绿帘石和绿泥石进行了电子探针成分分析:石榴子石属于钙铝榴石-钙铁榴石系列,端元组分以钙铝榴石为主(体积分数51.02%～82.63%),钙铁榴石体积分数为12.45%～47.74%;辉石为透辉石-钙铁辉石系列,端元组分以钙铁辉石为主,明显缺乏透辉石;角闪石属于Mg-Fe-Mn-Li组,主要为镁角闪石;绿帘石中Fe的含量较;绿泥石主要为铁镁绿泥石,部分为铁斜绿泥石、密绿泥石或铁绿泥石,显示富镁铁质的特点。依据矽卡岩矿物的组分特征对矿区矽卡岩的成因、成矿条件及矿床成因等进行了讨论,认为矿区矽卡岩及金属矿化主要与晚白垩世老君山花岗岩具有成因关系,锡锌多金属矿床属于岩浆热液渗透交代型矿床。     

长江下游宁镇地区晚中生代侵入岩：同位素年龄、地球化学特征与成因探讨

发育于长江中下游构造-岩浆-成矿带最东端宁镇地区的晚中生代中酸性-酸性侵入岩以富钠、高Sr和Ba、富集轻稀土元素,强烈亏损重稀土元素为特征,高场强元素Ti、Nb、Ta等表现出显著的负异常,岩石地球化学的总体特征类似于高Sr/Y的埃达克岩。但与长江中下游其他地区的高Sr/Y岩浆岩相比,宁镇地区的这些侵入岩体还表现出低的放射性成因Pb、更低的重稀土元素含量、相对高的MgO、Cr和Ni含量及Mg#值等特征,推测它们的形成过程是由(再)富集的上地幔物质部分熔融形成的岩浆与古老的大陆下地壳物质部分熔融形成的埃达克质岩浆混合,混合岩浆在演化过程中还经历过较强的矿物分离结晶作用以及一定程度的上地壳物质混染。该再富集事件的发生可能与俯冲的古太平洋板块部分熔融所析出的熔体(或流体)交代上覆的地幔楔有关,导致原已富集的陆下岩石圈地幔更进一步富集挥发分以及不相容元素,古老的富集地幔中所累积的放射性成因Sr、Nd同位素被"中和",该作用在长江中下游地区可能仅影响到最东段的宁镇地区,并没有波及到更靠内陆的其他地区。宁镇地区的这些埃达克岩侵位于100~108Ma的早白垩世末期,晚于长江中下游其他地区高Sr/Y岩体长达30Ma左右,其间存在着较长时间的岩浆活动静止期,意味着它们可能形成于不同的动力学背景。后者的形成可能与区内印支期—早燕山期陆内挤压造山后的应力松池,加厚的大陆下地壳及其富集的岩石圈地幔发生拆沉和部分熔融有关,这种发生在长江中下游广大地区的岩石圈减薄事件可能并没有波及到最东段的宁镇地区。而前者可能与早白垩世末期—晚白垩世初期,太平洋板块相对亚洲大陆板块运动方向发生了改变,中国东部大陆边缘进入拉张-裂解的构造环境有关,但其效应在长江中下游地区可能主要影响到了最东段的宁镇地区,其他地区对这次构造变动并没有产生明显的岩浆活动。     

Zircon and titanite U-Pb dating of the Zhangjiawa iron skarn deposit,Luxi district,North China Craton: Implications for a craton-wide iron skarn mineralization

