FTIR studies of reactions between the nitrate radical and haloethenes

Products and mechanisms for the gas-phase reactions of NO₃ radicals with CH₂=CHCl, CH₂=CCl₂, CHCl=CCl₂,cis-CHCl=CHCl andtrans-CHCl=CHCl in air have been studied. The experiments were carried out at 295±2 K and 740±5 Torr in a 480-L Teflon-coated reaction chamber and at 295±2 K and 760±5 Torr in a 250-L stainless steel reactor. NO₃ was generated by the thermal dissociation of N₂O₅. Experiments with¹⁵NO₃ and CD₂CDCl have also been performed. The initially formed nitrate peroxynitrates decay into carbonyl compounds, nitrates, HCl and ClNO₂. In adidtion, there are indications of nitrooxy acid chlorides being produced. The reactions with CH₂=CCl₂ and CHCl=CCl₂ are more complex due to release of chlorine atoms which eventually lead to formation of chloroacid chlorides.A general reaction mechanism is proposed and the observed concentration-time profiles of reactants and products are simulated for each compound. The rate constants for the initial step of NO₃ addition to the chloroethenes are determined as: (2.6±0.5, 9.4±0.9, 2.0±0.4 and 1.4±0.4) × 10^–16 cm³ molecule^–1 s^–1 for CH₂=CHCl, CH₂=CCl₂, CHCl=CCl₂ andcis-CHCl=CHCl, respectively.     

台风外围暴雨成因及其增幅的一种动力学机理

通过对9216号台风外围暴雨的诊断分析，发现暴雨是由低层低压气旋流场系统、与高层高压反气刻流场系统以及深厚的饱和湿度层所组成的一种高层抽吸作用所形成。暴雨的增幅原因，是通过台风和东风波系统与风带的低涡低槽系统合并加深后，导致暴雨区上空暖平流因子增强和高层抽吸作用增强所开。最后对预报和研究这类暴雨提出了几点看法。     

华北地区的共轭地震构造带

本文采用小地震活动图象和４．０级（Ｍｓ）以上地震震源机制资料的构造分析方法，得到一幅华北地区震源构造在地面的投影分布图，它显示４条ＮＮＥ－ＮＥ向和１条ＮＷＷ－ＮＷ向地震构造带交切成的共轭剪切构造格架。每条地震构造带又由一系列共轭剪切构造组成。由发生在带内的５个大震序列共轭破裂特征发现，共轭地震构造的孕震与控震作用是地震构造带形成的机制。     

大同地震序列的震源机制解

使用ＣＤＳＮ长周期地震波形记录，利用Ｈｅｌｍｂｅｒｇｅｒ（１９６８）的广义地震射线理论得到的线性反演地震矩张量的方法，对１９８９年１０月１８日－１９９１年３月２５日发生在大同的４个Ｍｓ＞５．０的地震进行了反演，计算了这些地震矩张量和断层面解。     

求震源机制P波初动解的格点尝试概率法

考虑到Ｐ波初动数据在震源球面上分布的不均匀性对节面解的可能影响，不用矛盾符号所占比例的大小作为选择可取节面解的标准，而是将震源球面分成许多小块，再确定有Ｐ波初动数字的小块为正号区或负号区的概率，最后以全部有数据小块的平均概率的高低作为选择解答的标准。用此改进方法重新测定了徐纪仁等（Ｘｕ ｅｔ．ａｌ，，１９８８）发表的青藏高原地区９９个地震的震源机制解，从中筛选出了２０个可信的解答。     

秦岭山脉对冷空气屏障的理论研究

利用二维大气中尺度数值模式，以１９７７年１月２０日－２２日的冷空气侵袭秦岭山区为例，从观测资料与数值计算两方面分析了由秦岭山脉的屏障作用而引起南北温差的主要原因。结果表明：这种屏障作用不仅体现在秦岭山脉对冷空气的阻挡作用上，而且还与秦岭南坡上的下坡风引起的绝热下沉增温有关。秦岭山脉对冷空气阻挡的动力原因除与秦岭山脉本身的拔海高度较高有关外，还与它的地形形状有关，尤其是位于秦岭北部的渭河河谷，它抑制冷空气入侵谷内，进而阻挡冷空气翻越秦岭山脉。     

内蒙地轴南缘盖层中逆冲断层的样式及形成机制

内蒙地轴南缘盖层中,发育了多种样式的逆冲断层,如叠瓦式、背冲式、对冲式和楔冲式.这些逆冲断层都发育在基底断裂控制的断陷盆地边缘,并向盆内逆冲。形成发育的过程是:区域拉伸、基底断裂活动和断陷盆地发育→区域挤压、盆缘逆冲断层发育→盆缘进一步隆起、逆冲断层进一步发育。所以区域拉伸和挤压、断陷盆地的发育和盆缘逆冲断层的活动三者密切相关。逆冲作用主要发生于燕山运动时期。     

地幔氧逸度的研究进展

通过对目前国际上诸多有关地幔氧逸度的研究结果的系统分析和总结 ,提出了地幔中自由氧对地幔物质的性质、状态及运动过程产生影响的基本作用方式 ;介绍了目前地幔氧逸度研究的主要研究手段 ,包括本征氧逸度的实验室测量、模拟氧逸度的实验室测量、地幔氧逸度计及理论计算等及其优缺点 ;定性探讨了地幔氧逸度的时空分布规律 ,获得了地幔随时间的推移变得愈来愈氧化 ,随深度的增加变得愈来愈还原 ,以及在横向上不同大地构造部位的地幔区域具有不同的氧逸度等诸多结论。结合目前人们对地幔物质组成、性质、状态、运动过程及地球的起源与演化历史等的认识 ,初步提出了地幔不同圈层氧逸度的约束机制。最后 ,针对目前地幔氧逸度的研究现状 ,为今后提出了一些参考性的研究方向。     

Structural style and deformation mechanism of the southern Dabashan foreland fold-and-thrust belt, central China

The Daba Mountains define the southern margin of the East Qinling orogenic belt, and form the boundary of the Sichuan basin in the north and northeast. The Daba Mountains can be divided into two structural belts by the NW-striking Chengkou fault, namely the northern Dabashan thrust-nappe belt and the southern Dabashan foreland fold-and-thrust belt. The southern Dabashan fold-and-thrust belt is a southwestward extruding thin-skinned thrust wedge, showing obvious belted change in deformation style and deformation intensity along the dip direction, and can be divided further into three sub-belts, i.e. the imbricate thrust sub-belt characterized by imbricate stepped-thrust sheets, the thrust-fold sub-belt characterized by the combination of the equally-developed thrusts and related folds, and the detachment-fold sub-belt characterized by box folds and closed overturned-isoclinal folds on the outcrops. Several kinds of structures have been recognized or inferred, including imbricate thrust system, passive-roof duplex (triangle zone), fault-related folds, back-thrust system and pop-up structure. The NE-SW compressive stress from the Qinling orogenic belt and detachment layers in the covering strata are the two most important determinants of deformation style. After the collision between the North China block and Yangtze block at the end of the Middle Triassic, the northward intracontinental subduction along the southern edge of the Qinling orogenic belt was initiated, which led to the corresponding southward thrusting in the upper crust. The thrusting propagated towards the foreland through the Jurassic and extended to the southernmost part of the southern Daba Mountains around the end of the Early Cretaceous, with thrusting deformation to be preferentially developed along major detachment layers and progressing upwards from the Lower Sinian through the Lower Cambrian and Silurian to Middle-Lower Triassic. Translated from Geotectonica et Metallogenia, 2006, 30(3): 294–304 [译自: 大地构造与成矿学]