Comparative high-resolution chemostratigraphy of the Bonarelli Level from the reference Bottaccione section (Umbria-Marche Apennines) and from an equivalent section in NW Sicily: Consistent and contrasting responses to the OAE2

The Bonarelli Level (BL) from the upper Cenomanian portion of the reference Bottaccione section (central Italy) is characterized by the presence of black shales containing high TOC concentrations (up to 17%) and amounts of CaCO₃ near to zero. In the absence of carbonate and, consequently, of relative carbon- and oxygen-isotopic data, the elemental geochemistry revealed to be a very useful tool to obtain information about the palaeoclimatic and palaeoceanographic evolution of the Tethys Ocean during the OAE2. Based on several geochemical proxies (Rb, V, Ni, Cr, Si, Ba), the BL is interpreted as a high-productivity event driven by increasingly warm and humid climatic conditions promoting an accelerated hydrological cycle. The enrichment factors of peculiar trace metals (Zn, Cd, Pb, Sb, Mo, U) provide further insight about the H₂S activity at the seafloor during the organic-rich sediment deposition and permitted us to evaluate the use of Ba as palaeoproductivity tracer in conditions of high rate of sulphate reduction.By comparing geochemical records from the reference Bottaccione section (central Italy) with those previously obtained for the coeval Calabianca section (northwestern Sicily), different degrees of oceanic anoxia were delineated and ascribed to different abundance and type (degradable or refractory) of organic matter, which are limiting factors in the bacterial sulphate reduction reactions and in subsequent euxinic conditions at seafloor in the Tethys realm. Based on a ciclostratigraphic approach, consistent fluctuations at 100 ky scale in the chemostratigraphic signals from the two sections are inferred to be expression of a strong orbital-climatic forcing driving changes in the oceanic environment during the BL deposition.     

The 1780 seismic sequence in NE Sicily (Italy): shifting an underestimated and mislocated earthquake to a seismically low rate zone

The southernmost sector of the Italian peninsula is crossed by an almost continuous seismogenic belt capable of producing M ∼ 7 earthquakes and extending from the Calabrian Arc, through the Messina Straits, as far as Southeastern Sicily. Though large earthquakes occurring in this region during the last millennium are fairly well known from the historical point of view and seismic catalogues may be considered complete for destructive and badly damaging events (IX ≤ I _o ≤ XI MCS), the knowledge and seismic completeness of moderate earthquakes can be improved by investigating other kinds of documentary sources not explored by the classical seismological tradition. In this paper, we present a case study explanatory of the problem, regarding the Ionian coast between the Messina Straits and Mount Etna volcano, an area of North-eastern Sicily lacking evidence of relevant seismic activity in historical times. Now, after a systematic analysis of the 18th century journalistic sources (gazettes), this gap can be partly filled by the rediscovery of a seismic sequence that took place in 1780. According to the available catalogues, the only event on record for this year is a minor shock (I _o = VI MCS, M _w = 4.8) recorded in Messina on March 28, 1780. The newly discovered data allow to reinstate it as the mainshock (I _o = VII–VIII MCS, M _w = 5.6) of a significant seismic period, which went on from March to June 1780, causing severe damage along the Ionian coast of North-eastern Sicily. The source responsible for this event appears located offshore, 40-km south of the previous determination, and is consistent with the Taormina Fault suggested by the geological literature, developing in the low seismic rate zone at the southernmost termination of the 1908 Messina earthquake fault.     

Sicilian serpentinite xenoliths containing abiotic organics with nanodiamond clusters as key model for prebiotic processes

Rock fragments from the deepest parts of a buried hydrothermal system belonging to the Mesozoic Tethys Ocean entered as xenoliths in a Miocenic diatreme,hence brought to the surface,in the Hyblean Plateau(Sicily).Some xenoliths consist of strongly serpentinized ultramafic rocks bearing blebs of abiotic organic matter,where clusters of amorphous carbon nanoparticles,including nanodiamonds,are immersed.Such an occurrence conjures up established hypotheses that diamond surfaces are suitable catalytic platforms stimulating the assemblage of complex bio-organic molecules relevant to the emergence of life on Earth.The appearance of bio-organic molecules under primitive Earth conditions is one of the major unsolved questions on the origin of life.Here we report new micro-Raman spectra on blebs of abiotic organic matter from a selected xenolith.Diamond bands were related to hydrogenated nanocrystalline diamonds,with size of nearly 1-1.6 nm,formed from organics at low pressures and temperatures.In particular,diamond surfaces can give rise to crystalline interfacial water layers that may have played a fundamental role in the early biosphere evolution as a good medium for rapidly transporting positive charges in the form of hydrated protons.Nowadays,proton gradients in alkaline hydrothermal vents along oceanic ridges are generally viewed as key pre-biotic factors.In general,serpentinites span the entire geological record,including prebiotic times.These hydrous ultramafic rocks often display evidence of abiotic carbon species,both organic and inorganic,including nanodiamonds,being also capable to give rise to chemiosmotic processes and proton gradients necessary to the organisms,such as the"Last Universal Common Ancestor"(LUCA),in the prebiotic Earth.     

