云南安楚高速公路大红田隧道涌水分析

依据大红田隧道水文地质勘察和监测数据,结合前人已有成果,重点探讨隧道涌水特征、涌水影响范围及地下水消失量,并尝试对断流泉出流进行预测。     

Heat of formation of petalite, LiAlSi4O10

The enthalpy of formation of petalite, LiAlSi₄O₁₀, has been measured using high-temperature solution calorimetry. The measurements were carried out in a Calvet-type twin micro calorimeter at 728?°C. A 2PbO?·?B₂O₃ melt was used as a solvent. Tabulated heats of formation of the components and tabulated heat capacities of the reactants and the product (Robie and Hemingway 1995) were used to calculate the standard heat of formation of petalite from the measured heats of solution. The calculations yielded a mean value of Δ _f H ^pet _298.15=?4872±5.4 kJ mol^?1. This value may be compared to the heat of formation of Δ _f H ^pet _298.15= ?4886.5±6.3 kJ mol^?1 determined by the HF solution calorimetry by Bennington et?al. (1980). Faßhauer et?al. (1998) combined thermodynamic data with phase-equilibrium results to obtain best-fit thermodynamic results using the Bayes method, in order to derive an internally consistent dataset for phases in the NaAlSiO₄– LiAlSiO₄–Al₂O₃–SiO₂–H₂O system. They determined ?4865.6?±?0.8?kJ?mol^?1 as the enthalpy of formation of petalite, a value that is appreciably closer to the enthalpy found in this work.     

基于AHP-熵-TOPSIS对极轨气象卫星应用系统健康程度评价指标体系

以实现对极轨气象卫星应用系统健康程度进行综合评价为目的,提出结合主观分析的层次分析法(Analytic Hierarchy Process,AHP)和客观分析的熵权法(Entropy Weight,EW)确定待评价系统指标值的综合权重,再采用逼近理想解排序法(Technique for Order Preference by Similarity to an Ideal Solution,TOPSIS)对系统的指标进行多角度评价排序来作为最终评价结果。本文根据连续5个月3颗极轨气象卫星在实际业务系统运行中异常指标样本进行实证分析。结果表明该方法较为全面考虑了影响应用系统的多种因素,避免了单一判据的局限性,并对各指标的重要性进行综合对比分析,使得评价结果更科学准确,可以作为构建极轨气象卫星应用系统健康程度评价指标体系的一种方法。     

多组份电解质溶液热力学——活度系数和渗透系数与高次极限定律的关联

自1973年Pitzer电解质溶液理论问世以来,它在海洋学、地球科学、生物学乃至化工中获得了广泛的应用。本文介绍在实际应用中有重要意义的高次极限定律及与活度系数、渗透系数间的关联,它们是Pitzer理论发展的重要组成部份。     

矿物热力学数据的获取

简介矿物热力学数据获取方法发展现状,重点评述量热法和相平衡法的近期发展状况。     

Limestone solution rates and processes in the Waitomo District,New Zealand

Karst solution processes are investigated on Oligocene limestones in the Waitomo district, west central North Island, New Zealand. Estimates of the inputs, throughputs and outputs of water and dissolved calcium and magnesium in two drainage basins were used to establish the rate of limestone solution by autogenic waters. The best estimate for solution loss from the basins during the study year is 69 m³/km². The potential measurement errors inherent in each parameter used in the erosion rate computations were assessed and the probable maximum and minimum erosion rates were estimated to be 88 and 61 m³/km². In both basins approximately 67 per cent of the annual solute load is transported by flows greater than the mean annual discharge, over 15 per cent being transported by flood flows that are exceeded only 5 per cent of the time. Almost half of the annual load is transported during the three winter months (June-August), but no one month accounts for more than 18 per cent or less than 2.7 per cent of the annual total. Approximately 37 per cent of solution takes place within the soil profile, and most of the remainder is concentrated in 5–10 m of weathered bedrock (the subcutaneous zone) beneath this. Thus, it is likely that at least 85 per cent of the total solutional erosion contributes to the surface lowering of soil and bedrock.     

Hydrochemistry and solution rates in gypsum karst: case study from the Western Ukraine

The gypsum karst in the Western Ukraine spreads through a large territory covering more than 20,000 km² and is represented by a range of stages (evolutionary types), from deep-seated through subjacent to entrenched. Correspondingly, hydrogeological settings of karst development, circulation patterns and chemical characteristics of groundwaters differ substantially between the respective areas. Based on 1,800 analyses, this paper summarises hydrochemistry of the gypsum-hosting Miocene aquifer. The majority of sampling has been performed in conjunction with a study regime of gypsum solution rates by means of standard tablets. In this study, which included 53 tablet stations representing varying conditions of water-rock interaction, 644 weight-loss measurements were made over the period 1984–1992. The highest rates are characteristic of entrenched karst although active dissolution is localised along well-defined sinking streams with short underground courses, rare vertical percolation paths and the water table. Lower but still quite substantial rates are characteristic of subjacent and deep-seated (confined) karst. However, the overall dissolution removal is greater due to higher flow through the gypsum and the larger area of rock-solvent contact. The results are generalised in order to derive the approximate solution rates characterising major situations and to be suitable for modeling purposes.     

智能大厦接地电阻检测中应注意的问题

根据目前常用接地电阻检测仪器的测量原理，对在日常检测中所出现导致接地电阻检测数据失真的情况进行了分析和探讨，同时针对不同的成因，提出了不同的解决方法。     

Dissolution Enthalpies of Magnesian Calcites

A series of synthetic and biogenicmagnesian calcites was dissolved in weak acetic acidsolutions to measure the enthalpies of dissolution at25°C. For the synthetic phases, heat releasedwas 33.5 kJ/mol for calcite, decreasing to 33 kJ/molfor a phase of 2 mol % MgCO3, and increasing to35 kJ/mol for a phase of 15 mol %. Values of excessenthalpies, ΔHxs, calculated using calciteand magnesite end-members, average about -1 kJ/mol forthe synthetic phases. Total entropies of solidsolution formation, ΔSSS, also werecalculated using available data on Gibbs free energiesof formation and these excess enthalpies. Values ofΔSSS range from -2 J/(mol-K) at 2 mol % to-5 J/(mol-K) at 15 mol % MgCO3. These negativevalues of ΔHxs and ΔSSSsuggest that some form of ordering (cation?) isobtained in the synthetic phases, and that vibrationalentropies of the solid solution are diminished incomparison to the end-members. In contrast, biogenic samples generally have positivevalues of ΔHxs, increasing from +1 kJ/molat 5 mol % to +3 kJ/mol at 20 mol % MgCO3. Mostvalues of ΔSSS are equal (within errors)to values expected from configurational enthalpyalone. Thus, in most biogenic materials cationordering probably is not obtained, and most phases aremore typical of equivalent-site solid solutions.     

正定矩阵的三角分解及其在测量平差中的应用

介绍正定矩阵的三角分解方法；讨论利用正定矩阵三角分解，求线性对称方程组中未知数、未知数函数，以及方程组系数矩阵逆阵的方法；给出了相应计算的紧凑格式和在测量平差中的应用实例。