赣南中侏罗世流纹岩地球化学及成因研究：上地壳成因的的微量元素和Pb-Nd-Sr同位素地球化学制约

江西南部龙南-寻邬地区余田群菖蒲组的流纹岩形成于中侏罗世(164．8．1Ma～174．9Ma)，为双峰式火山岩组合的酸性端元，属弱过铝质(ACNK平均为1．04)钙碱性系列(σ平均为1．90)。稀土元素含量高(平均为278．9μg/g)，轻稀土富集(IMH平均为7．94)，Eu亏损中等(δEu平均为0．41)。微量元素以富集Rb，Ba，Th，U，Zr，Y，Pb，而亏损Sr，Nb为特征。Pb，Nd，Sr同位素组成为：(^206Pb/^204Pb)t=17．89～18．58，(^207Pb/^204Pb)t=15．58～15．70，(^208Pb/^204Pb)t=37．94～38．82；εNd(t)=-7．44～-11．9；ISr=0．71126～0．71228。对赣南流纹岩微量元素采用蛛网图和模糊聚类分析方法进行对比研究的结果及Pb-Nd-Sr同位素相关特征为其上地壳成因提供了地球化学佐证。赣南流纹岩是由进入上地壳内高位岩浆房的石英拉斑玄武岩浆的底侵作用直接使上地壳部分熔融形成的产物。     

西天山艾肯达坂组火山岩系同位素定年及其构造意义

西天山艾肯达坂地区较好发育了艾肯达坂纽红色陆相火山岩建造．它不整合在下石炭统大哈拉军山组之上,未经变形和变质，属于陆陆碰撞晚期的橄榄安粗岩系，其年龄确定是厘定从碰撞造山向陆内构造演化的关键。因此,通过16件新获得的钾氩年龄测值，确定艾肯达坂组火山岩系形成在260Ma～270Ma之间，属早二叠世，而不是过去认为的石炭纪；西天山的陆陆碰撞应在二叠纪末结束,此后进入陆内造山阶段。     

西秦岭三个典型金矿床稳定同位素地球化学特征

据八卦庙金矿、李坝金矿、小沟里金矿稳定同位素研究,金矿床δ34S比正常沉积岩变化范围窄,比岩浆-火山岩型矿床宽,硫源是海水硫酸盐还原硫与深部热液来源硫所组成的混合硫。石英包裹体流体氢、氧同位素分布于岩浆水、大气降水的重叠过渡区,更靠近岩浆水区,岩浆水的同位素特征更明显。八卦庙金矿石英脉3He/4He高于地壳3He/4He值(n×10-8),低于地幔3He/4He值(n×10-5),为壳-幔混合源。上述同位素地球化学证据表明,金成矿与岩浆岩有一定的成因关系。岩浆岩与金矿床空间关系密切,矿区内脉岩发育,脉岩为矿体的上下盘。含矿岩石中发育斑点构造,斑点为黄铁矿、磁黄铁矿、毒砂、绿泥石、石英、绢云母、黑云母、堇青石、红柱石、电气石、碳酸盐等热变质矿物和热液交代矿物,表明花岗岩为成矿提供热动力。据八卦庙金矿、李坝金矿、小沟里金矿稳定同位素地球化学研究,结合成矿地质背景分析和区域成矿地质特征对比,认为凤太、西成、礼岷地区金矿与微细浸染型(卡林型)金矿有明显的差别,该区金矿类似于岩浆热液矿床。     

Kinetic-simulating experiment combined with GC-IRMS analysis: application to identification and assessment of coal-derived methane from Zhongba Gas Field (Sichuan Basin, China)

