The structural role of Ti in aluminosilicate liquids in the glass transition range: insights from heat capacity and shear viscosity measurements

The shear viscosities and 1 bar heat capacities of glasses and melts along the 67mol% silica isopleth in the system SiO₂-Al₂O₃-Na₂O-TiO₂ have been determined in the temperature ranges 780-1140 K and 305-1090 K respectively. Anomalous behaviour of both these properties is observed for compositions rich in TiO₂ and/or Al₂O₃, an observation attributed to liquid-liquid phase separation followed by anatase crystallization. For samples which do not show anomalous behaviour, it is found that the partial molar heat capacity of the TiO₂ component previously determined in Al-free compositions reproduces our heat capacities to within 1.3%. Viscosity data show that addition of TiO₂ tends to increase viscosity and melt fragility at constant temperature. Furthermore, heat capacity and viscosity data may be combined within the framework of the Adam-Gibbs theory to extract values of the configurational entropy of the liquids and qualitative estimates of the variation of the average energy barrier to viscous flow. Configurational entropy at 900K is inferred to decrease upon addition of TiO₂, in contrast to previous results from Al-free systems. The compositional limit separating normal from anomalous behaviour, as well as the data for homogenous melts have been used to constrain the structural role of Ti in these samples. Our data are consistent with a majority of Ti in five-fold coordination associated with a titanyl bond, in agreement with previous spectroscopic studies. Furthermore, we find no evidence for a Ti-Al interaction in our samples, and we are led to the conclusion that Al and Ti are incompletely mixed, a hypothesis consistent with the observed reduction of configurational entropy upon addition of TiO₂, suggesting an important role of medium range order in controlling the variations in thermodynamic properties.     

沙漠增温效应特征及绿洲农业热量资源分异规律的研究

为了进一步认识绿洲高效农业特殊的热量资源，通过研究沙漠增温效应特征表明：沙漠增温效应强弱随距离沙漠远近而不同，100km范围内沙漠对绿洲的平均增温为1．76℃；另外增温效应导致绿洲日、年温差大、干热风及冷害等气候特征；由于沙漠的面积、地貌特点等的差异，使增温效应产生原因及作用程度不尽相同，表现出绿洲农业资源分异规律，并将西北干旱区绿洲分为5个类型区。     

Discourse,representation and urban planning: How a critical approach to discourse helps reveal the spatial re-ordering of street sex work1

This paper shows how a critical approach to discourse sheds light on processes of spatial re-orderings. It uses a case study of urban planning in an area of street sex work to explore the ways in which various representations of prostitution can be used to inform planning decisions. Representations of sex worker identity also expose complex spatial and social geographies and evolving processes of marginalisation and exclusion.     

The development of talus slopes around Lord Howe island and implications for the history of island planation

Lord Howe Island is a small eroded remnant of a Late Miocene shield volcano. A fringing coral reef dissipates wave energy along a portion of the shoreline, but the remainder of the coast is rugged with spectacular high basaltic sea cliffs. This paper investigates the evolution of talus slopes that occur beneath the loftiest cliffs, and places this analysis within the context of a longer history of island planation that has resulted in a wide truncated shelf around the island. During the Last Glacial, when the sea level was lower than at present, talus slopes accumulated around the extent of the island's cliffed coast because material eroded from cliffs by subaerial processes could not be removed by marine processes. The survival of these slopes during the Holocene has depended on a balance achieved between rates of subaerial and marine erosion. This balance is fundamentally influenced by cliff height, as cliffs higher than 200 m are plunging or veneered by talus slopes, whereas lower cliffs have erosional shore platforms. On comparison with published erosion rates from inland basalt scarps it appears that marine processes may account for over 90 per cent of the total cliff retreat that has occurred at Lord Howe Island, yet contemporary coastal morphology attests to the significance of subaerial processes in recent times. It is likely that marine cliffing was very rapid soon after volcanism ceased, but rates of erosion decreased through time as wave energy became increasingly attenuated across a widening planation surface, and as increasing cliff heights yielded greater quantities of talus that provided protection from rapid marine erosion.     

Possible Impacts of the Arctic Oscillation on the Interdecadal Variation of Summer Monsoon Rainfall in East Asia

The influences of the wintertime AO (Arctic Oscillation) on the interdecadal variation of summer monsoon rainfall in East Asia were examined. An interdecadal abrupt change was found by the end of the 1970s in the variation of the AO index and the leading principal component time series of the summer rainfall in East Asia, The rainfall anomaly changed from below normal to above normal in central China, the southern part of northeastern China and the Korean peninsula around 1978. However,the opposite interdecadal variation was found in the rainfall anomaly in North China and South China.The interdecadal variation of summer rainfall is associated with the weakening of the East Asia summer monsoon circulation. It is indicated that the interdecadal variation of the AO exerts an influence on the weakening of the monsoon circulation. The recent trend in the AO toward its high-index polarity during the past two decades plays important roles in the land-sea contrast anomalies and wintertime precipitation anomaly. The mid- and high-latitude regions of the Asian continent are warming, while the low-latitude regions are cooling in winter and spring along with the AO entering its high-index polarity after the late 1970s. In the meantime, the precipitation over the Tibetan Plateau and South China is excessive, implying an increase of soil moisture. The cooling tendency of the land in the southern part of Asia will persist until summer because of the memory of soil moisture. So the warming of the Asian continent is relatively slow in summer. Moreover, the Indian Ocean and Pacific Ocean which are located southward and eastward of the Asian land, are warming from winter to summer. This suggests that the contrast between the land and sea is decreased in summer. The interdecadal decrease of the land-sea heat contrast finally leads to the weakening of the East Asia summer monsoon circulation.     

