Palynological records of Holocene monsoon change from the Gulf of Tonkin (Beibuwan), northwestern South China Sea

Palynological records in cores C4 and B106 from the Gulf of Tonkin reveal signals of paleo-monsoon and paleoenvironmental change during the late Pleistocene and Holocene. Before ∼ 13.4 cal kyr BP, the Gulf of Tonkin was exposed to the atmosphere and covered by grassland. Starting at ∼ 11.7 cal kyr BP, the Gulf of Tonkin was inundated by brackish water, indicated by the appearance of the brackish algae Cleistosphaeridium, Sentusidinium and Spiniferites, a decrease of herb content, and an increase of Pinus. After Hainan Island was completely separated from the Leizhou Peninsula by Qiongzhou Strait at ∼ 8.5 cal kyr BP, a continuous marine sedimentary environment was found. The current patterns were similar to those of the present, with a general trend of current homogenization reflected by gradually decreasing quantities of Quercus pollen and a narrowing gap between the palynological concentrations of the southern and northern parts of the region. The data suggest that three short periods of strengthened winter monsoons and currents were centered at ∼ 6.0 cal kyr BP, ∼ 2.7 cal kyr BP and ∼ 0.2 cal kyr BP and that two short periods of strengthened summer monsoons and currents were centered at ∼ 7.5 cal kyr BP and ∼ 3.4 cal kyr BP.     

砂岩中的凝灰质填隙物分异特征及其对油气储集空间影响--以鄂尔多斯盆地西北部二叠系为例

运用铸体薄片、扫描电镜、能谱分析及溶蚀实验等多种测试手段对鄂尔多斯盆地西北部二叠系砂岩填隙物进行了成份和成岩演化分析,认为砂岩中的填隙物主要为凝灰质填隙物,而不是普通意义上的粘土矿物。在有残余粒间孔隙或裂缝沟通的较开放性水环境里,凝灰质填隙物蚀变程度强,Si、Al、K、Na及Ca等离子因活性不同而发生分异,蚀变为“脏”高岭石及硅质团块等产物;封闭环境下,凝灰质填隙物保存完好,偏光显微镜下显示出似非晶态波状消光,活性强的K、Na元素含量仍然很高。凝灰质填隙物分异过程中,可以产生一定数量的溶蚀孔隙及晶间孔隙,砂岩储集性能得到了明显改善。对声波时差异常带砂岩进行大量的铸体薄片观察,证实了本区砂岩粒间溶蚀孔隙发育,凝灰质填隙物发生了强烈溶蚀。综合分析26口井的资料,发现垂向上凝灰质填隙物溶蚀强度呈箱型展布,箱内“脏”高岭石及溶蚀孔隙发育,箱顶部凝灰质填隙物含量高,保存好,并缺少“脏”高岭石团块出现。     

乌鲁木齐河源1号冰川积累区透底冰芯地层及冰结构分析

对乌鲁木齐河源１号冰川积累区一支深达９１．６４ｍ的透底冰芯进行了详细的层位及冰结构分析，结果表明，在２０ｍ深度以内，很好地保存了原始沉积的特征，但在７０￣８０ｍ深处还发现小密度的乳白色冰占优势的冰层，可能形成于小冰期，中层具有动力变质及再结晶作用共存及反复消长的结构特征（冰晶尺寸、气泡），未见单极大型组构，但出现弱竖环形组构，底层出现弱宝石状的多极大组构。     

