陕西省略阳县铧厂沟金矿床主矿带地球化学原生晕特征及其地质意义

陕西省铧厂沟金矿是一个主要赋存于海底基性火山喷流细碧岩中的金矿床。在野外地质工作的基础上,对主矿带样品的测试数据进行了数学地质分析和原生晕分带序列计算。结果表明,Au11矿体的原生晕轴向分带序列从上至下为:Hg-Sb-Ni-As-Bi-Cu-Au-Co-Zn-W-Mo-Mn-Pb-Ag-Cd;Au8矿体的原生晕轴向分带序列从上至下为:Cu-Co-W-Au-Ni-Sb-Mn-As-Pb-Bi-Hg-Mo-Ag-Zn-Cd;并提出了主矿带理想原生晕分带序列:Sb-As-Cu-Hg(前缘晕)→Au-Ag-Bi-Pb-W(近矿晕)→Ni-Co-Mn-Mo-Zn-Cd(尾晕)。结合微量元素衬值空间变化规律,建立了2个矿体的原生晕叠加理想模型。Au11矿体在1 150 m中段以前缘晕和尾晕叠加为特征;在1 110 m中段,发育较强的尾晕。Au8矿体在1 150 m和1 070 m中段以前缘晕和尾晕叠加为特征;在1 110 m中段,矿体减薄,近矿晕减弱,发育很弱的前缘晕和尾晕。综合分析认为,Au11矿体到达中下部,向深部仍有一定延伸;Au8矿体已经接近尾部,深部可能存在新的矿体。     

论东秦岭秋树湾铜钼矿区扩大找矿的有利因素

作为东秦岭铜钼矿带上重要的铜钼矿区,秋树湾及其外围的找矿工作一直未取得重大突破,因此,明确秋树湾岩体形态及位置是扩大找矿的关键所在。本文通过分析成矿母岩、蚀变及矿化分带,结合遥感、地球物理探测技术,总结出研究区矿化蚀变分带模型,并利用钻孔验证,在秋树湾矿区先期取得了找矿突破。在理论和实践上指出:秋树湾斑岩体为本区的成矿母岩;埋深在1000m以下仍存在花岗斑岩体,深部斑岩体是重要的找矿方向;近南北向断裂为岩浆沿断裂从东向北西倾入提供了通道,岩体具有西浅东深的特点。     

Geochemical constraints on the distribution of trace elements and volatiles in fluorapatite from the Panasqueira tin-tungsten deposit (Portugal)

A large, euhedral crystal of fluorapatite (ca. 19.5 × 20.0 mm) from the Panasqueira tin-tungsten deposit (Portugal) was investigated in terms of the distribution of trace elements by using several microanalytical techniques. The studied material represents almost pure fluorapatite with minor amounts of other cations (mainly Sr, Mn, REE and Fe), OH and Cl. Particular interest was given to the distribution of rare earth elements with respect to the crystallographic orientation. A broad range of analytical techniques were used, including optical microscopy coupled with cathodoluminescence imaging, electron probe microanalysis (EPMA), laser ablation – inductively coupled plasma mass spectrometry (LA-ICPMS), Raman microspectroscopy, and simultaneous thermal analysis coupled with mass spectrometry. The investigated crystal consists of the main crystal with a distinct core and rim (Ap_2core and Ap_2rim, respectively), which grew on a previous, euhedral crystal (Ap₁). The fluorapatite demonstrates various types of zoning: regular oscillatory, irregular, and internal sectoring, which is also reflected in trace elements concentrations. The rim Ap_2rim has lower concentrations of Mn, Sr and Fe, and significantly higher concentrations of REE compared to the core Ap_2core and older crystal Ap₁. Furthermore, the rim Ap_2rim is strongly depleted in Th, U and Pb. The entire crystal shows elevated Eu contents, expressed as a strong positive anomaly in chondrite-normalized REE patterns. With regards to the volatiles, F concentrations are constant in Ap₁, Ap_2core and Ap_2rim, whereas Cl is below the EPMA detection limit. The Ap_2rim was the only part of the investigated material containing OH and CO₃, which were observed in the Raman spectra. Furthermore, part of the crystal Ap_2core is extensively altered, likely due to fluid-induced metasomatic processes. LA-ICPMS U-Pb dating yielded highly discordant dates due to common Pb content. A lower intercept age of 297 ± 13 Ma (MSWD = 0.13) indicates the age of the fluorapatite crystallization. The overall analytical data constrain growth and post-growth processes, including crystallization of Ap₁ and Ap_2core, which both have typical hydrothermal Sn-W deposit characteristics, whereas Ap_2rim is related to a carbonate stage of the mineralization in the Panasqueira deposit.     