The North China craton hosts numerous iron skarn deposits containing more than 2600 Mt of iron ores, mostly with an average grade of >45 wt% Fe, which have been among the most important source of high-grade iron ores for the last three decades in China. These deposits typically form clusters and can be roughly divided into the western and eastern belts, which are located in the middle of Trans-North China orogen and to the west of the Tan-Lu fault zone in the eastern part of North China craton, respectively. The western belt mainly consists of the southern Taihang district, as well as the Linfen and Taiyuan ore fields, whereas the eastern belt comprises the Luxi and Xu-Huai districts. The Zhangjiawa deposit in the Luxi district has proven reserves of 290 Mt at an average of 46% Fe (up to >65%). The iron mineralization occurs mainly along contact zones between the Kuangshan dioritic intrusion and middle Ordovician marine carbonate rocks that host numerous evaporite intercalations. Titanite grains from the mineralized skarn are closely intergrown with magnetite and retrograde skarn minerals including chlorite, phlogopite and minor epidote, indicating a hydrothermal origin. The titanite grains have extremely low REE contents and low Th/U ratios, consistent with their precipitation directly from hydrothermal fluids responsible for the iron mineralization. Ten hydrothermal titanite grains yield a weighted mean ²⁰⁶Pb/²³⁸U age of 131.0 ± 3.9 Ma (MSWD = 0.1, 1σ), which is in excellent agreement with a zircon U-Pb age (130 ± 1 Ma) of the ore-related diorite. This age consistency confirms that the iron skarn mineralization is temporally and likely genetically related to the Kuangshan intrusion. Results from this study, when combined with existing isotopic age data, suggest that iron skarn mineralization and associated magmatism throughout both the eastern and western belts took place coevally between 135 and 125 Ma, with a peak at ca. 130 Ma. As such, those deposits may represent the world's only major Phanerozoic iron skarn concentration hosted in Precambrian cratons. The magmatism and associated iron skarn mineralization coincide temporally with the culmination of lithospheric thinning and destruction of the North China craton, implying a causal link between the two.     

陕西省泾惠渠灌区地下水污染与人体健康风险评价

为了研究陕西省泾惠渠灌区地下水污染特征及人体健康风险状况,采集地下水样品进行分析测定,首先运用单因子指数法进行污染评价,再利用GIS获取主要污染物As、Cr （Ⅵ）和NO₃^--N的空间分布特征,最后借鉴美国环境保护署的人体健康风险评价模型对灌区地下水污染物的人体健康风险做出评价。结果表明：研究区地下水中As、Cr （Ⅵ）、NO₃^--N的质量浓度均超标,As对成人的致癌风险最高达3.50×10^-4,明显超出限值1.00×10^-4,长期暴露对当地居民带来罹患癌症的健康风险较高;As、Cr （Ⅵ）、NO₃^--N的非致癌风险从大到小排序为Cr （Ⅵ）、NO₃^--N、As,其中Cr （Ⅵ）对儿童的非致癌风险最高,达8.693 7,远超限值1.000 0,危害性最大。空间分布特征方面,As的致癌风险区域面积比例最高,为42.82%,As、Cr （Ⅵ）、NO₃^--N的非致癌风险区域面积比例分别高达69.19%、69.06%和66.55%,水安全问题突出。     

粤东新寮岽铜多金属矿区钻孔深部矿体铜同位素研究

新寮岽铜多金属矿床是近年来粤东地区新发现的铜多金属矿床之一,矿区位于东南沿海锡、钨、铜等重要矿产发育地区,成矿地质条件非常好。本文通过对矿体中黄铜矿的铜同位素研究表明,其δ~(65)Cu值(-0.34‰~+1.37‰)与斑岩型矿床的δ~(65)Cu值基本一致,成矿物质Cu主要来源于深部岩浆,成矿流体显示为中高温(250~420℃)岩浆热液特征,Cu的分馏与岩浆热液活动关系密切,矿体的形成与成矿流体出溶有关。铜同位素组成随深度增加有增高趋势,能形成规模矿体。同时,铜同位素可以直接指示热源的位置,在热液流体石英脉出现的区域,铜矿体δ~(65)Cu值都低于0,在热液接触带、特殊的赋矿围岩和构造作用部位铜同位素值较高,预示着主矿体的边缘或前锋,是最为明显的找矿标志。