Correlation between magnetic susceptibility and heavy metals in urban topsoil: a case study from the city of Xuzhou, China

Anthropogenic influence, mainly due to urban and industrial activities and traffic exhaust, may affect urban topsoil via atmospheric contamination and solid waste. Magnetic susceptibility measurements were conducted on 21 urban topsoil samples from the city of Xuzhou, China. High intensities of magnetic susceptibility were detected in the majority of the samples. SEM analysis shows that magnetic minerals are in the form of spherules and mainly due to anthropogenic inputs. The heavy metals Pb, Cu, Zn, Se, Sc, Mo, Fe, and Bi show strong correlations with magnetic susceptibility, and Ag, Ba, Cd, Ni, Cr, Sb, and Sn, on the other hand, show a weak correlation with magnetic susceptibility. Whereas, of these metals studied, only Hg has no significant correlation with the susceptibility. The Tomlinson pollution load index (PLI) also shows significant correlation with the susceptibility (χ). The present study shows that magnetic susceptibility is a fast, inexpensive, and non-destructive method for the detection and mapping of contaminated soils.     

基于可持续发展的广东省城市供水价格改革探讨

针对目前城市供水价格计算与计量方式不合理和突出的水资源供需矛盾,提出了按全成本水价模式测算广东省城市供水价格,并采用阶梯水价、两部制水价和季节水价计量方式逐步达到全成本水价的措施与实施步骤,确保水资源的持续利用支撑广东省经济社会的可持续发展.     

Pixel‐oriented land use classification in energy balance modelling

Mass and energy transfer between soil, vegetation and atmosphere is the process that allows to maintain an adequate energy and water balance in the earth–atmosphere system. However, the evaluation of the energy balance components, such as the net radiation and the sensible and latent heat fluxes, is characterized by significant uncertainties related to both the dynamic nature of heat transfer processes and surfaces heterogeneity. Therefore, a detailed land use classification and an accurate evaluation of vegetation spatial distribution are required for an accurate estimation of these variables. For this purpose, in the present article, a pixel‐oriented supervised classification was applied to obtain land use maps of the Basilicata region in Southern Italy by processing three Landsat TM and ETM+ satellite images. An accuracy analysis based on the overall accuracy index and the agreement Khat of Cohen coefficient showed a good performance of the applied classification methodology and a good quality of the obtained maps. Subsequently, these maps were used in the application of a simplified two‐source energy balance model for estimating the actual evapotranspiration at a regional scale. The comparison between the simulations made by applying the simplified two‐source energy balance model and the measurements of evapotranspiration at a lysimetric station located in the study area showed the applicability and the validity of the proposed methodology. Copyright © 2012 John Wiley & Sons, Ltd.     

Prediction of river water temperature: a comparison between a new family of hybrid models and statistical approaches

River water temperature is a key physical variable controlling several chemical, biological and ecological processes. Its reliable prediction is a main issue in many environmental applications, which however is hampered by data scarcity, when using data‐demanding deterministic models, and modelling limitations, when using simpler statistical models. In this work we test a suite of models belonging to air2stream family, which are characterized by a hybrid formulation that combines a physical derivation of the key equation with a stochastic calibration of parameters. The air2stream models rely solely on air temperature and streamflow, and are of similar complexity as standard statistical models. The performances of the different versions of air2stream in predicting river water temperature are compared with those of the most common statistical models typically used in the literature. To this aim, a dataset of 38 Swiss rivers is used, which includes rivers classified into four different categories according to their hydrological characteristics: low‐land natural rivers, lake outlets, snow‐fed rivers and regulated rivers. The results of the analysis provide practical indications regarding the type of model that is most suitable to simulate river water temperature across different time scales (from daily to seasonal) and for different hydrological regimes. A model intercomparison exercise suggests that the family of air2stream hybrid models generally outperforms statistical models, while cross‐validation conducted over a 30‐year period indicates that they can be suitably adopted for long‐term analyses. Copyright © 2016 John Wiley & Sons, Ltd.     

Modeling deepwater seabed steady-state thermal fields around buried pipeline including trenching and backfill effects

Deepwater pipelines are designed to transport mixtures of oil and gas, and their associated impurities at wellhead temperatures that can be in excess of 149 °C (∼300 °F or 422 K) while the external temperature maybe in the range of 5 °C (∼41 °F or 278 K). Depending on the circumstances these pipelines may be buried for physical protection or for additional thermal insulation using robotic trenching equipment. This results in a complex cut and backfill geometry in the seafloor in addition to altering the thermal properties of the backfill. A two-dimensional boundary element model was developed specifically to address to investigate the local steady-state thermal field in the near field of the pipeline. The model allows one to account for the complex geometries in the near field associated with this burial technique, site-specific multi-layered soil conditions and the seawater adjacent to the seafloor. A parametric study was preformed to evaluate effects of the thermal power loss, burial depth, pipe diameter and soil thermal conductivity on the thermal field in the near field of a buried pipeline. The numerical examples illustrate the influence of the backfill thermal property on the temperature at the pipe wall, that the pipe diameter controls the required output thermal power needed to maintain the desired pipe wall temperature, and the importance of pipeline burial depth on seabed temperature distribution above the pipeline.     

