C/2002 VQ94 (LINEAR) and 29P/Schwassmann-Wachmann 1 — CO and N2 rich comets

We investigated comets active at large heliocentric distances using observations obtained at the 6-m BTA telescope (SAO RAS, Russia). Long-slit and photometric modes of the focal reducer SCORPIO were used. Two of the comets, 29P/Schwassmann-Wachmann 1 (SW1) and C/2002 VQ94 (LINEAR) were observed to be emission rich. Detection of CO⁺ and N⁺₂ emissions in the comae of these comets is evidence that they were formed in the outer regions of the Solar System or in a pre-solar interstellar cloud in a low temperature environment with T?25 K. The ratio of N⁺₂/CO⁺ is equal to 0.011 and 0.027 for SW1 and LINEAR, respectively. Comet LINEAR is the most distant object in the Solar System (7.332 AU) for which CO⁺ and N⁺₂ are measured. The photometric maximum of the isolated CO⁺ coma in Comet LINEAR is shifted by 1.4 arcsec (7.44×¹⁰³ km) relative to the photometric maximum of the dust coma. This shift deviates from the sunward direction by 63 degrees.     

Anwendung eines neuen Feldanalysenverfahrens zur Untersuchung der Stabilität von Arsen und seinen anorganischen Spezies in aquatischen Systemen

Using of a New Field Analysis Method to Investigate the Stability of Arsenic and its Inorganic Species in Aquatic Systems The stability of arsenic species in aquatic systems is limited by the possibilities of chemical and biochemical reactions. Redox reactions and bioalkylation lead to changes of the species ratios. In this work, the stability of As(III) and As(V) was examined at storage of distilled, de-ionized, and drinking water at different conditions (refrigerator/room temperature; daylight/darkness) and additions (sulfuric acid; ascorbic acid). The determination of these species was carried out by a modified spectrophotometric method, suitable for laboratory analysis as well as for field analysis. The results show that chemical oxidation and biochemical reduction can occur. Sulfuric acid is favourable for the stabilization of total arsenic and of the inorganic species.     

Ultraviolet spectroscopy of Asteroid (4) Vesta

We report a comprehensive review of the UV–visible spectrum and rotational lightcurve of Vesta combining new observations by Hubble Space Telescope and Swift Gamma-ray Burst Observatory with archival International Ultraviolet Explorer observations. The geometric albedos of Vesta from 220 nm to 953 nm are derived by carefully comparing these observations from various instruments at different times and observing geometries. Vesta has a rotationally averaged geometric albedo of 0.09 at 250 nm, 0.14 at 300 nm, 0.26 at 373 nm, 0.38 at 673 nm, and 0.30 at 950 nm. The linear spectral slope as measured between 240 and 320 nm in the ultraviolet displays a sharp minimum near a sub-Earth longitude of 20°, and maximum in the eastern hemisphere. This is consistent with the longitudinal distribution of the spectral slope in the visible wavelength. The photometric uncertainty in the ultraviolet is ∼20%, and in the visible wavelengths it is better than 10%. The amplitude of Vesta’s rotational lightcurves is ∼10% throughout the range of wavelengths we observed, but is smaller at 950 nm (∼6%) near the 1-μm band center. Contrary to earlier reports, we found no evidence for any difference between the phasing of the ultraviolet and visible/near-infrared lightcurves with respect to sub-Earth longitude. Vesta’s average spectrum between 220 and 950 nm can well be described by measured reflectance spectra of fine particle howardite-like materials of basaltic achondrite meteorites. Combining this with the in-phase behavior of the ultraviolet, visible, and near-infrared lightcurves, and the spectral slopes with respect to the rotational phase, we conclude that there is no global ultraviolet/visible reversal on Vesta. Consequently, this implies a lack of global space weathering on Vesta, as previously inferred from visible–near-infrared data.     

A laboratory study of the bidirectional reflectance from particulate samples

The Hapke (Hapke, B. [1981]. J. Geophys. Res. 86, 3039-3054) photometric model and its modifications are widely used to characterize telescopic, spacecraft, and laboratory observations of the bidirectional reflectance of particulate surfaces. Following work and methods laid out in a companion paper (Helfenstein, P., Shepard, M.K. [2011]. Icarus, in press), we deconstruct the Hapke model and, separating all empirical and ad hoc parameters (opposition surge, particle phase function, surface roughness), combine them into a single parameter called the surface phase function, F(α). We illustrate how to extract this function from scattering data sets acquired with the Bloomsburg University Goniometer (BUG). We show how this method can be used to rapidly and accurately characterize bidirectional reflectance data sets from laboratory and spacecraft measurements, often giving better fits to the data. We examine samples with strong color contrasts in different wavelengths. This allows us to examine the exact same surface, changing only the albedo to investigate how the amplitude and the detailed shape of the surface phase function might systematically depend on wavelength and albedo. We also examine the changes in scattering behavior that result when samples are compacted and find the surface phase function and single scattering albedo to be significantly changed. We suggest that these observations support the hypothesis that much of the scattering behavior attributed to the single particle phase function is instead cause by the surface micro-structure.     

