库车坳陷侏罗系煤成气动力学模拟研究

应用黄金管—高压釜封闭体系热模拟实验与GC、GC-IRMS分析技术,结合KINETICS专用软件,对库车坳陷侏罗系煤成气进行了动力学模拟研究。库车坳陷侏罗系煤具有高的产气性,在高演化阶段主要产甲烷气;侏罗系煤热解气甲烷碳同位素为-36‰～-25‰,乙烷碳同位素为-28‰～-16‰;甲烷、C2-C5气态烃的生成活化能分别为(47～64k)calm/ol、(55～72k)calm/ol,频率因子各为5.265×1013s-1、5.388×1018s-1。在此基础上,进一步探讨了克拉2气田天然气的成因。研究认为,克拉2气田天然气属阶段捕获的煤成气,主要聚集了5～1Ma时期的天然气,其成熟度Ro分布范围为1.3%～2.5%。     

Ammonium regeneration in intertidal sediments of the Yangtze estuary during air-exposure

The influences of exposure to the atmosphere on ammonium cycle in the intertidal surface sediments were in situ studied with a geochemical approach at a typical station in the Yangtze Estuary during three tidal cycles in September 2003. During an about 8-h emersion period of each diurnal tide, six high-resolution vertical profiles of adsorbed and dissolved ammonium were measured. It was observed that both adsorbed and dissolved ammonium generally had an increasing trend in sediment cores during the exposure. The rate of ammonium regeneration in sediments was estimated using the accumulation amount of ammonium including adsorbed and soluble fractions during the daytime emersion. The calculation result showed that there was relatively high ammonification rate (˜500 nmol N cm⁻³ day⁻¹), which reflected that organic nitrogen in sediments was quickly decomposed with a residence time of ˜52.7 days. Due to the dramatic temperature difference observed in sediment profiles, free convection was considered an important mechanism of regulating the efflux of produced ammonium into overlying waters. The total estimated amount of regenerated ammonium was ˜1.35×10⁵ t N year⁻¹ in the intertidal flat of the Yangtze Estuary, which occupied 7.6% of the total inorganic nitrogen annually transported to the estuarine ecosystem.     

Petrogenesis and geotectonic setting of the PanAfrican basement rocks in Bamenda Massif, Obudu Plateau, southeastern Nigeria： Evidence from trace element geochemistry

1 IntroductionThe study area is part of the Obudu Plateau,which forms part of the Precambrian Pan-African tec-tonothermal belt, lying between the West African Cra-ton and the Gabon-Congo Craton ( Fig. 1). It isbounded by the Benue Trough, in the NE-SW axi…     

Evolution from Oceanic Subduction to Continental Collision: a Case Study from the Northern Tibetan Plateau Based on Geochemical and Geochronological Data

Two apparently distinct, sub-parallel, paleo-subduction zonescan be recognized along the northern margin of the Tibetan Plateau:the North Qilian Suture Zone (oceanic-type) with ophioliticmélanges and high-pressure eclogites and blueschistsin the north, and the North Qaidam Belt (continental-type) inthe south, an ultrahigh-pressure (UHP) metamorphic terrane comprisingpelitic and granitic gneisses, eclogites and garnet peridotites.Eclogites from both belts have protoliths broadly similar tomid-ocean ridge basalts (MORB) or oceanic island basalts (OIB)in composition with overlapping metamorphic ages (480–440Ma, with weighted mean ages of 464 ± 6 Ma for North Qilianand 457 ± 7 Ma for North Qaidam), determined by zirconU–Pb sensitive high-resolution ion microprobe dating.Coesite-bearing zircon grains in pelitic gneisses from the NorthQaidam UHP Belt yield a peak metamorphic age of 423 ±6 Ma, 40 Myr younger than the age of eclogite formation, anda retrograde age of 403 ± 9 Ma. These data, combinedwith regional relationships, allow us to infer that these twoparallel belts may represent an evolutionary sequence from oceanicsubduction to continental collision, and continental underthrusting,to final exhumation. The Qilian–Qaidam Craton was probablya fragment of the Rodinia supercontinent with a passive marginand extended oceanic lithosphere in the north, which was subductedbeneath the North China Craton to depths >100 km at c. 423Ma and exhumed at c. 403 Ma (zircon rim ages in pelitic gneiss). KEY WORDS: HP and UHP rocks; subduction belts; zircon SHRIMP ages; Northern Tibetan Plateau     

东准噶尔纸房地区晚石炭世巴塔玛依内山组陆相火山-沉积体系特征

东准噶尔巴塔玛依内山组是典型陆相火山．沉积体系(盆地)，主体由基性及中酸性火山熔岩组成，火山碎屑岩及火山碎屑沉积岩较少，通过对纸房地区晚石炭世巴塔玛依内山组陆相火山岩的岩石化学、地球化学特征进行系统研究，认为它属于造山期后固结初期，新陆壳裂谷向高原火山岩演化的同岩浆源、同沉积盆地、同火山作用的钙碱系列双峰式火山岩．     