Numerical Simulation of Wind and Temperature Fields over Beijing Area in Summer

1. IntroductionThe basic role of urban-rural boundary layer re-search is to study all kinds of physical process changesin the atmosphere boundary layer over urban and itssurrounding areas. Urban heat island (UHI) is a well-known feature of urban-rural climate. Attempts toincrease the understanding of the causes of the UHIand other urban-rural boundary layer phenomena haveused observational, theoretical and modelling methodssince long before. Seaman (1989) used a hydrostaticmodel, with real …     

On the applicability of KirchofPs law and the principle of heat balance in thermal infrared remote sensing:A non-isothermal system

This paper proposes a basic equation of thermal radiation interaction between surface objects on the basis of the principle of heat balance in the interface. The solution of this equation takes account of the contribution of sensible heat flux and latent heat flux more completely, compared with traditional solution for surface cooling and heating processes. By the aid of the experimental data conducted in the Xiaotangshan experimental site, Beijing, both the non-applicability of Kirchoff's law and the measurability of surface emissivity in a non-isothermal system have been highlighted. Two methods called ventilation and time-delay compensations have been proposed to reduce the error induced by change of surface temperatures of non-isothermal objects during the measurement of emissivity. Based on the solution of the basic equation, this paper has analyzed and pointed out the misunderstanding in comprehension and application of Kirchoff's law published in literature.     

Changes in the spatial scale of Beijing UHI and urban development

The seasonal and interannual variations of Beijing urban heat island (UHI) are investigated in this paper using the temperature data from 1960 to 2000 at 20 meteorological stations in the Beijing region, and then the relationship between the intensity and spatial scale of UHI and Beijing urbanization indices is analyzed and discussed. Main conclusions are the followings. First, Beijing UHI shows obvious seasonal variations, and it is strongest in winter, next in spring and autumn, and least in summer. The seasonal variation of the UHI mainly occurs in the urban area. The UHI intensity at the center of Beijing is more than 0.8℃ in winter, and only 0.5℃ in summer. Second, the intensity of Beijing HUI exhibits a clear interannual warming trend with its mean growth rate (MGR) being 0.3088℃/10 a. The MGR of HUI is largest in winter, next in spring and autumn, and least in summer, and the urban temperature increase makes a major contribution to the growth of HUI intensity. Third, since the Reform and Opening, the urbanization indices have grown several ten times or even one hundred times, the intensity of HUI has increased dramatically, and its spatial scale also expanded distinctively along with the expansion of urban architectural complexes. Fourth, the interannual variation of urbanization indices is very similar with that of HUI intensity, and their linear correlation coefficients are significant at a more than 0.001 confidence level.     

The diurnal and seasonal characteristics of urban heat island variation in Beijing city and surrounding areas and impact factors based on remote sensing satellite data

Based on the land surface temperature (LST), the land cover classification map,vegetation coverage, and surface evapotranspiration derived from EOS-MODIS satellite data, and by the use of GIS spatial analytic technique and multivariate statistical analysis method, the urban heat island (UHI) spatial distribution of the diurnal and seasonal variabilities and its driving forces are studied in Beijing city and surrounding areas in 2001. The relationships among UHI distribution and landcover categories, topographic factor, vegetation greenness, and surface evapotranspiration are analyzed. The results indicate that: (i) The significant UHI occur in Beijing city areas in the four seasons due to high heat capacity and multi-reflection of compression building, as well as with special topographic features of its three sides surrounded by mountains,especially in the summer. The UHI spatial distribution is corresponding with the urban geometry structure profile. The LST difference is approximately 4-6℃ between Beijing city and suburb areas, comparatively is 8- 10℃ between Beijing city area and outer suburb area in northwestern regions. (ii) The UHI distribution and intensity in daytime are different from nighttime in Beijing city area, the nighttime UHI is obvious. However, in the daytime, the significant UHI mainly appears in the summer, the autumn takes second place, and the UHI in the winter and the spring seem not obvious. The surface evapotranspiration in suburb areas is larger than that in urban areas in the summer, and high latent heat exchange is evident, which leads to LST difference between city area and suburb area. (iii) The reflection of surface landcover categories is sensitive to the UHI, the correlation between vegetation greenness and UHI shows obviously negative.The scatterplot shows that there is the negative correlation between NDVI and LST (R2 = 0.6481).The results demonstrate that the vegetation greenness is an important factor for reducing the UHI,and large-scale construction of greenbelts can considerably reduce the UHI effect.     

A large landslide on the urban fringe of metropolitan Phoenix, Arizona

A granitic rock avalanche, one of the largest Quaternary landslides in Arizona outside the Grand Canyon with a volume of approximately 5.25 M m³ and a width a little under 0.5 km, ran 1 km from the eastern McDowell Mountains. With lateral levees and pressure ridges, the rock avalanche deposit displays many features found on classic sturzstroms. Failure occurred along a major joint plane paralleling the slope with a dip of 44°, when a major base level lowering event in the Salt River system would have undermined the base of the failed slope, and probably during a period of more moisture than normally available in the present-day arid climate. Failure at the subsurface weathering front highlights the importance of the dramatic permeability change between grussified regolith and relatively fresh bedrock. Rock varnish microlaminations (VMLs) dating, in concert with other geomorphic evidence, suggests that the rock avalanche deposit is slightly older than 500 ka. The rock vanish results also have important implications for sampling strategies designed to use cosmogenic nuclide to date Quaternary landslide deposits. Discovery of a large landslide in close proximity to the extending urban fringe of metropolitan Phoenix argues for a more careful analysis of landslide hazards in the region, especially where rapid development excavates bedrock at the base of steep mountain slopes and where the subsurface weathering front is near the surface.