Mercury resolved spectroscopy from NTT

Mercury has been observed in June 2006 with the SofI instrument at NTT. Resolved spectroscopy was performed in the range. The observations were acquired close to a favorable quadrature with maximum elongation, and span mostly the southern hemisphere in the 235–315°E longitude area.In contrast to recent observations from IRTF, the present study does not indicate any pyroxene absorption in the near-infrared range, neither in the region nor at . Detailed spectral analysis allows to derive an upper limit of 1.5% type-A pyroxene (hedenbergite) or 1.1% enstatite (assuming minimum lunar iron content) in the regions observed, at the 700 km scale. Assuming lunar-like maturity effects on band depth, this corresponds to an upper limit of 0.15 and 0.6 wt.% FeO content in silicates, an order of magnitude less than previous estimates.     

Global photometric properties of Asteroid (4) Vesta observed with Dawn Framing Camera

Dawn spacecraft orbited Vesta for more than one year and collected a huge volume of multispectral, high-resolution data in the visible wavelengths with the Framing Camera. We present a detailed disk-integrated and disk-resolved photometric analysis using the Framing Camera images with the Minnaert model and the Hapke model, and report our results about the global photometric properties of Vesta. The photometric properties of Vesta show weak or no dependence on wavelengths, except for the albedo. At 554 nm, the global average geometric albedo of Vesta is 0.38 ± 0.04, and the Bond albedo range is 0.20 ± 0.02. The bolometric Bond albedo is 0.18 ± 0.01. The phase function of Vesta is similar to those of S-type asteroids. Vesta’s surface shows a single-peaked albedo distribution with a full-width-half-max ∼17% relative to the global average. This width is much smaller than the full range of albedos (from ∼0.55× to >2× global average) in localized bright and dark areas of a few tens of km in sizes, and is probably a consequence of significant regolith mixing on the global scale. Rheasilvia basin is ∼10% brighter than the global average. The phase reddening of Vesta measured from Dawn Framing Camera images is comparable or slightly stronger than that of Eros as measured by the Near Earth Asteroid Rendezvous mission, but weaker than previous measurements based on ground-based observations of Vesta and laboratory measurements of HED meteorites. The photometric behaviors of Vesta are best described by the Hapke model and the Akimov disk-function, when compared with the Minnaert model, Lommel–Seeliger model, and Lommel–Seeliger–Lambertian model. The traditional approach for photometric correction is validated for Vesta for >99% of its surface where reflectance is within ±30% of global average.     

磷酸亚铁锂碳复合物中碳、铁、磷含量的测定

采用重量法测定了自制磷酸亚铁锂碳复合物中的碳含量,且将碳过滤分离后,制得了样品溶液,用来测定其中的元素含量。采用EDTA络合滴定法和邻菲啰啉分光光度法测得铁离子质量分数分别为33.88%、33.77%,测定的RSD分别为0.1%、0.6%。两种方法的测定结果很接近,但是通过F检验法得到EDTA络合滴定法的精密度显著高于邻菲啰啉分光光度法的精密度。采用磷钼酸喹啉重量法和磷钒钼黄光度法测得磷的质量分数分别为19.22%、19.36%,测定的RSD为1.81%、1.89%。两种方法的测定结果很接近,通过F检验法发现两种方法的精密度不存在显著性差异,通过t检验法发现两种方法在置信度为90%时,不存在显著性差异。     

水中爆破地震动强度计算方法的研究

介绍了爆破地震动强度的主要因素及经验公式 ,分析了利用最小二乘法求场地系数K、α值方法的不足之处 ,提出最大似然法求解K、α值的新思路 ,并用实例证明了其具有更高的预测准确度     

Spectral study of the Eunomia asteroid family Part II: The small bodies

Reflectance spectra in visible and near-infrared wavelengths of 97 nominal members of the Eunomia asteroid family have been obtained and analyzed. According to these investigations, 94% of the observed dynamic family members belong to the Tholen S-class, only 4% to the C-class and 2% to the M-class. The S-asteroids are believed to be “genetic” members of the Eunomia family and thus are fragments of 15 Eunomia. The fragments show different 1- and 2-μm absorption band characteristics, which are likely attributed to their place of origin within the parent body. The major volume fraction of the investigated members seems to originate from the “crust” of the parent body while the volume fraction of “mantle” material is less. Previous spectral investigations (Nathues, A., Mottola, S., Kaasalainen, M., Neukum, G. [2005], Icarus 175 (2), 452-463) of the family’s main body, 15 Eunomia, revealed variations of olivine and pyroxene on a hemispherical scale. These findings, together with the conclusion that the major mineral component of 15 Eunomia and its fragments is olivine, suggest that a large fraction of the original pyroxene-enriched crust layer has been lost due to a major collision that created the asteroid family. Significant spectral evidences consistent with high concentrations of metals have not been found in the rotational resolved spectra of 15 Eunomia and in its fragments. This led to the conclusion that either a core, which consists mainly of metals, does not exist or that an eventual one has not yet been unearthed by an impact. The absence of V-type asteroids, the low number of M-types among the dynamic family members and the lack of distinct feldspar absorption features in the S-asteroid spectra suggest that the parent body of the Eunomia family was partially differentiated rather than fully differentiated.