The main purpose of this study is to model the δ¹³C values of methane derived from coal by combining kinetic-simulating experiment with the gas chromatography-isotope ratio mass spectrum (GC-IRMS) analysis. The stable carbon isotopic variation of methane in pyrolysates with heating temperature indicates that the assumptions for both a constant kinetic isotope effect (α) and a uniform initial isotopic composition (δ¹³C_o) are impractical for explaining the carbon isotopic fractionation during coalification. For purposes of simplification, two approaches are used in this paper to deal with the heterogeneity of terrestrial organic matter. One is that, assuming a uniform initial isotopic composition (i.e., δ¹³C_{i, o}=δ¹³C_o) for all methane-generating precursors in coal, the isotopic variation of methane is fitted by adjusting ΔE_{a, i} (E_{a¹³C, i}−E_{a¹²C, i}) for each hypothetical reaction. The other is that, assuming a constant kinetic isotope effect during the whole gas formation, that is all ΔE_{a, i} values are identical, the modeling of methane isotopic composition is achieved by changing the ¹³CH₄ generation potential of each reaction (f_{i, ¹³C}), namely, by adjusting the initial δ¹³C value (δ¹³C_{i, o}) for each methane-generating precursor. Results of the kinetic calculation shows that the two simulating methods can yield a similar result at a geological heating rate of 2 °C/My, which further demonstrates that those natural gases with methane δ¹³C value being approximately −36‰ are possibly sourced from the upper Triassic coal measure strata in the Northwestern Sichuan Basin.     

Petrology and Geochemistry of Early Cretaceous Bimodal Continental Flood Volcanism of the NW Etendeka, Namibia. Part 1: Introduction, Mafic Lavas and Re-evaluation of Mantle Source Components

The bimodal NW Etendeka province is located at the continentalend of the Tristan plume trace in coastal Namibia. It comprisesa high-Ti (Khumib type) and three low-Ti basalt (Tafelberg,Kuidas and Esmeralda types) suites, with, at stratigraphicallyhigher level, interstratified high-Ti latites (three units)and quartz latites (five units), and one low-Ti quartz latite.Khumib basalts are enriched in high field strength elementsand light rare earth elements relative to low-Ti types and exhibittrace element affinities with Tristan da Cunha lavas. The unradiogenic²⁰⁶Pb/²⁰⁴Pb ratios of Khumib basalts are distinctive, most plottingto the left of the 132 Ma Geochron, together with elevated ²⁰⁷Pb/²⁰⁴Pbratios, and Sr–Nd isotopic compositions plotting in thelower ¹⁴³Nd/¹⁴⁴Nd part of mantle array (EM1-like). The low-Tibasalts have less coherent trace element patterns and variable,radiogenic initial Sr (     

Late-glacial and Holocene vegetation and climatic history of the Cass Basin, central South Island, New Zealand

Lithology, pollen, macrofossils, and stable carbon isotopes from an intermontane basin bog site in southern New Zealand provide a detailed late-glacial and early Holocene vegetation and climate record. Glacial retreat occurred before 17,000 cal yr B.P., and tundra-like grassland–shrubland occupied the basin shortly after. Between 16,500 and 14,600 cal yr B.P., a minor regional expansion of forest patches occurred in response to warming, but the basin remained in shrubland. Forest retreated between 14,600 and 13,600 cal yr B.P., at about the time of the Antarctic Cold Reversal. At 13,600 cal yr B.P., a steady progression from shrubland to tall podocarp forest began as the climate ameliorated. Tall, temperate podocarp trees replaced stress-tolerant shrubs and trees between 12,800 and 11,300 cal yr B.P., indicating sustained warming during the Younger Dryas Chronozone (YDC). Stable isotopes suggest increasing atmospheric humidity from 11,800 to 9300 cal yr B.P. Mild (annual temperatures at least 1°C higher than present), and moist conditions prevailed from 11,000 to 10,350 cal yr B.P. Cooler, more variable conditions followed, and podocarp forest was completely replaced by montane Nothofagus forest at around 7500 cal yr B.P. with the onset of the modern climate regime. The Cass Basin late-glacial climate record closely matches the Antarctic ice core records and is in approximate antiphase with the North Atlantic.     