喀斯特山区溪流上覆水—孔隙水—沉积物中不同形态氮的赋存特征及其迁移——以麦西河为例

选取贵州百花湖入湖支流麦西河为对象,研究了上覆水—孔隙水—沉积物体系氮的形态差异,结果表明:麦西河上覆水中,以硝态氮(NO-3-N)为主,氨态氮(NH+4-N)次之,亚硝态氮(NO-2-N)最低;孔隙水中,溶解无机氮中以NH+4-N为主, NO-3-N次之, NO-2-N最低;沉积物中,总氮(TN)的含量为1110.67～4413.16mg/kg;固定态铵含量为34.56～170.05mg/kg,占TN的1.47%～6.25%;可交换态氮以NH+4-N为主, NO-3-N次之, NO-2-N最低。孔隙水NH+4-N是上覆水NH+4-N的2.65～19.51倍,上覆水NO-3-N是孔隙水NO-3-N的7.14～20.43倍。沉积物TN与孔隙溶解水无机氮(DIN)、孔隙水NH+4-N、沉积物可交换态氮和沉积物可交换性NH+4-N呈显著正相关;在沉积物中,可交换性NO-3-N与可交换性NH+4-N及可交换态氮呈显著正相关,可交换性NH+4-N与可交换态氮呈极显著正相关;孔隙水溶解无机氮与孔隙水NH+4-N呈极显著正相关。麦西河不同介质中氮的迁移关系则表现为:由于浓度梯度,上覆水中的NO-3-N扩散到孔隙水中,进而累积到沉积物中;沉积物的可交换性NH+4-N,进入孔隙水,最终扩散到上覆水中。      

高分辨湖泊沉积和孢粉记录对气候、水文变化的响应

通过对长江中游网湖钻孔高精度分层样品(1.5年/样品)的沉积学和孢粉学研究,试图揭示过去百年网湖在由开放到封闭体系变化中,沉积孢粉与气候、水文动力变化的过程及其相互关系.相关分析和低频滤波分析,反映出沉积物和孢粉的变化对流域降水和长江流量的敏感响应.在过去130年中的多雨洪水年份,湖泊受长江倒灌影响,沉积物以黏土细颗粒...     

中缓倾角结构面分类及其抗剪强度的研究

西南某坝区中缓倾角结构面具有分别倾向上游和下游的空间分布规律。根据结构面接触情况,首先将结构面分为刚性结构面和软弱结构面两大类。其中,刚性结构面属于裂隙型;软弱结构面根据其物质组成和结构特征,可以细分为岩块岩屑型、岩屑夹泥型、泥夹岩屑型3个亚类。断层类结构面具有垂直于断层走向,由高高程到低高程,由泥夹岩屑型岩屑夹泥型岩屑砾型裂隙型逐渐过渡的发育规律。最后在分析抗剪试验资料和分类及发育规律的基础上,提出了抗剪强度指标的建议值。     

西南某水电站谷底深厚覆盖层与卸荷松弛带特征及其成因机制分析

钻孔揭示,该水电站河谷谷底发育着深厚覆盖层及卸荷松弛带。深厚覆盖层纵向上可以分为3层:下部和上部为正常的河流相,中部为多成因堆积物加积层;谷底浅表部岩体结构松弛,完整性差,裂隙张开、泥质充填,裂面严重风化锈染。研究表明,谷底松弛是由于河流切至谷底时造成应力集中,导致岩体剪切破坏;并经过漫长的卸荷回弹及风化作用在谷底形成一定厚度的松弛带。     

Changes in nutrient uptake of phytoplankton under the interaction between sunlight and phosphate in the Changjiang （Yangtze） River Estuary

We conducted ship-board incubation experiments to investigate changes in nutrient uptake of phytoplankton under different phosphate concentrations and irradiances in the Changjiang River Estuary and its adjacent waters in China. Under 100% natural irradiance the uptake rates of phosphate, silicate, and nitrate were accelerated at high phosphate levels （1.84 μM）, while under low irradiance （about 50% natural irradiance） their uptake rates were restrained at the high but stimulated greatly at the intermediate phosphate concentrations （1.26 μM）, as the growth of phytoplankton, changes in nitrite and ammonium uptake didn＇t follow an obvious pattern. Our results also showed that there were linear relationships between nitrate, silicate and phosphate uptake at different phosphate concentrations under low and high irradiances, and the growth period of phytoplankton was prolonged both at the high phosphate concentrations under high irradiance and at the intermediate concentrations under low irradiance, suggesting that the limitation of phytoplankton growth mainly reflected changes in its growth period, and because no such environment （low irradiance and low phosphate concentrations） actually existed in a high turbidity zone, phytoplankton blooms hardly occurred there. In the absence of irradiance, denitrification occurred readily and phytoplankton was kept decreasing, which resulted in phosphate regeneration.     