The youngest record of metriorhynchid crocodylomorphs,with implications for the extinction of Thalattosuchia

Here we describe an isolated tooth of a metriorhynchid crocodylomorph from the Hybla Formation (Aptian, Lower Cretaceous) of Rocca Chi Parra quarry (Montagna Grande, Calatafimi, Trapani Province), Sicily, Italy. The specimen shares with the Upper Jurassic taxon Plesiosuchus manselii a mediolaterally compressed conical tooth crown, noticeable lingual curvature, mesial and distal carinae with microscopic, rectangular contiguous denticles, strong distal curvature of the mesial margin, and the presence of weak 'carinal flanges' on the labial and lingual surfaces (which are preeminent at the mid-crown). This suite of morphologies is also present in an unnamed Valanginian (Lower Cretaceous) plesiosuchinan from France. However, the Sicilian tooth differs from these taxa in having more pronounced carinae, and faint apicobasally aligned enamel ridges. It also differs from P. manselii in having more extensive 'carinal flanges' on the labial surface. The specimen extends the known geological range of Metriorhynchidae and Thalattosuchia by approximately 7–8 million years. This overturns previous hypotheses of Metriorhynchidae becoming extinct early in the Early Cretaceous.     

Empirical prediction of the ground shaking scenario for the Catania area

Simplified approaches for prediction of strong ground shaking, that can be efficiently implemented through a Geographical Information System (GIS), are applied to constructing earthquake scenarios for the Catania municipal area. Ground shaking maps in terms of peak ground acceleration and response spectral ordinates are developed both for a repetition of the catastrophic 1693 earthquake (M7.3), and for a lower energy event, like that which occurred in 1818 (M6.2). The maps account for amplification due to local site conditions. According to the commonly used attenuation relations, the local amplification is taken into account either in a simpler way or in a more detailed approach, derived from an extensive geotechnical zonation. The approximation introduced by the simpler methodology, to be used whenever accurate data are not available, is estimated by a comparison with damage distribution.     

A new facies model for the Upper Gypsum of Sicily (Italy): chronological and palaeoenvironmental constraints for the Messinian salinity crisis in the Mediterranean

The Upper Gypsum unit of the Caltanissetta Basin (Sicily) records the last phase of the Messinian salinity crisis comprising the so‐called ‘Lago Mare’ event. A new facies analysis study recognizes nine to ten depositional cycles consisting of seven rhythmically interbedded primary gypsum bodies, and two to three sandstone bodies separated by marly terrigenous horizons showing laterally persistent vertical organization. A basal thin gypsum bed is overlain by a cluster of five thicker gypsum bodies. A marly interval containing two distinct sandstone horizons separates this cluster from the overlying uppermost (seventh) gypsum body. The terrigenous Arenazzolo Formation, in turn followed by the lower Pliocene Trubi Formation, is considered here to form the uppermost part of the Upper Gypsum unit. The rhythmic alternation in the sandy marls and gypsum/sandstone bodies records the response of sediments from shelfal to deltaic systems to precession‐driven arid‐wet climate fluctuations causing cyclical changes of both base‐level and water concentration. During wet climate phases (at insolation maxima) marl and sandstone were deposited in a hypohaline environment as suggested by: (i) the typical Lago Mare faunal assemblage and (ii) the negative δ¹⁸O values. During arid phases (at insolation minima) the reduced meteoric supply, recorded by higher δ¹⁸O values in the carbonate, caused the development of a negative hydrological budget leading to evaporite precipitation. At a basinal scale the Upper Gypsum unit unconformably overlies a mainly clastic evaporite unit containing carbonate breccia (the so‐called ‘Calcare di Base’) and/or clastic gypsum. Towards the basin centres, where the basal contact becomes conformable, a primary gypsum cumulate horizon is present. This layer is interpreted as a possible lateral equivalent of the Halite unit present only in the deepest depocentres. Based on astronomical calibration of the depositional cycles, the Upper Gypsum unit, including the Arenazzolo Formation, spans the interval between 5·33 and 5·53 Ma. This new age calibration allows the deposition of the Halite unit to be dated between 5·6 Ma (top of the Lower Evaporites) and 5·55 Ma (base of the Upper Evaporites) corresponding to isotopic stages TG12 and/or TG14.     

Ground penetrating radar survey finalized to the recovery of the “S. Agata alla Badia” church in Catania (eastern Sicily,Italy)

Numerous archaeological sites dating to the greek-roman period have been found in the underground of the city of Catania (eastern Sicily, Italy). Their presence is a testimony of the several settlements that have followed in this area over time. In this work we have conducted electromagnetic surveys, consisting of ten georadar profiles, inside the church of “S. Agata alla Badia”, damaged during the earthquake occurred in eastern Sicily on 13 December 1990. The aim was to investigate the area where the church is located to obtain information useful for its structural recovery. Mechanical drillings were also carried out to reconstruct the local stratigraphy, which could be complicated by the presence of underground cavities and artefacts, as evidenced by recent excavations beneath the Catania Cathedral, in the nearby Piazza Duomo. From the interpretation of the GPR data, the presence of ancient masonry structures underlying the recent foundations was highlighted. In addition, the GPR survey allowed us to identify and locate reflective horizons in the subsurface, probably due to the presence of materials with different state of aggregation and/or to buried structures.