Comparisons on seasonal and annual variations of δ~(18)O in precipitation

interpretationofpaleoclimaticrecordsinicecore(Dansgaardetal.,1969;Rozanskietal.,1997;Yao,1999;Thompsonetal.,2000).SincethefirstdeepicecorewasdrilledinGreenlandin1966(Dansgaardetal.,1969),hundredsoficecoreswereobtainedsuccessivelyfromicesheetsinAntarcticaandArctic,andmountainglaciersatmid-highlatitudes,fundedbynumerousresearchprogramsonglobalclimateandenvironmentalchange.Theseicecoresprovideuniqueandvaluablefirst-handinformationinrecoveringglobalpaleoenvironmentalrecordsandforecastingfuturecl…     

Modern stable isotopic (δ18O, δ2H, δ13C) variation in terrestrial,fluvial, estuarine and marine waters from north‐central Sarawak,Malaysian Borneo

Stable isotope data on humid tropical hydrology are scarce and, at present, no such data exist for Borneo. Delta¹⁸O, δ²H and δ¹³C were analysed on 22 water samples from different parts of the Sungai (river) Niah basin (rain, cave drip, rainforest pool, tributary stream, river, estuary, sea) in north‐central Sarawak, Malaysian Borneo. This was done to improve understanding of the modern stable isotope systematics of the Sungai Niah basin, essential for the palaeoenvironmental interpretation of the Late Quaternary stable isotope proxies preserved in the Great Cave of Niah. The Niah hydrology data are put into a regional context using the meteoric water line for Southeast Asia, as derived from International Atomic Energy Agency/World Meteorological Organization isotopes in precipitation network data. Although the Niah hydrological data‐set is relatively small, spatial isotopic variability was found for the different subenvironments of the Sungai Niah basin. A progressive enrichment occurs towards the South China Sea (δ¹⁸O ?4·6‰; δ²H ?29·3‰; δ¹³C ?4·8‰) from the tributary stream (δ¹⁸O ?8·4‰; δ²H ?54·7‰; δ¹³C ?14·5‰) to up‐river (δ¹⁸O c. ?8‰; δ²H c. ?51‰; δ¹³C c. ?12‰) and down‐river values (δ¹⁸O c. ?7·5‰; δ²H c. ?45‰; δ¹³C c. ?11‰). This is thought to reflect differential evaporation and mixing of different components of the water cycle and a combination of depleted biogenic δ¹³C (plant respiration and decay) with enriched δ¹³C values (due to photosynthesis, atmospheric exchange, mixing with limestone and marine waters) downstream. Cave drip waters are relatively enriched in δ¹³C as compared to the surface waters. This may indicate rapid degassing of the cave drips as they enter the cave atmosphere. Copyright © 2005 John Wiley & Sons, Ltd.     

Geochemistry of ore-forming fluids and geological significance of the Kuoerzhenkuola gold field in Xinjiang, China

The Kuoerzhenkuola gold field (including the Kuo- erzhenkuola and the Buerkesidai gold deposits), lo- cated 68 km east of Jimunai County in northern Xing- jiang, China, is an important component of the Sawuer gold belt which is the eastward extending part of the Zarma-Sawur gold-copper belt in Kazakhstan. Some studies are concerned with the geology of the gold ores[1―3], the associated volcanic rocks[4], radiogenic isotope[5―8], and the ore-forming environment[8]. Most researchers inferr…     

Isotopic evidence of TSR origin for natural gas bearing high H_2S contents within the Feixianguan Formation of the northeastern Sichuan Basin, southwestern China

Isotopic evidence of TSR origin for natural gas bearing high H2S contents 1961 As the hazardous component of natural gas, the ex-istence of H2S, due to its extremely strong toxicity and corrosivity, not only decreases the percentage of hy-drocarbon gas within natural gas and reduces its in-dustrial value, it also threatens each aspect of drilling and exploitation. It frequently causes serious safety accidents[1] and leads to the E&P cost and risk of natural gas with higher H2S contents be…