Dangerous assemblages: Salts,trihalomethanes and endocrine disruptors in the water palimpsest of the Llobregat River,Catalonia

Water flows through time are connected to specific instances of socionatural and sociotechnical assemblages of human and non-human components. We propose the concept of “water palimpsest” in order to characterize the complex histories of chemical and metabolic alterations embodied in water flows, potentially disruptive for humans and other living beings. Through the concept of palimpsest we interpret the configuration of water flows as constantly evolving towards new patterns maintaining at the same time traces of past mixtures. In order to decipher water pollution by means of a political ecology approach we argue that it is necessary to characterize the historical contours under which certain substances in river waters appear, interact and become hazardous. Engaging critically with literature on assemblages but also with chemical and epidemiological scientific literature, and drawing from archival and oral sources, we provide an account of historically produced pollution in the waters of Llobregat River (Catalonia) by unravelling the assemblages that shape the water palimpsest in this river. In parallel, we narrate the advances in instrumentation and analysis which permitted to detect and measure substances beyond recognition by human senses and preceded legal regulations on pollutants, starting from milligrams and (thus far) arriving at nanoscales. Focusing on the emergence of three typologies of pollutants – salts, trihalomethanes (THMs) and endocrine disruptors (EDs) – we unveil how these three assemblages embody specific instances of Llobregat socioenvironmental history, pointing towards a palimpsest characterized by increasing levels of complexity and uncertainty. The concept of water palimpsest allows us to incorporate non-human agency into the analysis of water quality and to infuse political ecology with materiality and thus with a (largely missing) focus on physicochemical and biological processes.     

Magnetite geochemistry of the Longqiao and Tieshan Fe–(Cu) deposits in the Middle-Lower Yangtze River Belt: Implications for deposit type and ore genesis

Magnetite is a common mineral in many ore deposits and their host rocks, and contains a wide range of trace elements (e.g., Ti, V, Mg, Cr, Mn, Ca, Al, Ni, Ga, Sn) that can be used for deposit type fingerprinting. In this study, we present new magnetite geochemical data for the Longqiao Fe deposit (Luzong ore district) and Tieshan Fe–(Cu) deposit (Edong ore district), which are important magmatic-hydrothermal deposits in eastern China.Textural features, mineral assemblages and paragenesis of the Longqiao and Tieshan ore samples have suggested the presence of two main mineralization periods (sedimentary and hydrothermal) at Longqiao, among which the hydrothermal period comprises four stages (skarn, magnetite, sulfide and carbonate); whilst the Tieshan Fe–(Cu) deposit comprises four mineralization stages (skarn, magnetite, quartz-sulfide and carbonate).Magnetite from the Longqiao and Tieshan deposits has different geochemistry, and can be clearly discriminated by the Sn vs. Ga, Ni vs. Cr, Ga vs. Al, Ni vs. Al, V vs. Ti, and Al vs. Mg diagrams. Such difference may be applied to distinguish other typical skarn (Tieshan) and multi-origin hydrothermal (Longqiao) deposits in the MLYRB. The fluid–rock interactions, influence of the co-crystallizing minerals and other physicochemical parameters, such as temperature and fO₂, may have altogether controlled the magnetite trace element contents of both deposits. The Tieshan deposit may have had higher degree of fO₂, but lower fluid–rock interactions and ore-forming temperature than the Longqiao deposit. The TiO₂–Al₂O₃–(MgO + MnO) and (Ca + Al + Mn) vs. (Ti + V) magnetite discrimination diagrams show that the Longqiao Fe deposit has both sedimentary and hydrothermal features, whereas the Tieshan Fe–(Cu) deposit is skarn-type and was likely formed via hydrothermal metasomatism, consistent with the ore characteristics observed.