Urban re-generations: afterword to special issue on the politics of urban greening in Australian cities

ABSTRACT

‘Urban re-generations' is written as an afterword to the special issue of Australian Geographer on ‘The Politics of Urban Greening in Australian Cities'. The collection prompts a deep questioning of reparative and regenerative work associated with greening, green spaces and green infrastructures. The climate-driven 2019-2020 bushfire crisis and COVID-19 have amplified the visibility of the more-than-human connectivity of our cities and the deep underlying structures of social and environmental inequity underpinning a variety of urban green spaces and agendas. Inspired by the articles in this special issue, the afterword explores how we might call back the grammars and practices of regeneration from their service to the neo-liberal, settler-colonial city and instead nurture reparative de-colonial practices that aid in the collaborative work of re-composing, becoming into better relation with, and working in modes of situated historical and cultural difference, with green and just cities.     

Improved spatial delineation of streambed properties and water fluxes using distributed temperature sensing

A new method was developed for analysing and delineating streambed water fluxes, flow conditions and hydraulic properties using coiled fibre‐optic distributed temperature sensing or closely spaced discrete temperature sensors. This method allows for a thorough treatment of the spatial information embedded in temperature data by creating a matrix visualization of all possible sensor pairs. Application of the method to a 5‐day field dataset reveals the complexity of shallow streambed thermal regimes. To understand how velocity estimates are affected by violations of assumptions of one‐dimensional, saturated, homogeneous flow and to aid in the interpretation of field observations, the method was also applied to temperature data generated by numerical models of common field conditions: horizontal layering, presence of lateral flow and variable streambed saturation. The results show that each condition creates a distinct signature visible in the triangular matrices. The matrices are used to perform a comparison of the behaviour of one‐dimensional analytical heat‐tracing models. The results show that the amplitude ratio‐based method of velocity calculation leads to the most reliable estimates. The minimum sensor spacing required to obtain reliable velocity estimates with discrete sensors is also investigated using field data. The developed method will aid future heat‐tracing studies by providing a technique for visualizing and comparing results from fibre‐optic distributed temperature sensing installations and testing the robustness of analytical heat‐tracing models. Copyright © 2016 John Wiley & Sons, Ltd.     

A long‐lived metamorphic history in the contact aureole of the Mooselookmeguntic pluton revealed by in situ dating of monazite grains preserved as inclusions in staurolite porphyroblasts

Emplacement of the Mooselookmeguntic pluton, located in the western Maine region of the northern Appalachians, was thought to have occurred towards the end of the Acadian deformation at around 370 Ma. Crystallization ages from different parts of the pluton suggest a more sequential emplacement history over a period of c. 20 Myr. Foliation inflection/intersection axes (FIAs) within porphyroblasts from its aureole reveal at least five periods of garnet and staurolite growth. The orientation of FIAs in both garnet and staurolite porphyroblasts trend successively from ESE–WNW, NNW–SSE, E–W, ENE–WSW to NE–SW. Electron probe microanalysis dating of monazite grains included in staurolite porphyroblasts containing one of these five periods of FIA development reveals a succession of apparent ages from 410 Ma to 345 Ma. A similar spread of crystallization ages can be observed for plutons from Maine and adjacent regions. This succession indicates that deformation and metamorphism began well before and continued long after what is classically regarded as the Acadian orogeny. The thermal structure of the orogen progressively evolved to enable pluton emplacement, and it continued to develop afterwards with magmatic fluids still forming at depth.     

Structural geometry and controls on basement‐involved deformation in the northern Flinders Ranges,Adelaide Fold Belt,South Australia

In the northern Flinders Ranges, Neoproterozoic and Cambrian sedimentary rocks were deformed and variably metamorphosed during the ca 500 Ma Cambro‐Ordovician Delamerian Orogeny. Balanced and restored structural sections across the northern Flinders Ranges show shortening of about 10–20%. Despite the presence of suitable evaporitic detachment horizons at the basement‐cover interface, the structural style is best interpreted to be thick‐skinned involving basement with only a minor proportion of the overall shortening accommodated along stratigraphically controlled detachments. Much of the contractional deformation was localised by the inversion of former extensional faults such as the Norwest and Paralana Faults, which both controlled the deposition of Neoproterozoic cover successions. As such, both faults represent major, long‐lived structures which effectively define the present boundaries of the northern Flinders Ranges with the Gawler Craton to the west and the Curnamona Craton to the east. The most intense deformation, which resulted in exhumation of the basement along the Paralana Fault to form the Mt Painter and Babbage Inliers, coincides with extremely high heat flows related to extraordinarily high heat‐production rates in the basement rocks. High heat flow in the northern Flinders Ranges suggests that the structural style not only reflects the pre‐Delamerian basin architecture but is also a consequence of the reactivation of thermally perturbed, weakened basement.