内蒙乌拉山金矿床钾长石的矿物化学及有序度的分析

采用电子探针显微分析(EMPA)和粉末X射线衍射(XRD)分析了采自乌拉山金矿床含金钾长石石英脉、石英脉以及其他类型岩石中的10 0多个钾长石样品的化学成分和结果状态,并采用R和Q模式聚类分析、Spearman等级相关分析方法对实验数据进行了统计分析。结果表明,含金矿脉、岩浆热液脉和蚀变花岗岩中的钾长石为中等到最大微斜长石,其特征为K2 O含量高,但相对而言,Na2 O、CaO和BaO的含量低。其他岩石类型中的钾长石的化学成分和结果状态变化很大,可以从透长石、正长石到微斜长石,其特征为K2 O的含量相对较低,但Na2 O、CaO和BaO的含量相对较高。含金样品中的钾长石通常更富K2 O ,表明金的成矿作用与富钾的热液流体和碱质交代作用有关。乌拉山金矿床的成矿作用分为两个阶段,主要的含金钾长石石英脉中的钾长石富K2 O ,形成温度为30 7～379℃,平均为35 3℃;第二阶段含金石英脉中的钾长石含K2 O较低,形成温度为2 6 0～318℃,平均为2 81℃。这些结果表明成矿流体与岩浆热液作用有关,流体朝温度降低、K2 O含量降低的方向演化,K2 O含量高的热液流体和2 6 0～380℃的形成温度有利于金的成矿作用。     

青藏高原东缘缅萨洼金矿成矿流体地质地球化学特征

缅萨洼金矿位于中国中轴构造带的中南段,青藏高原的东缘,赋存于金河-箐河断裂带次级断裂羊坪子韧性剪切带中本文根据对该矿床硫化物流体包裹体的氦氩同位素、硫化物的硫同位素以及与硫化物共生的石英的流体包裹体特征、成分以及氢氧同位素组成的测定,讨论了缅萨洼金矿的成矿流体来源及其矿床成因。结果显示,该矿床硫化物流体包裹体中的3He/4He变化较小,为0.69-0.82,显示了地幔流体参与成矿作用的可能性。而4He的含量变化范围较大,一般在2.19-10.62×10-6cm3STP/g(方铅矿除外)与3He/4He相比,40Ar/36Ar的比值则变化较小,一般为251-509。而硫化物的δ34S同位素变化范围在-1.8-2.2‰,平均值为0.5‰,说明硫的地幔来源。与硫化物共生的石英的流体包裹体的类型主要有富液相的盐水溶液包裹体、富气相的盐水溶液包裹体、三相CO2包裹体、纯液相CO2包裹体以及有机流体包裹体。成矿流体的氢氧同位素则显示成矿流体来源于岩浆水(或地幔流体)与大气降水的混合流体,本文认为,缅萨洼金矿的成矿流体为地幔流体与大气降水的混合流体,是渐新世印度大陆与亚洲大陆碰撞之后,该地区大规模走滑与剪切作用过程中,局部伸展作用的产物。     

青藏高原北羌塘地区晚三叠世地层展布和沉积型式

北羌塘盆地地处拉竹龙-金沙江缝合带和双湖构造混杂岩带之间,自北向南可划分出5个沉积相带/岩石地层单位：以砂泥质复理石-洋岛、岛弧型火山岩-大理岩岩石组合沉积为特征的若拉岗日群,以深水复理石盆地相沉积为特征的藏夏河组,以深水暗色细碎屑岩盆地相沉积为特征的结扎群,以开阔台地相/缓坡相碳酸盐岩沉积为特征的菊花山组,以三角洲相含煤碎屑岩系沉积为特征的土门格拉群.晚三叠世北羌塘盆地显示为南缓北陡的箕状沉积格局,盆地内充填物为南薄北厚的楔形沉积体,且双物源、沉降中心和沉积中心不一致,表明其具有前陆盆地的一系列沉积特征.     

卫星遥感探讨杭州湾跨湖桥古文化消失原因

 8000 a前产生于杭州湾南部的跨湖桥史前灿烂文化，在辉煌了1000多a后，却神秘地消失了。针对这种消失，考古界还没有发 现确凿的原因。本文从卫星遥感角度，分析跨湖桥所处的地理、地貌特征，提出了钱塘江天文大潮冲毁跨湖桥文化的假说，希望这种 观点能够对跨湖桥这个难以用常规考古方法解决的史前文化消失问题提供一种有益的研究方法和思路。     

滨里海盆地东缘阿克纠宾地区遥感地质及地球物理场研究

 以图像处理、GIS为平台，对哈萨克斯坦阿克纠宾地区的重、磁、电、遥感及地震资料进行了综合分析。指出，该地区重、磁力资料信息含量较高，对于确定盐下构造分布具有积极意义。使用遥感资料对小断层及裂隙发育状况进行研究，有助于裂隙孔隙型碳酸盐岩油藏开发注水效率的提高。同时可对扎纳若尔、阿里别克莫拉等油田的井网状况进行监控和地面设施进行调查。