泰青威天然气管道临朐段水毁灾害分布特征与风险评价

对泰青威天然气管道临朐段地质灾害发育特征进行调查研究发现,临朐段地质灾害类型主要为水毁灾害,具体可分为坡面水毁、河沟道水毁和台田地水毁。野外地质灾害实地调查临朐段管道沿线共发现地质灾害15处,其中坡面水毁点6处,河沟道水毁点4处,台田地水毁点5处。采用定性与半定量相结合的评价方法对其进行地质灾害风险评价,结果表明: 地质灾害风险等级较高的有1处,占6.66%; 风险等级中等的有4处,占26.67%; 风险等级较低的有10处,占66.67%。根据管道沿线地形地貌、地质灾害发育密度、风险等级等因素,划分地质灾害中易发区61 km,低易发区10 km,管道沿线以地质灾害中易发区为主。最后,针对不同类型、不同风险等级地质灾害提出了相应的防治消减措施,为后期管道安全运营和风险整治决策提供了有效的技术依据。     

Controls on metamorphic equilibration: the importance of intergranular solubilities mediated by fluid composition

A dramatic demonstration of the role of intergranular solubility in promoting chemical equilibration during metamorphism is found in the unusual zoning of garnet in pelitic schist exposed at Harpswell Neck, Maine, USA. Many garnet crystals have irregular, patchy distributions of Mn, Cr, Fe and Mg in their inclusion‐rich interiors, transitioning to smooth, concentric zoning in their inclusion‐poor outer rims; in contrast, zoning of Ca and Y is comparatively smooth and concentric throughout. We re‐assess the disputed origin of these zoning features by examining garnet growth in the context of the thermal and structural history of the rocks, and by evaluating the record of fluid–rock interaction revealed in outcrop‐scale veining and fluid‐inclusion assemblages. The transition in the character of garnet zoning correlates with the onset of a synkinematic, simple‐shear‐dominated phase of garnet growth and with a shift in the composition of the intergranular fluid from CO₂‐rich to H₂O‐rich. Compositional variations in garnet are therefore best explained by a two‐stage growth history in which intergranular diffusive fluxes reflect differences in the concentration of dissolved species in these two contrasting fluids. Interiors of garnet crystals grew in the presence of a CO₂‐rich fluid, in which limited solubility for Mn and Cr (and perhaps Fe and Mg) produced patchy disequilibrium overprint zoning, while appreciable solubility for Ca and Y permitted their rock‐wide equilibration. Rims grew in the presence of an H₂O‐rich fluid, in which high intergranular concentrations for all elements except Cr enabled diffusion over length scales sufficient for rock‐wide equilibration. This striking example of partial chemical equilibrium during reaction and porphyroblast growth implies that thermal effects may commonly be subsidiary in importance to solubilities in the intergranular medium as determinants of length scales for metamorphic equilibration.     

云南兰坪北部铜多金属矿化区成矿流体流动与矿化分带——流体包裹体和稳定同位素依据

滇西兰坪盆地北部发育了一类受逆冲推覆构造控制的浅成热液Cu—Ag—Pb-Zn矿化，形成了白秧坪、富隆厂、吴底厂、麻栗坪及金满、科登涧等大-中型矿床和矿点，并存在矿化分带。文章利用这些矿化脉体的流体包裹体和热液方解石的碳氧同位素组成资料，研究成矿流体与矿化分带的关系。结果表明，成矿流体主要属于NaCl-H2O成分体系，盐度ω(NaCleq)为2％～11％，形成温度为170～300℃，形成于1．8～3．8km深度内，这些相似性说明这类矿化的发生具有相似的流体性质和沉淀机制。热液方解石在δ^13C-δ^18O图解中呈近水平线展布的型式，指示流体源自地壳浅部的地下水系统，与海相灰岩等围岩作用形成了溶解碳以[HCO3^]-为主的成矿流体，流体与岩石的相互作用可能是成矿流体沉淀的主要机理。从西到东，流体包裹体的盐度-温度由高到低变化与矿化分带和逆冲推覆构造的根带→中带→锋带相配套，显示重力驱动流动可能是主要的流体流动机制。成矿流体在不同构造部位流动的通畅及流体．岩石系统的封闭-开放程度等流体流动性质与矿化发生的强度和规模有关，兰坪北部逆冲推覆构造中带的流体通畅地流动及沉淀时处于相对开放状态，有利于该区形成较大规模的浅成热液多金属矿化。     

得尔布干成矿带西南段矿床类型、成矿分带及找矿方向

得尔布干成矿带的西南段位于内蒙古自治区的新巴尔虎右旗至满洲里一带,是大兴安岭成矿省内极具找矿潜力的地区.铜、钼、铅、锌、银是该区的主要矿种,区内已发现大型矿床4处,小型矿床和矿点多处,分别形成于燕山早期和燕山晚期这2个主要成矿期,并可划分为3个矿床类型、6个矿床式.燕山早期的成矿元素主要是Cu、Mo、Au,以斑岩型和矽卡岩型矿床为主;燕山晚期的成矿元素主要为Pb、Zn、Ag,以次火山热液型和浅成热液型矿床为主.燕山期隆坳相间的构造格局和超浅成-浅成的中-酸性小岩体,控制着矿床的产出和分布.矿产地集中于燕山期隆坳交接带及其两侧,并形成以隆坳交接带为中心的、与成矿流体温度和盐度降低相伴的不对称分带.文章提出,得尔布干成矿带西南段的找矿潜力主要在隆坳交接带及其两侧,具体为已知矿区的深部及边部、乌奴格吐山-哈拉胜隆坳交接带和甲乌拉-山登脑隆坳交接带的两侧.此外,位于该区西南部的另一个隆坳交接带是潜在的矿化集中区.     

Progress in the Application of Ground Gravity Observation Data in Earthquake Prediction

The mechanism of earthquake inoculation and the process of earthquake occurrence are very complicated. Additionally, earthquakes do not happen very often, and we lack enough cognition to the earth’s interior structure, activity regularity and other key elements. As a result, research progress about the theory of earthquake precursors has been greatly restricted. Ground gravity observation has become one of the main ways to study earthquake precursor information in many countries and regions. This paper briefly summarized the surface gravity observation technology and observation network in China: the surface gravity measurement instrument developed from Huygens physical pendulum in seventeenth Century to today’s high-precision absolute gravimeter, and its accuracy reached to ±1×10^-8 m/s². China has successively established the National Gravity Network, Digital Earthquake Observation Network of China,the Crustal Movement Observation Network of China Ⅰ and the Crustal Movement Observation Network of China, to provide a public platform for monitoring non tidal gravity change, seismic gravity and tectonic movement. The use of specific examples illustrated the role of gravity observation data in earthquake prediction. The gravity observation data of ground gravity can be used to capture the information of gravity change in the process of strong earthquake inoculation, and to provide an important basis for the long-term prediction of strong earthquakes. The temporal and spatial variation characteristics of the regional gravity field and its relation to strong earthquakes were analyzed: Before the earthquake whose magnitude is higher than M_S 5, generally there will be a large amplitude and range of gravity anomaly zones. Strong earthquakes occur mainly in areas where the gravity field changes violently. The dynamic change images of gravity field can clearly reflect the precursory information of large earthquakes during the inoculation and occurrence. Finally, the existing problems of surface gravity technology in earthquake precursor observation were put forward and the use of gravity measurement data in earthquake prediction research was prospected.     

湖北铜绿山铜铁矿床中煌斑岩的矿物学特征及岩石成因初探

湖北铜绿山矽卡岩型铜铁矿床处于长江中下游铁铜成矿带西部的鄂东南矿集区。最近我们在该矿区工作中采集到两条侵入于含矿石英二长闪长玢岩中的煌斑岩脉。本文对这些煌斑岩脉进行了详细的镜下岩相学观察,并对其中造岩矿物黑云母、辉石和长石进行了电子探针成分分析。根据这些数据本文论述了煌斑岩的物源、形成环境以及岩浆体系的物理化学条件。研究表明,煌斑岩中云母为富镁黑云母,其形成的岩浆体系处于中低氧逸度(近Ni-Ni O);黑云母与全岩都具有高钛特征,表明煌斑岩的物源深度可能来自较深部地幔(如软流圈)。煌斑岩中辉石为单斜辉石,环带较为发育,有韵律环带和正环带,其韵律环带的形成可能是由于岩浆温压环境存在振荡性变化而形成的。铜绿山矿床中煌斑岩属于云煌岩;其岩浆来源具幔源性,受到地壳的混染作用不强。     

西藏厅宫斑岩铜矿床地质、蚀变及矿化特征研究

本文对西藏厅宫大型铜矿进行了详细研究,矿床详细的地质岩相学-蚀变以及典型剖面填图表明,矿区存在2个岩浆事件高峰,即始新世的钾长花岗岩(~50 Ma)和中新世的斑状二长花岗岩、英云闪长斑岩及闪长玢岩(约13~17 Ma)。野外和室内研究发现,厅宫矿区存在2期重要的矿化事件,即始新世(~50 Ma)铜矿化及中新世(~15Ma)的铜钼矿化。始新世含矿岩体为钾长花岗岩,其最主要的特点是其成矿岩体结构的特殊性,表现在该矿床的成矿岩体没有典型的斑状结构,而是独特的细晶-似伟晶结构,说明含矿岩浆发生过骤冷,可能是流体突然逃逸,矿物结晶的固相点发生漂移所致。同时,该岩体还发育大量显微文象结构、显微晶洞构造等,均说明岩浆曾经富水,并且曾经流体饱和;中新世含矿岩体为具有埃达克岩特征的斑状二长花岗岩,主要以脉状的铜、钼矿化为主。该矿床蚀变分带类似于冈底斯带其他斑岩矿床。时间上,分别为早期的钾硅酸盐化、转换阶段的青磐岩化、随后的绢英岩化及最晚期的泥化蚀变;空间上,以含矿岩体为中心向外依次为钾硅酸盐化、绢英岩化、青磐岩化,最晚期的泥化呈补丁状或条带状叠加早期各类蚀变。铜矿化主要发生在始新世的黑云母化阶段和中新世的绢英岩化阶段,而钼矿化主要发生在中新世的钾硅酸盐化和绢英岩化的转换阶段。